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HUP0100366A2 - Etilén homopolimerei és kopolimerei - Google Patents

Etilén homopolimerei és kopolimerei

Info

Publication number
HUP0100366A2
HUP0100366A2 HU0100366A HUP0100366A HUP0100366A2 HU P0100366 A2 HUP0100366 A2 HU P0100366A2 HU 0100366 A HU0100366 A HU 0100366A HU P0100366 A HUP0100366 A HU P0100366A HU P0100366 A2 HUP0100366 A2 HU P0100366A2
Authority
HU
Hungary
Prior art keywords
polymers
homopolymers
ethylene
copolymers
density
Prior art date
Application number
HU0100366A
Other languages
English (en)
Inventor
Choon Kooi Chai
Original Assignee
Bp Chemicals Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chemicals Limited filed Critical Bp Chemicals Limited
Publication of HUP0100366A2 publication Critical patent/HUP0100366A2/hu
Publication of HUP0100366A3 publication Critical patent/HUP0100366A3/hu
Publication of HU224167B1 publication Critical patent/HU224167B1/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
  • Artificial Filaments (AREA)

Abstract

A találmány szerinti etilén homopolimereknek és kopolimekeknek szélesmolekulatömeg-eloszlásuk, kiváló szilárdságuk és javítottfeldolgozhatóságuk van. Ezeket a polimereket egy reaktoros, gázfázisúeljárásban, egy metallocénes katalizátorrendszer alkalmazásávalállítják elő. Ezek a tipikusan 0,85-0,95 g/cm3 sűrűségű polimerekkülönösen az olvadékellenállásukkal (MS) és a hosszú oldalláncúelágazásukkal (LCB) tűnnek ki és különösen alkalmasak az olyanalkalmazásokban, ahol kissűrűségű fóliaként használják. Ó
HU0100366A 1998-01-07 1999-01-05 Etilén homopolimerei és kopolimerei és alkalmazásuk HU224167B1 (hu)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9800245.4A GB9800245D0 (en) 1998-01-07 1998-01-07 Novel polymers
PCT/GB1999/000021 WO1999035174A1 (en) 1998-01-07 1999-01-05 Homopolymers and copolymers of ethylene

Publications (3)

Publication Number Publication Date
HUP0100366A2 true HUP0100366A2 (hu) 2001-06-28
HUP0100366A3 HUP0100366A3 (en) 2002-03-28
HU224167B1 HU224167B1 (hu) 2005-06-28

Family

ID=10824911

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0100366A HU224167B1 (hu) 1998-01-07 1999-01-05 Etilén homopolimerei és kopolimerei és alkalmazásuk

Country Status (31)

Country Link
US (2) US6518385B1 (hu)
EP (2) EP1443062B1 (hu)
JP (2) JP2002500249A (hu)
KR (1) KR100645271B1 (hu)
CN (1) CN1134463C (hu)
AR (1) AR014252A1 (hu)
AT (1) ATE269873T1 (hu)
AU (1) AU760130B2 (hu)
BR (1) BR9906811A (hu)
CA (1) CA2316165C (hu)
CO (1) CO4830472A1 (hu)
CZ (1) CZ302705B6 (hu)
DE (1) DE69918263T2 (hu)
DK (1) DK1045868T3 (hu)
DZ (1) DZ2704A1 (hu)
EG (1) EG22389A (hu)
ES (2) ES2224598T3 (hu)
GB (1) GB9800245D0 (hu)
HU (1) HU224167B1 (hu)
MY (1) MY122063A (hu)
NO (1) NO20003488L (hu)
PL (1) PL198209B1 (hu)
PT (1) PT1045868E (hu)
RU (1) RU2223283C2 (hu)
SA (1) SA99191234B1 (hu)
SK (1) SK10132000A3 (hu)
TR (1) TR200001955T2 (hu)
TW (1) TW557303B (hu)
UA (1) UA66375C2 (hu)
WO (1) WO1999035174A1 (hu)
ZA (1) ZA9811886B (hu)

