JP2001506799A - リチウム二次電池の出力密度改善方法およびアノード（負極） - Google Patents
リチウム二次電池の出力密度改善方法およびアノード（負極）Info
- Publication number
- JP2001506799A JP2001506799A JP52822998A JP52822998A JP2001506799A JP 2001506799 A JP2001506799 A JP 2001506799A JP 52822998 A JP52822998 A JP 52822998A JP 52822998 A JP52822998 A JP 52822998A JP 2001506799 A JP2001506799 A JP 2001506799A
- Authority
- JP
- Japan
- Prior art keywords
- anode
- lithium
- borate
- battery
- additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 23
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 9
- 150000002642 lithium compounds Chemical class 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims description 13
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 9
- -1 borate ester Chemical class 0.000 claims description 7
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001450 anions Chemical class 0.000 description 16
- 239000003792 electrolyte Substances 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004327 boric acid Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000011149 active material Substances 0.000 description 3
- 239000010405 anode material Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000010668 complexation reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 208000020960 lithium transport Diseases 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 206010021036 Hyponatraemia Diseases 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000015598 salt intake Nutrition 0.000 description 2
- 229910015645 LiMn Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000001075 voltammogram Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/04—Esters of boric acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/168—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19654057.7 | 1996-12-23 | ||
| DE19654057A DE19654057C2 (de) | 1996-12-23 | 1996-12-23 | Verfahren zur Verbesserung der Leistungsdichte von Lithium-Sekundärbatterien |
| PCT/DE1997/002974 WO1998028807A1 (de) | 1996-12-23 | 1997-12-19 | Verfahren und anode zur verbesserung der leistungsdichte von lithiumsekundärbatterien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001506799A true JP2001506799A (ja) | 2001-05-22 |
Family
ID=7816040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52822998A Pending JP2001506799A (ja) | 1996-12-23 | 1997-12-19 | リチウム二次電池の出力密度改善方法およびアノード（負極） |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0948826A1 (ru) |
| JP (1) | JP2001506799A (ru) |
| KR (1) | KR20000062304A (ru) |
| AU (1) | AU731463B2 (ru) |
| BR (1) | BR9714165A (ru) |
| CA (1) | CA2275969A1 (ru) |
| DE (1) | DE19654057C2 (ru) |
| IL (1) | IL130566A0 (ru) |
| RU (1) | RU2175798C2 (ru) |
| WO (1) | WO1998028807A1 (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012064456A (ja) * | 2010-09-16 | 2012-03-29 | Toyota Central R&D Labs Inc | リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6150053A (en) * | 1997-06-06 | 2000-11-21 | Matsushita Electric Industrial Co., Ltd. | Non-aqueous electrolyte secondary battery |
| DE19910968A1 (de) | 1999-03-12 | 2000-11-09 | Merck Patent Gmbh | Anwendung von Additiven in Elektrolyten für elektrochemische Zellen |
| KR100553736B1 (ko) * | 1999-09-02 | 2006-02-20 | 삼성에스디아이 주식회사 | 리튬 2차 전지용 활물질 조성물 |
| US7527899B2 (en) | 2000-06-16 | 2009-05-05 | Arizona Board Of Regents For And On Behalf Of Arizona State University | Electrolytic orthoborate salts for lithium batteries |
| WO2001096446A1 (en) | 2000-06-16 | 2001-12-20 | Arizona Board Of Regents, A Body Corporate Acting On Behalf Of Arizona State University | Conductive polymeric compositions for lithium batteries |
| EP1197494A3 (en) * | 2000-09-21 | 2004-05-26 | Kanto Kagaku Kabushiki Kaisha | New organic borate compounds and the nonaqueous electrolytes and lithium secondary batteries using the compounds |
| CN102964369B (zh) * | 2012-10-24 | 2016-04-06 | 中国科学院青岛生物能源与过程研究所 | 一类聚合物型硼酸酯锂盐及其制备方法和应用 |
| CN104183867B (zh) * | 2014-08-12 | 2018-06-19 | 中国科学院青岛生物能源与过程研究所 | 一种单离子导体纳米颗粒增强锂电池隔膜或聚合物电解质的制备方法和应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU527775A1 (ru) * | 1975-02-03 | 1976-09-05 | Предприятие П/Я В-2763 | Способ изготовлени пористого электрода дл химического источника тока с неводным электролитом |
| US4195120A (en) * | 1978-11-03 | 1980-03-25 | P. R. Mallory & Co. Inc. | Hydrogen evolution inhibitors for cells having zinc anodes |
| JPH0448709A (ja) * | 1990-06-15 | 1992-02-18 | Japan Carlit Co Ltd:The | 固体電解コンデンサの製造方法 |
| WO1994018714A1 (en) * | 1993-02-12 | 1994-08-18 | Valence Technology, Inc. | Electrodes for rechargeable lithium batteries |
| DE4316104A1 (de) * | 1993-05-13 | 1994-11-17 | Manfred Wuehr | Elektrolyt zur Anwendung in einer galvanischen Zelle |
| EP0631340B1 (en) * | 1993-06-18 | 2001-11-21 | Hitachi Maxell Ltd. | Organic electrolytic solution cell |
| JP3208243B2 (ja) * | 1993-11-18 | 2001-09-10 | 三洋電機株式会社 | 非水系電池 |
| US5597663A (en) * | 1995-05-30 | 1997-01-28 | Motorola, Inc. | Low temperature molten lithium salt electrolytes for electrochemical cells |
| DE19633027A1 (de) * | 1996-08-16 | 1998-02-19 | Merck Patent Gmbh | Verfahren zur Herstellung von neuen Lithium-Borat-Komplexen |
-
1996
- 1996-12-23 DE DE19654057A patent/DE19654057C2/de not_active Expired - Fee Related
-
1997
- 1997-12-19 CA CA002275969A patent/CA2275969A1/en not_active Abandoned
- 1997-12-19 BR BR9714165-8A patent/BR9714165A/pt unknown
- 1997-12-19 JP JP52822998A patent/JP2001506799A/ja active Pending
- 1997-12-19 IL IL13056697A patent/IL130566A0/xx unknown
- 1997-12-19 KR KR1019997005724A patent/KR20000062304A/ko not_active Withdrawn
- 1997-12-19 WO PCT/DE1997/002974 patent/WO1998028807A1/de not_active Application Discontinuation
- 1997-12-19 RU RU99116263/09A patent/RU2175798C2/ru active
- 1997-12-19 AU AU57484/98A patent/AU731463B2/en not_active Ceased
- 1997-12-19 EP EP97953650A patent/EP0948826A1/de not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012064456A (ja) * | 2010-09-16 | 2012-03-29 | Toyota Central R&D Labs Inc | リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20000062304A (ko) | 2000-10-25 |
| RU2175798C2 (ru) | 2001-11-10 |
| EP0948826A1 (de) | 1999-10-13 |
| AU731463B2 (en) | 2001-03-29 |
| WO1998028807A1 (de) | 1998-07-02 |
| AU5748498A (en) | 1998-07-17 |
| CA2275969A1 (en) | 1998-07-02 |
| IL130566A0 (en) | 2000-06-01 |
| DE19654057A1 (de) | 1998-06-25 |
| DE19654057C2 (de) | 2001-06-21 |
| BR9714165A (pt) | 2002-01-02 |
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