HRP970411A2 - Process for the reductive post-cleaning of polyester-containing textiles - Google Patents
Process for the reductive post-cleaning of polyester-containing textilesInfo
- Publication number
- HRP970411A2 HRP970411A2 HR19629453.3A HRP970411A HRP970411A2 HR P970411 A2 HRP970411 A2 HR P970411A2 HR P970411 A HRP970411 A HR P970411A HR P970411 A2 HRP970411 A2 HR P970411A2
- Authority
- HR
- Croatia
- Prior art keywords
- acid
- mixture
- formula
- so3na
- compound
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 35
- 229920000728 polyester Polymers 0.000 title claims description 25
- 230000008569 process Effects 0.000 title claims description 19
- 238000004140 cleaning Methods 0.000 title claims description 16
- 239000004753 textile Substances 0.000 title claims description 15
- 230000002829 reductive effect Effects 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 claims description 89
- 150000001875 compounds Chemical class 0.000 claims description 40
- 239000000126 substance Substances 0.000 claims description 38
- 238000004043 dyeing Methods 0.000 claims description 29
- 239000002253 acid Substances 0.000 claims description 19
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 159000000000 sodium salts Chemical class 0.000 claims description 9
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 7
- GJEKKPWFVUNKRY-UHFFFAOYSA-N (5-methylheptylamino)methanesulfonic acid Chemical compound CCC(C)CCCCNCS(O)(=O)=O GJEKKPWFVUNKRY-UHFFFAOYSA-N 0.000 claims description 6
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 5
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- QJIJGXVUUWTYLH-UHFFFAOYSA-N (5-methylheptylamino)methanesulfinic acid Chemical compound CCC(C)CCCCNCS(O)=O QJIJGXVUUWTYLH-UHFFFAOYSA-N 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 229940079826 hydrogen sulfite Drugs 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 150000002016 disaccharides Chemical class 0.000 claims description 3
- 150000002431 hydrogen Chemical group 0.000 claims description 3
- 150000002772 monosaccharides Chemical class 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 3
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- CSABAZBYIWDIDE-UHFFFAOYSA-N sulfino hydrogen sulfite Chemical compound OS(=O)OS(O)=O CSABAZBYIWDIDE-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- -1 sodium Chemical class 0.000 description 40
- 150000003871 sulfonates Chemical class 0.000 description 29
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000004744 fabric Substances 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical compound [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- 150000001412 amines Chemical class 0.000 description 11
- 229910021529 ammonia Inorganic materials 0.000 description 11
- 239000000975 dye Substances 0.000 description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- 150000002460 imidazoles Chemical class 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 150000003141 primary amines Chemical class 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 5
- 238000012805 post-processing Methods 0.000 description 5
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 150000003335 secondary amines Chemical class 0.000 description 4
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- DETXZQGDWUJKMO-UHFFFAOYSA-N alpha-hydroxymethanesulfonic acid Natural products OCS(O)(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000986 disperse dye Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 235000011044 succinic acid Nutrition 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- WAVVZICBPYTVNH-UHFFFAOYSA-N 1-(2-ethylhexylamino)ethanesulfinic acid Chemical compound CCCCC(CC)CNC(C)S(O)=O WAVVZICBPYTVNH-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