Families Citing this family (38)

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GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers
GB9918668D0 (en) * 1999-08-06 1999-10-13 Bp Chem Int Ltd Polymerisation catalysts
AU782786B2 (en) * 1999-12-01 2005-08-25 Exxonmobil Chemical Patents Inc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
EP1108749A1 (en) * 1999-12-13 2001-06-20 Fina Research S.A. Medium density polyethylene compositions for film applications
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
KR100377287B1 (ko) * 2000-05-29 2003-03-26 삼성종합화학주식회사 에틸렌 중합 방법
AU2002211323A1 (en) * 2000-10-04 2002-04-15 Dow Global Technologies Inc. Supported catalyst compositions
US7132486B2 (en) 2000-10-06 2006-11-07 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
US6734265B1 (en) 2000-10-06 2004-05-11 Univation Technologies, Llc. Linear low density polyethylenes with high melt strength and high melt index ratio
US6884747B2 (en) * 2000-10-06 2005-04-26 Univation Technologies, Llc Linear low density polyethylenes with high melt strength and high melt index ratio
JP4903357B2 (ja) * 2003-03-28 2012-03-28 住友化学株式会社 エチレン重合体
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
JP5507048B2 (ja) * 2004-11-02 2014-05-28 ダウ グローバル テクノロジーズ エルエルシー 低密度ポリエチレン組成物の生成方法およびこれから生成されたポリマー
ES2340707T3 (es) 2005-02-09 2010-06-08 Ineos Europe Limited Copolimeros y peliculas de los mismos.
EP1845110A1 (en) * 2006-04-13 2007-10-17 Total Petrochemicals Research Feluy Chromium-based catalysts
WO2007118866A1 (en) * 2006-04-13 2007-10-25 Total Petrochemicals Research Feluy Branched low and medium density polyethylene
GB0610668D0 (en) * 2006-05-30 2006-07-12 Nova Chem Int Sa Supported antistatic polymerization catalysts
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
CN101711260B (zh) * 2007-05-16 2012-07-18 Lg化学株式会社 长链支化的乙烯-α烯烃共聚物
DE112008003204T5 (de) * 2007-11-30 2010-10-14 Sumitomo Chemical Company, Ltd. Ethylen-a-Olefin-Copolymer und Formgegenstand
JP5392015B2 (ja) * 2008-11-11 2014-01-22 住友化学株式会社 エチレン−α−オレフィン共重合体及び成形体
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
US8299194B2 (en) * 2009-05-29 2012-10-30 Sumitomo Chemical Company, Limited Ethylene-α-olefin copolymer and article
JP2010276128A (ja) * 2009-05-29 2010-12-09 Sumitomo Chemical Co Ltd チューブ
EP2348057A1 (en) 2010-01-21 2011-07-27 INEOS Manufacturing Belgium NV Novel polymers
CN103087240B (zh) * 2011-10-31 2015-07-22 中国石油化工股份有限公司 一种制备乙烯聚合物的方法
US9096700B2 (en) 2012-12-10 2015-08-04 Exxonmobil Chemical Patents Inc. Polymerization process for production of polymer
US9266977B2 (en) 2012-12-21 2016-02-23 Exxonmobil Chemical Patents Inc. Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
CN104822716B (zh) * 2012-12-21 2017-11-14 埃克森美孚化学专利公司 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜
KR101924198B1 (ko) 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
EP4428166A3 (en) * 2015-12-31 2024-12-11 Hanwha Chemical Corporation Hybrid supported metallocene catalyst, method for preparing olefin polymer by using same, and olefin polymer having improved melt strength
WO2018105852A1 (ko) * 2016-12-05 2018-06-14 주식회사 엘지화학 혼성 담지 촉매
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties

