IL46108A - Optically active 1,2-bis(disubstituted phosphino) ethane compounds,catalysts comprising them and asymmetric hydrogen-ation of -substituted - -acylamidoacrylic acids in the presence of these catalysts - Google Patents

Optically active 1,2-bis(disubstituted phosphino) ethane compounds,catalysts comprising them and asymmetric hydrogen-ation of -substituted - -acylamidoacrylic acids in the presence of these catalysts

Info

Publication number: IL46108A
Authority: IL; Israel
Prior art keywords: catalysts; ation; bis; substituted; optically active
Prior art date: 1973-12-03

Application number

IL7446108A

Other languages

English (en)

Other versions

IL46108A0 (en

Original Assignee

Monsanto Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-12-03

Filing date

1974-11-22

Publication date

1978-10-31

1974-11-22 Application filed by Monsanto Co filed Critical Monsanto Co

1975-02-10 Publication of IL46108A0 publication Critical patent/IL46108A0/xx

1978-10-31 Publication of IL46108A publication Critical patent/IL46108A/xx

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

IL7446108A 1973-12-03 1974-11-22 Optically active 1,2-bis(disubstituted phosphino) ethane compounds,catalysts comprising them and asymmetric hydrogen-ation of -substituted - -acylamidoacrylic acids in the presence of these catalysts IL46108A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US42146373A	1973-12-03	1973-12-03
US05/514,987 US4008281A (en)	1973-12-03	1974-10-15	Asymmetric catalysis

Publications (2)

Publication Number	Publication Date
IL46108A0 IL46108A0 (en)	1975-02-10
IL46108A true IL46108A (en)	1978-10-31

Family

ID=27025254

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL7446108A IL46108A (en)	1973-12-03	1974-11-22	Optically active 1,2-bis(disubstituted phosphino) ethane compounds,catalysts comprising them and asymmetric hydrogen-ation of -substituted - -acylamidoacrylic acids in the presence of these catalysts

Country Status (23)

