JP2002003334A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prepare a cosmetic having excellent feeling by solving the problem of stickiness while keeping the basic functions of a silicone surfactant modified with glyceral or polyglycerin. SOLUTION: The cosmetic contains 0.01-20 mass % of a silicone surfactant modified with a glyceral or a polyglycerin expressed by formula 1, 2 or 3, and 0.1-30 mass % of a saccharide selected from disaccharides and trisaccharides.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic composition which is less sticky, has good moisture retention, and is excellent in feel. More specifically, a glycerin-modified or polyglycerin-modified silicone-based surfactant that does not generate off-flavors over time and has excellent stability, emulsifying properties, and moisturizing properties, but has a tendency to sticky organoleptically A silicone surfactant modified with glycerin or polyglycerin by combining a non-adhesive disaccharide, a trisaccharide, and a saccharide selected from trisaccharides, which is excellent in improving the feel of an oil agent, especially raffinose. While maintaining the basic performance of
The present invention relates to a cosmetic which is characterized by eliminating stickiness and having an excellent feel.

[0002]

2. Description of the Related Art Hitherto, polyether-modified silicones, which have been modified with a polyoxyalkylene group, have had problems such as generation of an unpleasant odor over time and low stability of the preparation due to temperature change. In response to these problems, a silicone surfactant modified with glycerin or polyglycerin (hereinafter, referred to as a glycerin-modified silicone surfactant) has been developed. Glycerin-modified silicone surfactants are less likely to generate off-flavors over time, have excellent formulation stability due to temperature changes, and have excellent emulsifying properties due to their higher affinity for water than polyoxyalkylene chains. There is a feature that there is.

[0003]

However, the glycerin-modified silicone-based surfactant also has a sticky feeling, which is a characteristic of glycerin, and has a functional property, which hinders the freedom of formulation. .

[0004]

The present inventors have determined that saccharides, especially raffinose, can significantly alter the feel by reducing the sticky properties of glycerin and the like, and imparting a non-sticky tendency. Finding out and applying this technology to glycerin-modified silicone surfactants,
The sticky feeling was successfully reduced while maintaining the excellent properties such as the emulsifying properties of the glycerin-modified silicone surfactant.

That is, the present invention provides the following general formulas (1) to
(3) one or more glycerin- or polyglycerin-modified silicone surfactants, and a disaccharide;
And a saccharide selected from trisaccharides.

[0006]

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[0007]

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[0008]

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[In the formulas (1) to (3), R _{1 to} R ₂₅ represent an alkyl group having 1 to 30 carbon atoms, a phenyl group, a fluorine-substituted alkyl group or a polyoxyalkylene group, and A ₁ and A ₂
Represents an alkylene group having 1 to 10 carbon atoms, m, n, p,
q and r each represent an integer of 0 or more, and R ₂₆ represents the following general formula (a), (b) or (c). ]

[0010]

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[0011]

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[0012]

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In the formulas (a) to (c), A _{3 to} A ₅ represent an alkylene group having 1 to 10 carbon atoms, and x and y each represent an integer of 0 or more. ]

[0014]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The method for introducing a glycerin-derived group or a polyglycerin-derived group into a glycerin-modified silicone surfactant used in the present invention is described in JP-A-6-15.
For example, a glycerin derivative or a polyglycerin derivative having an olefinic bond at a terminal is prepared according to the synthesis method described in Japanese Patent Application Laid-Open No. 7236/1997 and Japanese Patent Application Laid-Open No. 9-71504, and this is mixed with methylhydrogenpolysiloxane under a platinum-based catalyst. Reaction. In the present invention, it is particularly preferable to use a fluoropolyglycerin co-modified silicone having dimethylpolysiloxane as a main chain and having a polyglycerin-derived group and a perfluoroalkyl group (particularly, a trifluoropropyl group) as a pendant group. As the HLB of the glycerin-modified silicone surfactant used in the present invention, an HLB in the range of 1 to 20 is preferably used.

The blending amount of the glycerin-modified silicone surfactant in the present invention is preferably 0.01 to 20% by mass based on the mass of the cosmetic. Within this range, the function as a surfactant or oil agent can be effectively exhibited. In the present invention, it is preferable to use various surfactants described below in combination with the glycerin-modified silicone surfactant.