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FR2532649B1 (fr) * 1982-09-07 1986-08-29 Bp Chimie Sa Copolymerisation d'ethylene et d'hexene-1 en lit fluidise
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
CN1131953A (zh) * 1993-08-06 1996-09-25 埃克森化学专利公司 聚合催化剂及其制备和用途
DE69412576T3 (de) * 1993-12-21 2002-05-29 Univation Technologies,Llc Herstellung von Polyolefinen mit lankettiger Verzweigung nach einem Gasphaseverfahren
PT1134238E (pt) * 1994-04-07 2005-11-30 Innovene Europ Ltd Co-polimeros
US5616664A (en) * 1994-08-02 1997-04-01 The Dow Chemical Company Polymerization process with biscyclopentadienyl diene complex containing catalysts
ATE202367T1 (de) * 1994-09-07 2001-07-15 Dow Chemical Co Elastisches lineares polyethylenniedriger dichte
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UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
GB9800245D0 (en) * 1998-01-07 1998-03-04 Bp Chem Int Ltd Novel polymers

Also Published As

Publication number Publication date
DZ2704A1 (fr) 2003-09-01
GB9800245D0 (en) 1998-03-04
EP1045868A1 (en) 2000-10-25
BR9906811A (pt) 2000-10-10
US6518385B1 (en) 2003-02-11
UA66375C2 (uk) 2004-05-17
ES2486842T3 (es) 2014-08-19
EP1045868B1 (en) 2004-06-23
RU2223283C2 (ru) 2004-02-10
EP1443062B1 (en) 2014-05-07
SA99191234B1 (ar) 2006-11-14
ATE269873T1 (de) 2004-07-15
ES2224598T3 (es) 2005-03-01
CA2316165A1 (en) 1999-07-15
CZ20002454A3 (cs) 2001-04-11
TW557303B (en) 2003-10-11
DE69918263T2 (de) 2005-07-21
MY122063A (en) 2006-03-31
CA2316165C (en) 2008-12-30
PL198209B1 (pl) 2008-06-30
EP1443062A3 (en) 2004-10-20
AU760130B2 (en) 2003-05-08
US20030139551A1 (en) 2003-07-24
NO20003488D0 (no) 2000-07-06
KR100645271B1 (ko) 2006-11-13
CN1292802A (zh) 2001-04-25
CN1134463C (zh) 2004-01-14
KR20010033966A (ko) 2001-04-25
EP1443062A2 (en) 2004-08-04
JP2002500249A (ja) 2002-01-08
HU224167B1 (hu) 2005-06-28
HUP0100366A3 (en) 2002-03-28
SK10132000A3 (sk) 2001-07-10
CZ302705B6 (cs) 2011-09-14
AU2064099A (en) 1999-07-26
TR200001955T2 (tr) 2000-11-21
EG22389A (en) 2003-01-29
ZA9811886B (en) 2000-06-28
AR014252A1 (es) 2001-02-07
CO4830472A1 (es) 1999-08-30
DK1045868T3 (da) 2004-10-25
PT1045868E (pt) 2004-10-29
DE69918263D1 (de) 2004-07-29
NO20003488L (no) 2000-09-07
WO1999035174A1 (en) 1999-07-15
PL341677A1 (en) 2001-04-23
JP2010047776A (ja) 2010-03-04
JP5804485B2 (ja) 2015-11-04

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HFG4 Patent granted, date of granting

Effective date: 20050428

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Owner name: INEOS EUROPE LIMITED, GB

Free format text: FORMER OWNER(S): BP CHEMICALS LIMITED, GB; INEOS EUROPE LIMITED, GB

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Owner name: INEOS EUROPE LIMITED, GB

Free format text: FORMER OWNER(S): BP CHEMICALS LIMITED, GB; INEOS EUROPE LIMITED, GB

GB9A Succession in title

Owner name: INEOS SALES (UK) LIMITED, GB

Free format text: FORMER OWNER(S): BP CHEMICALS LIMITED, GB; INEOS EUROPE LIMITED, GB; INEOS EUROPE LIMITED, GB

MM4A Lapse of definitive patent protection due to non-payment of fees