- ODZTXUXIYGJLMC-UHFFFAOYSA-N 2-hydroxycyclohexan-1-one Chemical compound OC1CCCCC1=O ODZTXUXIYGJLMC-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- PFCHFHIRKBAQGU-UHFFFAOYSA-N 3-hexanone Chemical compound CCCC(=O)CC PFCHFHIRKBAQGU-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- IYTXKIXETAELAV-UHFFFAOYSA-N Nonan-3-one Chemical compound CCCCCCC(=O)CC IYTXKIXETAELAV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 2
- FCMYSEXCLRFWBP-UHFFFAOYSA-N [NH4+].[NH4+].[O-]S(=O)S([O-])=O Chemical compound [NH4+].[NH4+].[O-]S(=O)S([O-])=O FCMYSEXCLRFWBP-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- OBESRABRARNZJB-UHFFFAOYSA-N aminomethanesulfonic acid Chemical class NCS(O)(=O)=O OBESRABRARNZJB-UHFFFAOYSA-N 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000012084 conversion product Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- DETXZQGDWUJKMO-UHFFFAOYSA-M hydroxymethanesulfonate Chemical compound OCS([O-])(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-M 0.000 description 2
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 150000002482 oligosaccharides Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- 150000003557 thiazoles Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- TXPJTBDCFURIRT-UHFFFAOYSA-N (3-methylbutylamino)methanesulfonic acid Chemical compound CC(C)CCNCS(O)(=O)=O TXPJTBDCFURIRT-UHFFFAOYSA-N 0.000 description 1
- HORGLPJINHGKKB-UHFFFAOYSA-N (3-methylpentylamino)methanesulfonic acid Chemical compound CCC(C)CCNCS(O)(=O)=O HORGLPJINHGKKB-UHFFFAOYSA-N 0.000 description 1
- GTCRFAWAOGUDTN-UHFFFAOYSA-N (4-methylhexylamino)methanesulfonic acid Chemical compound CCC(C)CCCNCS(O)(=O)=O GTCRFAWAOGUDTN-UHFFFAOYSA-N 0.000 description 1
- NCNKWVDSURNKKG-UHFFFAOYSA-N (4-methylpentylamino)methanesulfonic acid Chemical compound CC(C)CCCNCS(O)(=O)=O NCNKWVDSURNKKG-UHFFFAOYSA-N 0.000 description 1
- UYEJOLWHHPDBOH-UHFFFAOYSA-N (6-methylheptylamino)methanesulfonic acid Chemical compound CC(C)CCCCCNCS(O)(=O)=O UYEJOLWHHPDBOH-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WCYHCFGPLSCBHH-UHFFFAOYSA-N (cyclohexylamino)methanesulfinic acid Chemical class OS(=O)CNC1CCCCC1 WCYHCFGPLSCBHH-UHFFFAOYSA-N 0.000 description 1
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- 150000007979 thiazole derivatives Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- ULIAPOFMBCCSPE-UHFFFAOYSA-N tridecan-7-one Chemical compound CCCCCCC(=O)CCCCCC ULIAPOFMBCCSPE-UHFFFAOYSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- 238000004048 vat dyeing Methods 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/13—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
- C07C309/14—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton containing amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/07—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
- C07C309/08—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing hydroxy groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C313/02—Sulfinic acids; Derivatives thereof
- C07C313/04—Sulfinic acids; Esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/922—Polyester fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Coloring (AREA)
- Paper (AREA)
- Polyesters Or Polycarbonates (AREA)