Country	Link
US (2)	US4008281A (no)
JP (1)	JPS5410352B2 (no)
BE (1)	BE822848A (no)
BR (1)	BR7410074A (no)
CA (1)	CA1051912A (no)
CH (1)	CH601142A5 (no)
DE (2)	DE2463010C2 (no)
DK (3)	DK139873B (no)
FI (2)	FI60215C (no)
FR (1)	FR2253026B1 (no)
GB (1)	GB1466803A (no)
HU (1)	HU172991B (no)
IL (1)	IL46108A (no)
IN (2)	IN145549B (no)
IT (1)	IT1026717B (no)
MX (3)	MX149399A (no)
NL (1)	NL166692C (no)
NO (2)	NO744324L (no)
PL (1)	PL107722B1 (no)
RO (1)	RO72485A (no)
SE (2)	SE421316B (no)
SU (1)	SU663273A3 (no)
YU (1)	YU318874A (no)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
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US4124533A (en) *	1971-03-08	1978-11-07	Monsanto Company	Metal coordination complexes containing optically active phosphine or arsine ligands
SU731892A3 (ru) *	1974-10-15	1980-04-30	Монсанто Компани (Фирма)	Способ получени оптических изомеров -замещенных -ациламидопропионовых кислот
US4515731A (en) *	1975-08-25	1985-05-07	Monsanto Company	Asymmetric catalysis
US4123465A (en) *	1975-10-16	1978-10-31	Hoffmann-La Roche Inc.	Chiral tertiary phosphines
US4166824A (en) *	1977-06-14	1979-09-04	American Cyanamid Company	Chiral rhodium-diphosphine catalyst capable of catalytic reduction of a tetramisole precursor to give a significant excess of the desired S-(-)isomer, levamisole
US4120870A (en) *	1977-07-18	1978-10-17	Hoffmann-La Roche Inc.	Metal phosphine complex
IT1087963B (it) *	1977-10-17	1985-06-04	Snam Progetti	Idrogenazione asimmetrica di olefine prochirali mediante complessi di metalli di transazione immobilizzati in minerali argillosi.
ZA793744B (en) *	1978-07-24	1981-02-25	Merck & Co Inc	Z-2-acylamino-3-monsosubstituted propenoates
US4880793A (en) *	1978-07-24	1989-11-14	Merck & Co., Inc.	Combination of thienamycin-type antibiotics with dipeptidase inhibitors
US5147868A (en) *	1978-07-24	1992-09-15	Merck & Co., Inc.	Thienamycin renal peptidase inhibitors
US4616038A (en) *	1978-07-24	1986-10-07	Merck & Co., Inc.	Combination of thienamycin-type antibiotics with dipeptidase inhibitors
EP0159460A1 (en) *	1979-02-12	1985-10-30	Exxon Research And Engineering Company	A hydroformylation catalyst and process
US4302401A (en) *	1980-01-23	1981-11-24	Exxon Research & Engineering Co.	Tetraalkyl phosphonium substituted phosphine and amine transition metal complexes
US4204997A (en) *	1979-03-19	1980-05-27	Monsanto Company	Asymmetric amination of 1,3-dienes
US4539208A (en) *	1980-09-17	1985-09-03	Merck & Co., Inc.	Combination of thienamycin-type antibiotics with dipeptidase inhibitors
DE3000445C2 (de) *	1980-01-08	1982-12-02	Degussa Ag, 6000 Frankfurt	Rhodiumkomplexe und deren Verwendung
US4473505A (en) *	1980-02-12	1984-09-25	Exxon Research And Engineering Co.	Phosphine and phosphonium compounds and catalysts
US4331818A (en) *	1980-03-19	1982-05-25	The Procter & Gamble Company	Chiral phospine ligand
DE3018388A1 (de) *	1980-05-14	1981-11-19	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung von optisch aktiven verbindungen und deren verwendung zur herstellung von vitamin e
DE3039053C2 (de) *	1980-10-16	1984-05-24	Degussa Ag, 6000 Frankfurt	Verfahren zur Herstellung von Dipeptiden
US4376870A (en) *	1980-12-05	1983-03-15	Monsanto Company	Optically active phosphine compounds
US4343741A (en) *	1981-04-22	1982-08-10	Hoffmann-La Roche Inc.	Chiral phosphines
US4393240A (en) *	1981-07-06	1983-07-12	Stille John K	Optically active phosphines
US4422975A (en) *	1981-08-03	1983-12-27	Exxon Research And Engineering Co.	Organic salt compositions in extraction processes
US4440634A (en) *	1981-08-03	1984-04-03	Exxon Research And Engineering Co.	Organic salt compositions in extraction processes
US4359596A (en) *	1981-08-03	1982-11-16	Exxon Research And Engineering Co.	Liquid salt extraction of aromatics from process feed streams
JPS5849179A (ja) *	1981-09-17	1983-03-23	ブラザー工業株式会社	２本針ミシンの制御装置
JPS6061587A (ja) *	1983-09-16	1985-04-09	Takasago Corp	ロジウム−ホスフイン錯体
US4857549A (en) *	1984-02-01	1989-08-15	Smithkline Beckman Corporation	Antitumor compounds
US4766226A (en) *	1984-02-01	1988-08-23	Smithkline Beckman Corporation	Antitumor pharmaceutical compositions and methods for treating tumors employing α,ω-bis(disubstitutedphosphino)hydrocarbon derivatives or [α, ω-bis(disubstitutedphosphino)hydrocarbon] di
JPS6163690A (ja) *	1984-09-04	1986-04-01	Takasago Corp	ルテニウム−ホスフイン錯体
US5011995A (en) *	1987-07-28	1991-04-30	Ciba-Geigy Corporation	Process for the preparation of optically active secondary amines
US4912221A (en) *	1988-10-27	1990-03-27	Occidental Chemical Corporation	Chiral 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid and precursors and preparation thereof
JPH0623150B2 (ja) *	1988-11-15	1994-03-30	高砂香料工業株式会社	光学活性３−ヒドロキシブタン酸類の製造方法
US5202474A (en) *	1989-06-22	1993-04-13	Monsanto Company	Asymmetric catalytic hydrogenation of α-arylpropenoic acids
US5198561A (en) *	1989-06-22	1993-03-30	Monsanto Company	Ruthenium-BINAP asymmetric hydrogenation catalyst
US5233084A (en) *	1989-06-22	1993-08-03	Monsanto Company	Method for preparing α-arylpropionic acids
ES2106104T3 (es) *	1991-05-03	1997-11-01	Hoechst Ag	Procedimiento para la sintesis enantioselectiva de derivados de monoamida de acido 2(r)-bencilsuccinico.
US5744655A (en) *	1996-06-19	1998-04-28	The Dow Chemical Company	Process to make 2,3-dihalopropanols
JP2972887B1 (ja) *	1998-10-29	1999-11-08	千葉大学長	光学活性ビスホスフィノメタン並びにそれらのロジウム又は銅錯体を用いる不斉合成
GB9823716D0 (en)	1998-10-29	1998-12-23	Isis Innovation	Diphosphines
US6350922B1 (en)	1998-12-18	2002-02-26	The Dow Chemical Company	Process for making 2,3-dihalopropanols
GB0004297D0 (en)	2000-02-23	2000-04-12	Ucb Sa	2-oxo-1 pyrrolidine derivatives process for preparing them and their uses
FR2887253A1 (fr) *	2005-06-20	2006-12-22	Phosphoenix Sarl	Nouvelles arylphosphines p chirales ortho-fonctionnalisees et derives: leur preparation et utilisation en catalyse asymetrique
GB0707379D0 (en) *	2007-03-28	2007-05-23	Celtic Catalysts Ltd	Chiral phosphorus compounds
EP3801897A4 (en) *	2018-06-08	2022-06-08	Board of Supervisors of Louisiana State University and Agricultural and Mechanical College	Catalyst compositions for hydroformylation and methods of use thereof
CN110396072B (zh) *	2019-09-02	2022-09-13	上海欣海健伟实业有限公司	(s)-3-羟基四氢呋喃的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL276543A (no) *	1961-03-29	1900-01-01
US3145227A (en) *	1961-06-14	1964-08-18	American Cyanamid Co	Organic phosphine oxides and methods of preparing same
US3849480A (en) *	1968-09-09	1974-11-19	Monsanto Co	Catalytic asymmetric hydrogenation
US3657298A (en) *	1970-01-06	1972-04-18	Pressure Chemical Co	Arsenic and phosphorus containing polydentates
NL155004B (nl)	1970-05-11	1977-11-15	Monsanto Co	Werkwijze voor het asymmetrisch hydrogeneren van een eventieel beta-gesubstitueerd alfa-acylaminoacrylzuur en/of een zout daarvan, alsmede werkwijze voor de bereiding van een katalysatoroplossing.
FR2116905A5 (fr) *	1970-12-10	1972-07-21	Inst Francais Du Petrole	Nouveaux coordinats bidentes,leur fabrication et leurs applications
US4124533A (en) *	1971-03-08	1978-11-07	Monsanto Company	Metal coordination complexes containing optically active phosphine or arsine ligands
US3780112A (en) *	1972-08-09	1973-12-18	Union Carbide Corp	Substituted ethylene bis(phosphine oxides)
FR2230654B1 (no) *	1973-05-21	1975-11-21	Rhone Poulenc Ind