The saccharide used in the present invention is selected from disaccharides and trisaccharides, and examples thereof include raffinose, sucrose, lactose, maltose, maltitol, trehalose, and mixed isomerized sugars, with raffinose being particularly preferred. . Raffinose is a type of trisaccharide, O-α-
It has a structure of D-galactopyranosyl- (1,6) -O-α-D-glucopyranosyl- (1,2) -β-D-fructofuranoside. It can be obtained from eucalyptus manna, sugar beet molasses, cotton berries and the like, but is most preferably derived from sugar beet molasses derived from sugar beet. Further, a small amount of lactose (lactose) may be mixed with raffinose. Raffinose may be anhydrous or pentahydrate,
It is preferable to use pentahydrate because the supply is stable. It is preferable to use raffinose having a purity of 99% or more in consideration of quality stability. One or more of these saccharides are used.

In the present invention, the amount of the saccharide incorporated into the cosmetic is preferably 0.1 to 30% by mass based on the mass of the cosmetic. Within this range, the sticky feeling of the glycerin-modified silicone surfactant can be effectively suppressed.

The cosmetic of the present invention contains, in addition to the above components, oils and powders (pigments, pigments,
Resins), fluorine compounds, resins, surfactants, adhesives, preservatives, fragrances, UV protection agents (including organic and inorganic.
-A or B), moisturizers, physiologically active ingredients, salts, solvents, antioxidants, chelating agents, neutralizers, pH adjusters, insect repellents, enzymes and other components. Can be appropriately blended.

In the present invention, even when these optional components are used in combination with a glycerin-modified silicone-based surfactant or a polyhydric alcohol having excellent compatibility with saccharides such as raffinose, the feeling and the moisturizing property can be maintained without stickiness. Excellent cosmetics can be obtained. Examples of the polyhydric alcohol used in the present invention include ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, 3-methyl-1,3-butanediol, Examples include 3-butylene glycol, alkylated trehalose, sulfated trehalose, pullulan and the like. Further, these chemically modified products can also be used.

Examples of the oil agent used in the present invention include volatile and non-volatile oil agents, solvents and resins commonly used in cosmetics, and may be liquid, paste or solid at room temperature. Excellent liquids are preferred. Examples of oils include, for example, cetyl alcohol,
Higher alcohols such as isostearyl alcohol, lauryl alcohol, hexadecyl alcohol, octyldodecanol, fatty acids such as isostearic acid, undecylenic acid and oleic acid, myristyl myristate, hexyl laurate, decyl oleate, isopropyl myristate, and dimethyloctanoic acid Esters such as hexyldecyl, glyceryl monostearate, diethyl phthalate, ethylene glycol monostearate, octyl oxystearate, hydrocarbons such as liquid paraffin, petrolatum, squalane, waxes such as lanolin, reduced lanolin, carnauba wax, and mink oil And oils such as cocoa butter, coconut oil, palm oil, palm kernel oil, camellia oil, sesame oil, castor oil and olive oil, and ethylene / α-olefin / co-oligomers.

Examples of other types of oils include dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, polyether-modified organopolysiloxane, and fluoroalkyl.
Polyoxyalkylene co-modified organopolysiloxane,
Alkyl-modified organopolysiloxane, terminal-modified organopolysiloxane, fluorine-modified organopolysiloxane, amodimethicone, amino-modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicic acid, silicone compound such as silicone RTV rubber, perfluoropolyether, Pitch fluoride,
Fluorine compounds such as fluorocarbon and fluoroalcohol are exemplified.

Examples of the powder used in the present invention include dyes such as Red No. 104, Red No. 201, Yellow No. 4, Blue No. 1, Black No. 401, Yellow No. 4 Al Lake, Yellow No. 203 Ba Lake and the like. Lake pigments, nylon powder, silk powder, polyurethane powder, polyfluoroethylene powder, silicone powder, polymethyl methacrylate powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, yellow iron oxide,
Colored pigments such as red iron oxide, black iron oxide, chromium oxide, carbon black, ultramarine, navy blue, zinc oxide, titanium oxide,
White pigments such as cerium oxide, talc, mica, sericite, kaolin, extender pigments such as barium sulfate, pearl pigments such as mica titanium, barium sulfate, calcium carbonate,
Metal salts such as magnesium carbonate, aluminum silicate, and magnesium silicate; inorganic powders such as silica and alumina; bentonite, smectite, and boron nitride. The shape of these powders (spherical, rod-like, needle-like, plate-like, irregular, flake-like, spindle-like, etc.) is not particularly limited.

