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GB998880A - Process for gasification of liquid hydrocarbons to hydrogen and carbon monoxide - Google Patents

Process for gasification of liquid hydrocarbons to hydrogen and carbon monoxide

Info

Publication number
GB998880A
GB998880A GB17286/62A GB1728662A GB998880A GB 998880 A GB998880 A GB 998880A GB 17286/62 A GB17286/62 A GB 17286/62A GB 1728662 A GB1728662 A GB 1728662A GB 998880 A GB998880 A GB 998880A
Authority
GB
United Kingdom
Prior art keywords
zone
coke
gasification
oxygen
zones
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17286/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB998880A publication Critical patent/GB998880A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/78—High-pressure apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

A liquid hydrocarbon, e.g. bunker C oil, is coked in a zone 4 and part of the coke is transferred (via 5 . . . 7) to a gasification zone 3 where it is contacted by a gas containing free oxygen (e.g. air) at a temperature of 1700 DEG to <PICT:0998880/C4-C5/1> 2200 DEG F., the carbon/oxygen ratio of the feed to the zone 3 being controlled so that at least part of the coke is consumed, coke particles being supplied to the zone 3 at a rate to maintain a supply of coke therein. The zone 3 is preferably a fluidized bed, and the zone 4, to which an oxygen-containing gas may be delivered, may comprise a fluidized bed of coke introduced at 19. Preferred temperatures in the zone 3 are 1750 DEG to 2100 DEG F., and the pressure may be up to 40 p.s.i.g. The oil for the zone 4 and the air for zone 3 may be preheated, e.g. to 200 DEG to 650 DEG F. and 400 DEG to 1000 DEG F. respectively. The gaseous products, which mix in the space above the zones, are mainly hydrogen from zone 4 and CO from zone 3. In a modification, see Fig. 2 (not shown), the zones are in separate vessels, and liquid hydrocarbon may be additionally delivered to the gasification zone, along with some or all of the gases from the coking zone, in order to control the H2/CO ratio in the final gas. The coke introduced at 19 may be activated or petroleum coke. Two detailed examples of the gasification step and details of the operating conditions (including C/O2 mole ratios of 0.5 to 1.5 in the feed), of the apparatus of Fig. 1, are given.
GB17286/62A 1961-05-10 1962-05-04 Process for gasification of liquid hydrocarbons to hydrogen and carbon monoxide Expired GB998880A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US109137A US3128164A (en) 1961-05-10 1961-05-10 Process for gasification of hydrocarbons to hydrogen and carbon monoxide

Publications (1)

Publication Number Publication Date
GB998880A true GB998880A (en) 1965-07-21

Family

ID=22325995

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17286/62A Expired GB998880A (en) 1961-05-10 1962-05-04 Process for gasification of liquid hydrocarbons to hydrogen and carbon monoxide

Country Status (4)

Country Link
US (1) US3128164A (en)
DE (1) DE1255642B (en)
FR (1) FR1326704A (en)
GB (1) GB998880A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015128485A1 (en) * 2014-02-28 2015-09-03 Haldor Topsøe A/S Fuel cracking in a fluidized bed system

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7109406A (en) * 1970-08-14 1972-02-16
US5641327A (en) * 1994-12-02 1997-06-24 Leas; Arnold M. Catalytic gasification process and system for producing medium grade BTU gas
US20050108940A1 (en) * 2003-11-24 2005-05-26 Future Energy Gmbh Reactor wall for a fluidized-flow gasifier
DE102008014799A1 (en) * 2008-03-18 2009-09-24 Karl-Heinz Tetzlaff Process and apparatus for producing synthesis gas from biomass
DE102008032166A1 (en) 2008-07-08 2010-01-14 Karl-Heinz Tetzlaff Process and device for the production of tar-free synthesis gas from biomass
AU2013359595B2 (en) * 2012-12-10 2016-02-18 Southern Company Second stage gasifier in staged gasification
US11787694B2 (en) 2021-08-13 2023-10-17 General Atomics Producing high purity hydrogen and carbon monoxide from a hydrocarbon material

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE484743C (en) * 1926-10-08 1929-10-22 I G Farbenindustrie Akt Ges Process for the production of oil gas
DE642526C (en) * 1934-01-05 1937-03-09 I G Farbenindustrie Akt Ges Process for the production of town gas from gases containing hydrocarbons
DE699489C (en) * 1935-05-12 1940-11-30 Linde Eismasch Ag Process for the production of hydrogen-rich gas mixtures with partial combustion of methane with oxygen
US2301812A (en) * 1939-09-26 1942-11-10 William J Wesseler Method for producing and using nonoxidizing gases
US2618542A (en) * 1948-02-27 1952-11-18 Kellogg M W Co Manufacture of a gaseous mixture rich in hydrogen
DE960307C (en) * 1952-05-09 1957-03-21 Otto & Co Gmbh Dr C Process for the continuous generation of urban gas from oils
US2805177A (en) * 1954-06-02 1957-09-03 Exxon Research Engineering Co Production of hydrogen and coke
US2884303A (en) * 1956-03-06 1959-04-28 Exxon Research Engineering Co High temperature burning of particulate carbonaceous solids
DE1070771B (en) * 1956-10-10

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015128485A1 (en) * 2014-02-28 2015-09-03 Haldor Topsøe A/S Fuel cracking in a fluidized bed system

Also Published As

Publication number Publication date
DE1255642B (en) 1967-12-07
FR1326704A (en) 1963-05-10
US3128164A (en) 1964-04-07

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