- Removal Of Specific Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19629453A DE19629453A1 (de) | 1996-07-23 | 1996-07-23 | Verfahren zur reduktiven Nachreinigung von polyesterhaltigen Textilien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP970411A2 true HRP970411A2 (en) | 1998-08-31 |
Family
ID=7800449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HR19629453.3A HRP970411A2 (en) | 1996-07-23 | 1997-07-22 | Process for the reductive post-cleaning of polyester-containing textiles |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6730132B1 (xx) |
| EP (1) | EP0914516B1 (xx) |
| JP (1) | JP2000514879A (xx) |
| KR (1) | KR20000067955A (xx) |
| CN (1) | CN1106479C (xx) |
| AR (1) | AR007950A1 (xx) |
| AU (1) | AU3695097A (xx) |
| BR (1) | BR9710492A (xx) |
| CZ (1) | CZ18899A3 (xx) |
| DE (2) | DE19629453A1 (xx) |
| ES (1) | ES2208933T3 (xx) |
| HK (1) | HK1022002A1 (xx) |
| HR (1) | HRP970411A2 (xx) |
| ID (1) | ID17642A (xx) |
| TR (1) | TR199900116T2 (xx) |
| TW (1) | TW482840B (xx) |
| WO (1) | WO1998003725A1 (xx) |
| ZA (1) | ZA976464B (xx) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19940068A1 (de) * | 1999-08-24 | 2001-03-01 | Basf Ag | Verfahren zum Aufhellen von gefärbtem Textilmaterial |
| US6780205B2 (en) | 2001-08-21 | 2004-08-24 | E. I. Du Pont De Nemours And Company | Vat acid dyeing of textile fibers |
| DE10211292A1 (de) | 2002-03-14 | 2003-09-25 | Basf Ag | Verfahren zur Herstellung von gefälltem Calciumcarbonat mit hohem Weißgrad |
| DE10222978A1 (de) * | 2002-05-23 | 2003-12-04 | Basf Ag | Verfahren zur reduktiven Nachreinigung von textilen Materialien |
| US6942706B2 (en) | 2002-08-20 | 2005-09-13 | Invista North America S.A.R.L. | Vat acid dyeing of textile fibers |
| CN1302174C (zh) * | 2004-11-01 | 2007-02-28 | 上海市印染技术研究所 | 纺织品白地防沾污洗涤剂 |
| EP1984559A1 (en) * | 2006-02-17 | 2008-10-29 | Huntsman Advanced Materials (Switzerland) GmbH | Process for dyeing polyester |
| CN102586038B (zh) * | 2011-12-28 | 2013-08-21 | 浙江台华新材料股份有限公司 | 高耐皂洗色牢度和高升华牢度织物还原洗清洗剂、其制备方法及涤纶织物处理方法 |
| CN102535164B (zh) * | 2011-12-28 | 2014-09-03 | 浙江台华新材料股份有限公司 | 高耐皂洗色牢度和高升华牢度涤纶织物三防整理方法、整理剂及整理剂制备方法 |
| DE102014225545A1 (de) * | 2014-12-11 | 2016-06-16 | Henkel Ag & Co. Kgaa | "Verbesserte Entfärbung von gefärbten keratinischen Fasern" |
| DE102015210751A1 (de) | 2015-06-12 | 2016-12-15 | Henkel Ag & Co. Kgaa | Emulsionen zur verbesserten reduktiven Entfärbung keratinischer Fasern |
| DE102015222216A1 (de) | 2015-11-11 | 2017-05-11 | Henkel Ag & Co. Kgaa | Reduktiver Farbabzug mit Sulfinsäure-Derviaten in Pastenform |
| DE102015222215A1 (de) | 2015-11-11 | 2017-05-11 | Henkel Ag & Co. Kgaa | Verbesserte Entfärbung von gefärbten keratinischen Fasern |
| DE102015222214A1 (de) | 2015-11-11 | 2017-05-11 | Henkel Ag & Co. Kgaa | Verbesserte Entfärbung von gefärbten keratinischen Fasern |
| DE102016209981A1 (de) | 2016-06-07 | 2017-12-07 | Henkel Ag & Co. Kgaa | "Mehrkomponenten-Verpackungseinheit und Verfahren für die reduktive Entfärbung von gefärbten keratinischen Fasern" |
| DE102016209980A1 (de) | 2016-06-07 | 2017-12-07 | Henkel Ag & Co. Kgaa | "Nachbehandlungsmittel für die reduktive Entfärbung von gefärbten keratinischen Fasern" |
| CN107447543A (zh) * | 2017-09-02 | 2017-12-08 | 浙江爱利斯染整有限公司 | 一种中深色布料的染整工艺 |
| DE102017216611A1 (de) | 2017-09-19 | 2019-03-21 | Henkel Ag & Co. Kgaa | Verbesserte Entfärbung von gefärbten keratinischen Fasern |
| JP7209810B2 (ja) * | 2019-03-27 | 2023-01-20 | 日華化学株式会社 | 液状還元剤組成物及び還元洗浄方法 |
| KR102347915B1 (ko) * | 2019-08-06 | 2022-01-07 | 진주현 | 염색 세척용 환원세정제 조성물 및 이의 제조방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1619501A1 (de) * | 1967-01-03 | 1970-09-10 | Bayer Ag | Faerbereihilfsmittel |