These powders may be subjected to conventionally known surface treatments such as fluorine compound treatment, silicone treatment, silicone resin treatment, pendant treatment, silane coupling agent treatment, and the like.
Titanium coupling agent treatment, silane treatment, oil treatment, N
-Acylated lysine treatment, polyacrylic acid treatment, metal soap treatment, amino acid treatment, inorganic compound treatment, plasma treatment,
It may or may not have been surface-treated in advance by mechanochemical treatment or the like.

Examples of the solvent include purified water, cyclic silicone, ethanol, light liquid isoparaffin, lower alcohol, ethers, LPG, fluorocarbon, N-methylpyrrolidone, fluoroalcohol, volatile linear silicone, next-generation Freon, etc. Is mentioned.

As the surfactant, for example, an anionic surfactant, a cationic surfactant, a nonionic surfactant, and an amphoteric surfactant can be used. More specifically, fatty acid soap, α-acyl sulfonate, alkyl sulfonate, alkyl allyl sulfonate, alkyl naphthalene sulfonate, alkyl sulfate, alkyl ether sulfate, alkyl amide sulfate, alkyl phosphate,
Anionic surfactants such as alkylamidophosphates, alkylloylalkyltaurates, N-acylamino acid salts, sulfosuccinates, perfluoroalkylphosphates, alkyltrimethylammonium chloride, stearyltrimethylammonium chloride, stearyltrimethyl bromide Cationic surfactants such as ammonium, cetostearyltrimethylammonium chloride, distearyldimethylammonium chloride, stearyldimethylbenzylammonium chloride, behenyltrimethylammonium bromide, alkanolamide laurate, POE sorbitan fatty acid ester, POE glycerin fatty acid ester, P
Nonionic surfactants such as OE fatty acid ester and polyether-modified silicone, carboxybetaine type, amidobetaine type, sulfobetaine type, hydroxysulfobetaine type, amidosulfobetaine type, phosphobetaine type,
Examples include amphoteric surfactants such as aminocarboxylate type, imidazoline derivative type and amidoamine type. In addition, natural surfactants such as saponins and sugar surfactants can also be used.

Examples of the physiologically active ingredient used in the present invention include substances that give some physiological activity to the skin when applied to the skin. For example, whitening ingredients, anti-inflammatory agents,
Anti-aging agents, UV protection agents, slimming agents, tightening agents, antioxidants, hair growth agents, hair growth agents, humectants, blood circulation promoters,
Antibacterial agent, bactericide, desiccant, cooling agent, warming agent, vitamins, amino acid, wound healing promoter, stimulant, analgesic,
Cell activators, enzyme components and the like can be mentioned. Among them, natural plant extract components, seaweed extract components, and crude drug components are particularly preferable. In the present invention, one or more of these physiologically active components are preferably blended.

Examples of these components include, for example, Ashitaba extract, Avocado extract, Amacha extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Apricot kernel extract, Ginkgo extract, Fennel extract, Turmeric extract, Oolong tea extract, Agetsu Extract, Echinacea leaf extract, Japanese gourd extract, oak extract, spinach extract, barley extract, hypericum extract, scotch extract, Dutch mustard extract, orange extract, seawater dried product, seaweed extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk , Chamomile extract, carrot extract, sagebrush extract, licorice extract, calcade extract, syllium extract, kiwi extract, kina extract, cucumber extract, guanosine,
Gardenia extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Clematis extract, Chlorella extract, Mulberry extract, Gentian extract,
Black tea extract, yeast extract, burdock extract, rice bran extract, rice germ oil, comfrey extract, collagen,
Cowberry extract, Saishin extract, Psychoextract, Saitai extract, Salvia extract, Sabonso extract, Sasa extract, Hawthorn extract, Sansho extract, Shiitake extract, Jio extract, Shikon extract, Perilla extract, Shinanoki extract, Shimotsukei extract, Peony extract, Shobu root extract , Birch extract, horsetail extract, vegetative extract, hawthorn extract,
Sambucus elder extract, Achillea millefolium extract, Common mint extract, Sage extract, Genus mallow extract, Senkyu extract, Assembly extract, Soybean extract, Tissou extract, Thyme extract, Tea extract, Clove extract, Chigaya extract, Chimpi extract, Touki extract, Calendula extract, Tonin extract , Spruce extract, Dokudami extract, Tomato extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Hibiscus extract, Bacmondou extract, Parsley extract, Honey, Hamamelis extract, Parietaria extract, Hioki sorghum extract, Bisabolol, Loquat extract, Coltsfoot poppo extract , Fukinotou extract, kukuroyou extract, butcher bloom extract, grape extract, propolis, loofah extract, safflower Vinegar, peppermint extract, lime extract, button extract, hops extract, pine extract, horse chestnut extract, skunk cabbage extract, Sapindus extract, Melissa extract, peach, cornflower extract, eucalyptus extract, saxifrage extract, Yuzuekisu,
Yokuinin extract, mugwort extract, lavender extract,
Examples include apple extract, lettuce extract, lemon extract, astragalus extract, rose extract, rosemary extract, Roman chamomile extract, royal jelly extract and the like.