1974
- 1974-10-15 US US05/514,987 patent/US4008281A/en not_active Expired - Lifetime
- 1974-11-22 IL IL7446108A patent/IL46108A/xx unknown
- 1974-11-29 NL NL7415583.A patent/NL166692C/xx not_active IP Right Cessation
- 1974-12-02 NO NO744324A patent/NO744324L/no unknown
- 1974-12-02 MX MX170589A patent/MX149399A/es unknown
- 1974-12-02 JP JP13708774A patent/JPS5410352B2/ja not_active Expired
- 1974-12-02 DK DK625274AA patent/DK139873B/da not_active IP Right Cessation
- 1974-12-02 FR FR7439420A patent/FR2253026B1/fr not_active Expired
- 1974-12-02 MX MX170590A patent/MX148257A/es unknown
- 1974-12-02 FI FI3487/74A patent/FI60215C/fi active
- 1974-12-02 HU HU74MO00000927A patent/HU172991B/hu unknown
- 1974-12-02 DE DE2463010A patent/DE2463010C2/de not_active Expired
- 1974-12-02 CH CH1593974A patent/CH601142A5/xx not_active IP Right Cessation
- 1974-12-02 BR BR10074/74A patent/BR7410074A/pt unknown
- 1974-12-02 PL PL1974176129A patent/PL107722B1/pl unknown
- 1974-12-02 MX MX742888U patent/MX5144E/es unknown
- 1974-12-02 GB GB5201774A patent/GB1466803A/en not_active Expired
- 1974-12-02 RO RO7480666A patent/RO72485A/ro unknown
- 1974-12-02 CA CA215,181A patent/CA1051912A/en not_active Expired
- 1974-12-02 YU YU03188/74A patent/YU318874A/xx unknown
- 1974-12-02 SE SE7415029A patent/SE421316B/xx unknown
- 1974-12-02 BE BE151066A patent/BE822848A/xx not_active IP Right Cessation
- 1974-12-02 DE DE2456937A patent/DE2456937C3/de not_active Expired
- 1974-12-02 IT IT3008774A patent/IT1026717B/it active
1975
- 1975-08-21 SU SU752163234A patent/SU663273A3/ru active
1976
- 1976-06-03 DK DK245376A patent/DK245376A/da not_active Application Discontinuation
- 1976-06-03 DK DK245476A patent/DK245476A/da not_active Application Discontinuation
1977
- 1977-06-27 IN IN957/CAL/77A patent/IN145549B/en unknown
- 1977-06-27 IN IN958/CAL/77A patent/IN145550B/en unknown
1978
- 1978-07-31 US US05/929,635 patent/US4220590A/en not_active Expired - Lifetime
1980
- 1980-07-03 NO NO802008A patent/NO802008L/no unknown
- 1980-07-17 FI FI802271A patent/FI63216C/fi not_active IP Right Cessation
1981
- 1981-08-21 SE SE8104949A patent/SE8104949L/sv not_active Application Discontinuation