| CH619587B (de) * | 1977-02-04 | Sandoz Ag | Verfahren zum faerben oder bedrucken von polyester/cellulosefaser mischungen. | |
| DE2744607C2 (de) * | 1977-10-04 | 1979-11-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Nachbehandeln von gefärbten oder bedruckten Synthesefasern |
| US4227881A (en) * | 1978-11-17 | 1980-10-14 | Royce Chemical Company | New process of color stripping dyed textile fabric |
| DE3113732A1 (de) * | 1981-04-04 | 1982-10-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zum bedrucken von synthesefasern |
| JPH0291285A (ja) * | 1988-09-21 | 1990-03-30 | Sanyo Chem Ind Ltd | ソーピング剤および処理法 |
| JPH05272075A (ja) * | 1991-05-22 | 1993-10-19 | Nagase & Co Ltd | ポリエステル／ナイロン混紡品の一浴染色法 |
| CN1178851A (zh) * | 1996-09-20 | 1998-04-15 | 希巴特殊化学控股公司 | 疏水纤维材料防染印花法 |
-
1996
- 1996-07-23 DE DE19629453A patent/DE19629453A1/de not_active Withdrawn
-
1997
- 1997-07-14 WO PCT/EP1997/003753 patent/WO1998003725A1/de not_active Application Discontinuation
- 1997-07-14 BR BR9710492A patent/BR9710492A/pt not_active IP Right Cessation
- 1997-07-14 CN CN97196716A patent/CN1106479C/zh not_active Expired - Fee Related
- 1997-07-14 JP JP10506517A patent/JP2000514879A/ja not_active Ceased
- 1997-07-14 AU AU36950/97A patent/AU3695097A/en not_active Abandoned
- 1997-07-14 KR KR1019997000450A patent/KR20000067955A/ko active IP Right Grant
- 1997-07-14 TR TR1999/00116T patent/TR199900116T2/xx unknown
- 1997-07-14 DE DE59710814T patent/DE59710814D1/de not_active Expired - Fee Related
- 1997-07-14 CZ CZ99188A patent/CZ18899A3/cs unknown
- 1997-07-14 ES ES97933676T patent/ES2208933T3/es not_active Expired - Lifetime
- 1997-07-14 EP EP97933676A patent/EP0914516B1/de not_active Expired - Lifetime
- 1997-07-22 ID IDP972547A patent/ID17642A/id unknown
- 1997-07-22 AR ARP970103278A patent/AR007950A1/es not_active Application Discontinuation
- 1997-07-22 HR HR19629453.3A patent/HRP970411A2/hr not_active Application Discontinuation
- 1997-07-22 ZA ZA976464A patent/ZA976464B/xx unknown
- 1997-07-22 TW TW086110378A patent/TW482840B/zh not_active IP Right Cessation
-
1999
- 1999-01-22 US US10/048,029 patent/US6730132B1/en not_active Expired - Fee Related
-
2000
- 2000-02-11 HK HK00100817A patent/HK1022002A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1106479C (zh) | 2003-04-23 |
| TW482840B (en) | 2002-04-11 |
| CN1226298A (zh) | 1999-08-18 |
| ES2208933T3 (es) | 2004-06-16 |
| JP2000514879A (ja) | 2000-11-07 |
| CZ18899A3 (cs) | 1999-11-17 |
| WO1998003725A1 (de) | 1998-01-29 |
| ID17642A (id) | 1998-01-15 |
| EP0914516A1 (de) | 1999-05-12 |
| US6730132B1 (en) | 2004-05-04 |
| DE19629453A1 (de) | 1998-01-29 |
| HK1022002A1 (en) | 2000-07-21 |
| DE59710814D1 (de) | 2003-11-06 |
| TR199900116T2 (xx) | 1999-04-21 |
| EP0914516B1 (de) | 2003-10-01 |
| AR007950A1 (es) | 1999-11-24 |
| AU3695097A (en) | 1998-02-10 |
| BR9710492A (pt) | 1999-08-17 |
| KR20000067955A (ko) | 2000-11-25 |
| ZA976464B (en) | 1999-01-22 |
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| Date | Code | Title | Description |
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| A1OB | Publication of a patent application | ||
| AIPI | Request for the grant of a patent on the basis of a substantive examination of a patent application | ||
| ODRP | Renewal fee for the maintenance of a patent |
Payment date: 20030721 Year of fee payment: 7 |
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| ODBC | Application rejected |