Also, biopolymers such as deoxyribonucleic acid, mucopolysaccharides, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, hydrolyzed eggshell membranes, amino acids, sodium lactate, urea, sodium pyrrolidonecarboxylate; Betaine, moisturizing components such as whey, sphingolipids, ceramides, cholesterol, cholesterol derivatives, oily components such as phospholipids, ε-aminocaproic acid, glycyrrhizic acid, β-glycyrrhetinic acid, anti-inflammatory agents such as lysozyme chloride, guaiazulene, hydrocortisone, Vitamins A, B2, B6, C, D, E, calcium pantothenate, vitamins such as biotin, nicotinamide, vitamin C ester, allantoin, diisopropylamine dichloroacetate, 4-amido Active ingredients such as nomethylcyclohexanecarboxylic acid, tocopherols, carotenoids, flavonoids, antioxidants such as tannins, lignans, saponins, cell activators such as α-hydroxy acids and β-hydroxy acids, γ-oryzanol, vitamin E derivatives, etc. Blood circulation promoters, retinol, wound healing agents such as retinol derivatives, arbutin, kojic acid, placenta extract, whitening agents such as sulfur, ellagic acid, linoleic acid, tranexamic acid, glutathione, cepharanthin, licorice extract,
Pepper tincture, hinokitiol, garlic iodide extract, pyridoxine hydrochloride, dl-α-tocopherol,
Dl-α-tocopherol acetate, nicotinic acid, nicotinic acid derivatives, calcium pantothenate, D-pantothenyl alcohol, acetyl pantothenyl ethyl ether, biotin, allantoin, isopropylmethylphenol, estradiol, ethinylesteradiol, capronium chloride, benzalco chloride Ium, diphenhydramine hydrochloride, tacanal, camphor, salicylic acid, vanillyl amide nonylate, vanillyl nonanoate, pyrocton olamine, glyceryl pentadecanoate, l-menthol, mononitroguaiacol, resorcinol, γ-aminobutyric acid, benzethonium chloride, mexiletine hydrochloride, auxin , Female hormones, cantaris tincture, cyclosporine, zinc pyrithione, hydrocortisone, minoxidil, monostearin And a hair restorer such as polyoxyethylene sorbitan acid, peppermint oil and Sasanishiki extract.

In the present invention, the use of a tackifier or a resin is also effective because saccharides such as raffinose can exert the effect of suppressing tackiness and tackiness. Examples of the tackifier and resin include sodium polyacrylate, cellulose ether, calcium alginate, carboxyvinyl polymer, ethylene / acrylic acid copolymer, vinylpyrrolidone-based polymer, vinyl alcohol / vinylpyrrolidone copolymer, and nitrogen-substituted acrylamide-based Polymer, polyacrylamide, cationic polymer such as cationized guar gum, dimethylacrylammonium-based polymer, acrylic acid methacrylate acrylic copolymer, POE / POP
Copolymer, polyvinyl alcohol, pullulan, agar, gelatin, tamarind seed polysaccharide, xanthan gum, carrageenan, high methoxyl pectin, low methoxyl pectin, guar gum, gum arabic, crystalline cellulose, arabinogalactan, karaya gum, tragacanth gum, alginic acid, albumin, Examples include casein, curdlan, gellan gum, dextran, cellulose, polyethyleneimine, highly polymerized polyethylene glycol, cationized silicone polymer, and synthetic latex.