Also Published As

Publication number	Publication date
DK625274A (no)	1975-07-28
FR2253026A1 (no)	1975-06-27
BR7410074A (pt)	1976-06-08
JPS50113489A (no)	1975-09-05
CA1051912A (en)	1979-04-03
RO72485A (ro)	1982-12-06
DK245476A (da)	1976-06-03
IT1026717B (it)	1978-10-20
IN145550B (no)	1978-11-04
NL166692B (nl)	1981-04-15
DE2456937B2 (de)	1980-09-04
IL46108A0 (en)	1975-02-10
HU172991B (hu)	1979-01-28
SE421316B (sv)	1981-12-14
SU663273A3 (ru)	1979-05-15
AU7594574A (en)	1976-06-03
FI63216B (fi)	1983-01-31
DE2456937A1 (de)	1975-06-26
GB1466803A (en)	1977-03-09
DE2463010C2 (de)	1982-11-25
YU318874A (en)	1982-10-31
FI63216C (fi)	1983-05-10
DK139873C (no)	1979-10-01
CH601142A5 (no)	1978-06-30
DK139873B (da)	1979-05-07
US4008281A (en)	1977-02-15
FI348774A (no)	1975-06-04
PL107722B1 (pl)	1980-02-29
MX5144E (es)	1983-04-04
FI60215C (fi)	1981-12-10
JPS5410352B2 (no)	1979-05-04
IN145549B (no)	1978-11-04
FI60215B (fi)	1981-08-31
BE822848A (fr)	1975-06-02
NL7415583A (nl)	1975-06-05
MX149399A (es)	1983-11-03
SE7415029L (no)	1975-06-04
DK245376A (da)	1976-06-03
MX148257A (es)	1983-04-04
NL166692C (nl)	1981-09-15
DE2456937C3 (de)	1981-07-16
NO802008L (no)	1975-06-04
NO744324L (no)	1975-06-30
FR2253026B1 (no)	1978-05-05
US4220590A (en)	1980-09-02
FI802271A (fi)	1980-07-17
SE8104949L (sv)	1981-08-21

