GB990252A - Agglomeration process for making granular detergent compositions - Google Patents
Agglomeration process for making granular detergent compositionsInfo
- Publication number
- GB990252A GB990252A GB9502/62A GB950262A GB990252A GB 990252 A GB990252 A GB 990252A GB 9502/62 A GB9502/62 A GB 9502/62A GB 950262 A GB950262 A GB 950262A GB 990252 A GB990252 A GB 990252A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- mixture
- adhesive
- compositions
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 13
- 239000003599 detergent Substances 0.000 title abstract 3
- 238000005054 agglomeration Methods 0.000 title abstract 2
- 230000002776 aggregation Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 239000000853 adhesive Substances 0.000 abstract 7
- 230000001070 adhesive effect Effects 0.000 abstract 7
- 150000003839 salts Chemical class 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 5
- -1 orthophenylphenol sodium salt Chemical class 0.000 abstract 4
- 239000008187 granular material Substances 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 238000004140 cleaning Methods 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 230000036571 hydration Effects 0.000 abstract 2
- 238000006703 hydration reaction Methods 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 2
- 241000416162 Astragalus gummifer Species 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 abstract 1
- 235000017788 Cydonia oblonga Nutrition 0.000 abstract 1
- 229920001353 Dextrin Polymers 0.000 abstract 1
- 239000004375 Dextrin Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 229920001615 Tragacanth Polymers 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 abstract 1
- 235000019425 dextrin Nutrition 0.000 abstract 1
- 235000011180 diphosphates Nutrition 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N ortho-phenyl-phenol Natural products OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 abstract 1
- 235000010292 orthophenyl phenol Nutrition 0.000 abstract 1
- 239000004306 orthophenyl phenol Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/28—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic using special binding agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Abstract
Granular cleaning compositions which are particularly suitable for cleaning hard surfaces, and having a bulk density less than 80% of the average bulk density of the dry particulate components thereof, are prepared by agitating 70-96 parts of one or more alkali metal orthophosphates, tripolyphosphates, pyrophosphates, carbonates, bicarbonates, sesquicarbonates and tetraborates, of which salts all are in discrete particulate form and pass a 10-mesh Tyler screen and at least one has a water of hydration content substantially below its capacity, spraying the mixture with an aqueous solution containing 20-50% of an organic adhesive which, when dried, is resoluble in water in such amount that 1-10 parts of adhesive dissolved in 3-20 parts water are added to the mixture, and removing enough water from the adhesive solution by hydration of the salts to form a dehydrated adhesive, thereby causing agglomeration of the mixture into granules, preferably so that at least 75% of the particles are of a size 20-100 mesh (Tyler). The preferred salt is trisodium orthophosphate, and suitable adhesives are various starches and dextrins, gum tragacanth, quince seed gum and water-soluble glues. The adhesive solution preferably contains borax and a mould preventative such as orthophenylphenol sodium salt. The composition preferably also includes at least 1% of such non-cationic detergents as alkyl glyceryl ether sulphonates, fatty acid monoglyceride sulphates and sulphonates, fatty acyl esters of hydroxyalkane sulphonates, acyl taurides, alkyl oxyethylene sulphates, and ethylene oxide condensates with alkylphenols, fatty acids and fatty alcohols, but most suitably sodium C10- 18-alkyl sulphate or C9- 15-alkylbenzene sulphonate. Preferably the adhesive solution is used in an amount of 0.04-0.1 parts per part of dry salt mix, with the total water content of the final composition amounting to less than 40%. If desired, the liquid sprayed on to the hydratable salts may contain a pigment, e.g. a mixture of phthalocyanine blue and Polar Brilliant Blue, so as to produce brightly coloured granules having a chroma (Mansell) of at least 4, a Munsell value gf 4-7 and a minimum dimension greater than 0.2 mm.; alternatively the pigment may be sprayed on to the agglomerated mixture. Such coloured compositions may then be mixed with white compositions to produce speckled compositions. Sodium sulphate (as impurity in the detergent) may also be present, and the granules may be compressed to form tablets. Specification 808,668 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA818766 | 1961-03-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB990252A true GB990252A (en) | 1965-04-28 |
Family
ID=4141297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9502/62A Expired GB990252A (en) | 1961-03-10 | 1962-03-12 | Agglomeration process for making granular detergent compositions |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE621577A (en) |
| GB (1) | GB990252A (en) |
| MY (1) | MY6600103A (en) |
| OA (1) | OA01382A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2194793A (en) * | 1987-10-15 | 1988-03-16 | Unilever Plc | Mottled liquid detergents |
| WO2000063341A1 (en) * | 1999-04-19 | 2000-10-26 | The Procter & Gamble Company | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
| US6730652B1 (en) * | 1999-04-19 | 2004-05-04 | The Procter & Gamble Company | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
| CN110198779A (en) * | 2017-02-10 | 2019-09-03 | 克利夫兰波达斯有限公司 | Polyhalite method of granulating |
-
0
- BE BE621577D patent/BE621577A/xx unknown
-
1962
- 1962-03-12 GB GB9502/62A patent/GB990252A/en not_active Expired
-
1964
- 1964-12-31 OA OA51833A patent/OA01382A/en unknown
-
1966
- 1966-12-31 MY MY1966103A patent/MY6600103A/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2194793A (en) * | 1987-10-15 | 1988-03-16 | Unilever Plc | Mottled liquid detergents |
| WO2000063341A1 (en) * | 1999-04-19 | 2000-10-26 | The Procter & Gamble Company | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
| US6730652B1 (en) * | 1999-04-19 | 2004-05-04 | The Procter & Gamble Company | Process for making non-staining colored particles for improving aesthetics of a liquid automatic dishwashing detergent product, the particles, and a composition |
| CN110198779A (en) * | 2017-02-10 | 2019-09-03 | 克利夫兰波达斯有限公司 | Polyhalite method of granulating |
Also Published As
| Publication number | Publication date |
|---|---|
| BE621577A (en) | |
| OA01382A (en) | 1969-07-04 |
| MY6600103A (en) | 1966-12-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1302195C (en) | Detergent compositions | |
| US4009076A (en) | Enzyme granules | |
| GB1455873A (en) | Textile-softening detergent compositions | |
| EP0536110B1 (en) | Process for manufacturing tenside-containing granulates | |
| GB957868A (en) | Process for making a detergent tablet | |
| US3933673A (en) | Detergent compositions containing polymeric builders | |
| CH639690A5 (en) | METHOD FOR PRODUCING DETERGENT POWDER. | |
| GB808945A (en) | Detergent compositions | |
| US1621906A (en) | Cleansing compound | |
| US4298493A (en) | Method for retarding gelation of bicarbonate-carbonate-silicate crutcher slurries | |
| US4416809A (en) | Granular detergent composition | |
| GB1066234A (en) | Phosphate-containing compositions | |
| CA1298163C (en) | Surfactant mixtures and their use | |
| GB930394A (en) | Liquid detergent compositions | |
| US2333443A (en) | Method of preparing detergent | |
| GB990252A (en) | Agglomeration process for making granular detergent compositions | |
| US3639288A (en) | Detergent slurry process | |
| GB1280455A (en) | Preparation of granular detergent compositions | |
| US2026816A (en) | Soap preparation | |
| JPS60133095A (en) | Granular detergent composition | |
| JPH06503107A (en) | solid detergent | |
| GB1259551A (en) | ||
| US2730507A (en) | Method of making dustless soap powder | |
| US2603605A (en) | Process for production of washing powder from a normally oily liquid synthetic soapless detergent | |
| US3130166A (en) | Granular soap compositions containing carbamide |