It is also preferred that the cosmetic of the present invention impart an ultraviolet protection effect. In this case, it is preferable to use an ultraviolet protective agent as described below. The amount of the ultraviolet protective agent is 1 to 50% by mass based on the total amount of the cosmetic.
Is more preferable, and more preferably 1 to 40% by mass.

Examples of the ultraviolet protection agent include inorganic and organic types. Among the inorganic types, fine particle titanium oxide and fine particle zinc oxide are exemplified.
For example, 2-ethylhexyl paramethoxycinnamate, 2-
Hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfate, 2,
2'-dihydroxy-4-methoxybenzophenone, p
-Methoxyhydrocinnamic acid diethanolamine salt, para-aminobenzoic acid (hereinafter abbreviated as PABA), ethyldihydroxypropyl PABA, glyceryl PABA, homomenthyl salicylate, methyl-O-aminobenzoate, 2-ethylhexyl-2-cyano-3,3- Diphenyl acrylate, octyl dimethyl PABA, octyl salicylate, 2-phenyl-benzimidazole-5
-Sulfuric acid, triethanolamine salicylate, 3- (4-
Methylbenzylidene) camphor, 2,4-dihydroxybenzophenine, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2,2′-dihydroxy-4,4 ′
-Dimethoxybenzophenone, 2-hydroxy-4-N
-Octoxybenzophenone, 4-isopropyldibenzoylmethane, butylmethoxydibenzoylmethane, 4
-(3,4-dimethoxyphenylmethylene) -2,5-
Examples thereof include 2-ethylhexyl dioxo-1-imidazolidine propionate, a polymer derivative thereof, and a silane derivative. Furthermore, these absorbents, preferably 4-
What sealed tert-butyl-4'-methoxydibenzoylmethane in the polymer can also be used preferably.

Examples of the cosmetics of the present invention include makeup cosmetics such as foundation, white powder, eyeshadow, eyeliner, eyebrow, cheek, lipstick, nail color, emulsions, creams, lotions, calamine lotions, sunscreens, Suntan, after-shave lotion, pre-shave lotion, pack fee, anti-acne cosmetics, basic cosmetics such as essence, shampoo, rinse, conditioner, hair color, hair tonic, set agent, body powder, deodorant, depilatory, soap, body Shampoo, bath salt, hand soap,
Perfumes and the like.

The dosage form of the cosmetic of the present invention may be a two-layer,
Conventionally known dosage forms such as a water-in-oil emulsion, an oil-in-water emulsion, a gel, a spray, a mousse, an oil, a solid, and a sheet can be used.

[0034]

The present invention will be described in detail below with reference to examples and comparative examples. In addition, evaluation methods for various characteristics of the cosmetics used for evaluation of the examples and the comparative examples are shown below.

[Formulation stability test]
And left at room temperature for 6 months, and visually observed the state of the preparation.

[Evaluation of Sensory Characteristics] Ten expert panelists were prepared for each evaluation item (however, panelists may be duplicated depending on the item), and evaluation was performed according to the evaluation criteria shown in Table 1, and the total of all panelists was calculated. The evaluation result was given based on the score. Therefore, the higher the score, the higher the usefulness for the evaluation item is shown (full score: 50 points).

[Table 1] Reference points --------------------------------------- ------- The effect is felt high 5 The effect is felt 4 The effect is felt slightly 3 The effect is felt only slightly 2 The effect is not felt 1

Example 1 Lotion A lotion was prepared according to the formulation and manufacturing method shown in Table 2.
As the polyglycerin-modified dimethylpolysiloxane in the table, R ₂₆ in the general formula (3) is A _{5 in the} general formula (c).
Used was C ₃ H ₆ . The unit of the amount is mass%.

[Table 2] Ingredients Compounding amount --------------------------------------- ----------------------- (1) Ethanol 10.0 (2) 1,3-butylene glycol 3.0 (3) Glycerin 5.0 (4 ) Polyglycerin-modified dimethylpolysiloxane (HLB: 14) 0.3 (5) Methylparaben 0.1 (6) Tocopherol acetate 0.01 (7) Citric acid 0.1 (8) Sodium citrate 0.3 (9) Polyethylene glycol 4000 3.0 (10) Raffinose 3.0 (11) Trimethylglycine 1.0 (12) Sodium hyaluronate (molecular weight: about 100,000) 0.02 (13) Purified water to100

Production Method (A) Components (1) to (6) are uniformly mixed and dissolved. (B) Components (7) to (13) are uniformly mixed and dissolved. (B) was added to (A), mixed, stirred, filtered, and filled in a PET resin container with a pump to obtain a product.