Publication	Publication Date	Title
IL46108A (en)	1978-10-31	Optically active 1,2-bis(disubstituted phosphino) ethane compounds,catalysts comprising them and asymmetric hydrogen-ation of -substituted - -acylamidoacrylic acids in the presence of these catalysts
IL39444A0 (en)	1972-07-26	1,4-dihydro-4-oxo-3-quinoline-carboxylic acids and esters and their preparation
IL49234A0 (en)	1976-05-31	Novel cyclopropane-1,1-dicarboxylic acid derivatives and their preparation
IT1026993B (it)	1978-10-20	Processo per la preparazione di catalizzatori di polimerizzazione e catalizzatori cosi ottenuti
IT1017323B (it)	1977-07-20	Processo per la preparazione di 1.3 dichetoni aromatici
NL7412596A (nl)	1975-04-22	Gecombineerde huidverzorgingsmiddelen.
IT1049285B (it)	1981-01-20	Processo per preparare 2 fenil as triazine 3.5 2h.4h dioni e relativi prodotti
IT1051204B (it)	1981-04-21	L.norleucina 13 motilina,procedimento per la sua preparazione e prodotto contenente la stessa
ZA722318B (en)	1972-12-27	New amino alcohols derived from ortho trans-hydroxycinnamic acids,their esters and their amides
IT1000182B (it)	1976-03-30	Procedimento e catalizzatore per produrre 3 alogeno oppure 3, 5, dialogenofenoli
EP0018976A4 (fr)	1981-11-11	Hydrolysat de proteines a usage medical et son procede d'utilisation.
CA1002057A (fr)	1976-12-21	Catalyseurs perfectionnes de dimerisation de diolefines
IL45566A0 (en)	1974-11-29	Novel 2,3-dihydrobenzofuranyl-7-n-methylcarbamates,their preparation and their use as insecticides
IT953846B (it)	1973-08-10	Procedimento per la preparazione di metacrilonitrile da isobutene ammoniaca e ossigeno in presenza di catalizzatori
CA936546A (en)	1973-11-06	Rhodium based catalysts for the synthesis of 1,4-dienes
IT1004174B (it)	1976-07-10	Catalizzatore e procedimento per produrre i.3 di clorobutene 2
TR18053A (tr)	1976-09-23	O-etil-s, n-propil-o-/piridaz- (3)-on-6-il/tiono-fiolfosforik asid esterler, bunlarin en hazirlanmasina mahsus usul ve bunlarin en sektisidler ve akarisidler olarak kullanilmalari
IT1007342B (it)	1976-10-30	Acidi 1.3.5.7 naftalen tetracar bossilici e procedimento per pre pararli
ZA744354B (en)	1975-11-26	Novel amino acids, and their production and use
IL39114A0 (en)	1972-05-30	Novel cyanopyrazines carbamoyl diaminopyrazines,and 3,5-diaminopyrazinoic acid,and their preparation
IT995056B (it)	1975-11-10	Procedimento per la preparazione di metacroleina da isobutene e ossigeno in presenza di catalizza tori
AU7035674A (en)	1976-01-08	Prosta-5-cis, 11,13-trans-trienoic acids
IL36685A0 (en)	1971-06-23	5-sulphamoyl-1,3,4-thiadiazolyl-(2)-ureas,their production and their use as herbicides
BE791949A (fr)	1973-05-28	Derives d'insuline, leur preparation et leur utilisation
CH537211A (it)	1973-05-31	Procedimento per la preparazione di catalizzatori per l'ossiclorurazione