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GB990349A - Improved method of hydrogenolysis of sugars - Google Patents

Improved method of hydrogenolysis of sugars

Info

Publication number
GB990349A
GB990349A GB28418/63A GB2841863A GB990349A GB 990349 A GB990349 A GB 990349A GB 28418/63 A GB28418/63 A GB 28418/63A GB 2841863 A GB2841863 A GB 2841863A GB 990349 A GB990349 A GB 990349A
Authority
GB
United Kingdom
Prior art keywords
hydrogenolysis
product
calcium
glycols
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28418/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zeneca Inc
Original Assignee
Atlas Chemical Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Chemical Industries Inc filed Critical Atlas Chemical Industries Inc
Publication of GB990349A publication Critical patent/GB990349A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/205—1,3-Propanediol; 1,2-Propanediol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/26—Hexahydroxylic alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A continuous process for the hydrogenolysis of a reducible sugar comprises reacting a carbohydrate hydrogenolysis process residue depleted of a glycerol and glycols with hydrogen at an elevated temperature in the presence of a cracking additive and a hydrogenation catalyst to form a first hydrogenolysis product, mixing this product with a feed of reducible sugar and reacting the mixture with hydrogen at an elevated temperature in the presence of a cracking additive and a hydrogenation catalyst to form a second hydrogenolysis product, and separating glycerin and glycols from the latter product leaving another hydrogenolysis porous residue. The preferred catalyst is nickel promoted by iron. Suitable cracking additives are, for example, calcium oxide, calcium hydroxide, calcium carbonate or salts of calcium and weak acids. Specification 721,260 is referred to.
GB28418/63A 1962-07-20 1963-07-18 Improved method of hydrogenolysis of sugars Expired GB990349A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US21121962A 1962-07-20 1962-07-20

Publications (1)

Publication Number Publication Date
GB990349A true GB990349A (en) 1965-04-28

Family

ID=22786013

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28418/63A Expired GB990349A (en) 1962-07-20 1963-07-18 Improved method of hydrogenolysis of sugars

Country Status (1)

Country Link
GB (1) GB990349A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015119767A1 (en) 2014-02-10 2015-08-13 Archer Daniels Midland Company Improved multiphase low mixing processes
CN116472261A (en) * 2020-10-07 2023-07-21 国际壳牌研究有限公司 Preparation method of diol

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015119767A1 (en) 2014-02-10 2015-08-13 Archer Daniels Midland Company Improved multiphase low mixing processes
EP3110541A4 (en) * 2014-02-10 2018-01-17 Archer-Daniels-Midland Company Improved multiphase low mixing processes
CN116472261A (en) * 2020-10-07 2023-07-21 国际壳牌研究有限公司 Preparation method of diol

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