Comparative Example 1 A product was obtained in the same manner as in Example 1 except that purified water was used in place of raffinose used in Example 1.

Example 2 Emulsion (O / W) An emulsion was prepared according to the formulation and production method shown in Table 3. As the trifluoropropyl polyglycerin co-modified dimethylpolysiloxane in the table, R ₂₁ is a trifluoropropyl group and R ₂₆ is a group represented by the general formula (b) in the general formula (3).
And y was 1 and A ₄ was C ₃ H ₆ . The unit of the amount is mass%.

[Table 3] Ingredients Compounding amount --------------------------------------- ----------------------- (1) Squalane 10.0 (2) Olive oil 2.0 (3) Glycerin monostearate 2.5 (4) Glycerin tribehenate 1.0 (5) Trifluoropropyl polyglycerin co-modified dimethyl polysiloxane (HLB: 2) 2.0 (6) Glycerin modified dimethyl polysiloxane (HLB: 9) 4.0 (7) Butyl paraben 1 (8) Sodium N-stearoyl-L-glutamate 1.0 (9) Glycerin 5.0 (10) Alkyl-modified carboxyvinyl polymer 0.1 (11) Carboxyvinyl polymer 0.1 (12) Methylparaben 0.1 ( 13) Phenoxyethanol 0.3 (14) Potassium hydroxide 0.15 (15) Raffinose 10.0 (16) Japanese goon extract 3.0 (17) Natto extract 3.0 (18) Purified water to 100

Production Method (A) Components (1) to (7) are mixed and dissolved at about 80 ° C. (B) Components (8) to (18) are mixed and dispersed at about 80 ° C. After (B) was added to (A) and emulsified, the mixture was dispersed with a homogenizer, cooled to about 32 ° C., and filled in a container with a pump to obtain a product.

Comparative Example 2 A product was obtained in the same manner as in Example 2, except that purified water was used instead of raffinose in Example 2.

Example 3 Emulsion (W / O) An emulsion was prepared according to the formulation and production method shown in Table 4. The unit of the amount is mass%.

[Table 4] Ingredients Compounding amount --------------------------------------- ------------------------ (1) Vegetable squalane 5.0 (2) Jojoba oil 1.0 (3) Olive oil 1.0 (4) ) Dimethicone (40000CS) 1.0 (5) Decamethylcyclopentasiloxane 30.0 (6) (Mono-poly mixed) glycerin-modified dimethyl polysiloxane (HLB: 7) 5.0 (7) Sorbitan monoisostearate 0 (8) Methyl paraben 0.2 (9) Phenoxyethanol 0.5 (10) Glycerin 8.0 (11) Alkyl-modified carboxyvinyl polymer 0.8 (12) 1,3-butylene glycol 4.0 (13) Edetate Sodium 0.05 (14) Potassium hydroxide 0.45 (15) Raffinose 10.0 (16) Sorbitol 3.0 17) Trimethylglycine 3.0 (18) ascorbic acid glucosyl 0.5 (19) Lactic acid bacteria fermentation liquid 3.0 (20) Purified water to 100

Production Method (A) Components (1) to (7) are uniformly mixed and dissolved. (B) Components (8) to (20) are uniformly mixed and dispersed. (B) was added to (A), dispersed with a homogenizer, and filled in a PET container with a pump to obtain a product.

Example 4 Cleansing Gel A cleansing gel was prepared according to the formulation and manufacturing method shown in Table 5. As the glycerin-modified dimethylpolysiloxane, those having A _{2 in} the above formula (2) and C ₃ H ₆ were used.
The unit of the amount is mass%.

[Table 5] Ingredient Compounding amount --------------------------------------- ------------------------- (1) Squalane 5.0 (2) Olive oil 5.0 (3) Jojoba oil 1.0 (4) Decamethylcyclopentasiloxane 15.0 (5) Dimethicone (100CS) 4.0 (6) Glycerin-modified dimethylpolysiloxane (HLB: 12) 5.0 (7) Glycerin 3.0 (8) POE (16) Octyldodecyl Ether 1.0 (9) carboxyvinyl polymer 0.4 (10) methylparaben 0.3 (11) phenoxyethanol 0.1 (12) disodium edetate 0.03 (13) raffinose 10.0 (14) maltitol 5 0.0 (15) Lactic acid 0.5 (16) Potassium hydroxide 0.4 (17) Purified water to100

Production Method (A) Components (1) to (6) are uniformly mixed and dissolved. (B) Components (7) to (17) are uniformly mixed and dispersed. (B) was added to (A), dispersed with a homogenizer, and filled in a PET container with a pump to obtain a product.

Example 5 Cleansing Oil A cleansing oil was prepared according to the formulation and production method shown in Table 6. As the glycerin-modified dimethylpolysiloxane, those having A _{2 in} the above formula (2) and C ₃ H ₆ were used.
The unit of the amount is mass%.

[Table 6] Ingredients Compounding amount --------------------------------------- ------------------ (1) Squalane 30.0 (2) Olive oil 5.0 (3) Lavender oil 1.0 (4) Octyldodecyl myristate 10.0 (5) Glycerin-modified dimethylpolysiloxane (HLB: 7) 17.0 (6) Glycerin 30.0 (7) Raffinose 1.0 (8) 1,3-butylene glycol 5.0 (9) Purified water 1.0

Production Method Components (1) to (9) were uniformly mixed and stirred, filtered, and filled in a transparent PET resin container with a pump to obtain a product.

Table 7 shows the stability evaluation results of the examples and comparative examples.
Shown in

[0056]

Table 8 shows the results of the sensory evaluation of the examples and the comparative examples by using specialized panels.

[Table 8] No sticky feeling during use Moist feeling after use ------------------------------ ------------------------------- Example 1 45 44 Example 2 47 49 Example 3 43 42 Example 4 44 46 Example 5 42 49 Comparative Example 1 23 41 Comparative Example 2 22 19

From the results shown in Tables 7 and 8, each Example of the present invention is superior in stability of the preparation as compared with each Comparative Example, and has a feeling that there is no stickiness and excellent moisture retention. I found out. Also, from the results of interviews with panelists,
It was also found that the effect of maintaining a moist feeling after use was high.

[0060]

From the above, it can be seen that the present invention does not generate an odor over time and has excellent performance in terms of stability, emulsifying properties and moisturizing properties, but tends to cause organoleptic stickiness. Modified with glycerin or polyglycerin by combining a silicone-based surfactant modified with glycerin or polyglycerin and a saccharide, especially raffinose, which is non-adhesive and excellent in modifying the feel of oils and the like It is clear that a sticky feeling can be eliminated and a cosmetic excellent in feel can be obtained while maintaining the basic performance of the silicone-based surfactant.

Continued on front page F-term (reference) 4C083 AA032 AA112 AA122 AB032 AC022 AC102 AC122 AC132 AC172 AC182 AC292 AC302 AC422 AC442 AC482 AC532 AC582 AD042 AD112 AD161 AD162 AD172 AD211 AD212 AD332 AD662 BB06 CC01 CC04 CC05 CC23 DD27 DD30 DD31 EE06 EE03

Claims (3)

[Claims] 1. It contains one or more glycerin or polyglycerin-modified silicone surfactants represented by the following general formulas (1) to (3), and a saccharide selected from disaccharides and trisaccharides. Cosmetics characterized by the following. Embedded image Embedded image Embedded image [In formulas (1) to (3), R _{1 to} R _{25 each} have 1 to 30 carbon atoms.
Represents an alkyl group, a phenyl group, a fluorine-substituted alkyl group or a polyoxyalkylene group, wherein A ₁ and A ₂ have 1 to 1 carbon atoms.
10 represents an alkylene group, m, n, p, q, and r represent an integer of 0 or more, and R ₂₆ represents the following general formula (a), (b), or (c). ] Embedded image Embedded image [In formulas (a) to (c), A _{3 to} A ₅ represent an alkylene group having 1 to 10 carbon atoms, and x and y each represent an integer of 0 or more. ] 2. The silicone surfactant modified with glycerin or polyglycerin has a content of 0.01 to 20.
The cosmetic according to claim 1, wherein the content of the saccharide selected from the group consisting of disaccharides and trisaccharides is 0.1 to 30% by mass. 3. The cosmetic according to claim 1, wherein the saccharide is raffinose.