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GB985070A - Improvements in or relating to the manufacture of 2,3-dichlorobutadiene - Google Patents

Improvements in or relating to the manufacture of 2,3-dichlorobutadiene

Info

Publication number
GB985070A
GB985070A GB913963A GB913963A GB985070A GB 985070 A GB985070 A GB 985070A GB 913963 A GB913963 A GB 913963A GB 913963 A GB913963 A GB 913963A GB 985070 A GB985070 A GB 985070A
Authority
GB
United Kingdom
Prior art keywords
dichlorobutadiene
ammonia
polymer
tetrachlorobutane
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB913963A
Inventor
Richard Arthur Rose
Henry Norman Gibbs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Cellophane Ltd
Original Assignee
British Cellophane Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Cellophane Ltd filed Critical British Cellophane Ltd
Publication of GB985070A publication Critical patent/GB985070A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/25Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

2,3-Dichlorobutadiene is obtained by reacting ammonia with 1,2,3,4-tetrachlorobutane dissolved in an organic polar solvent, such as dimethyl sulphoxide, dimethyl formamide, formamide, acetone or mixtures thereof. The ammonia may be at substantially atmospheric pressure, preferably with a reaction temperature of 60-80 DEG C., or at superatmospheric pressure. Polymerization inhibitors may be present in the reaction mixture. Specification 951,312 is referred to.ALSO:2,3-Dichlorobutadiene obtained from ammonia and 1,2,3,4-tetrachlorobutane (see Division C2) may be polymerized to a polymer soluble in toluene and which can be cast from a suitable solvent or melt-extruded to form articles such as fibres, filaments and films. In an example, 2,3-dichlorobutadiene in solution in nitrobenzene is polymerized in the presence of azo-bis-isobutyronitrile and the polymer precipitated with methanol. Films prepared from the polymer are said to be of use as moisture vapour impermeable wrapping materials. Specification 951,312 is referred to.
GB913963A 1964-02-26 1963-03-07 Improvements in or relating to the manufacture of 2,3-dichlorobutadiene Expired GB985070A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB913964 1964-02-26

Publications (1)

Publication Number Publication Date
GB985070A true GB985070A (en) 1965-03-03

Family

ID=9866123

Family Applications (1)

Application Number Title Priority Date Filing Date
GB913963A Expired GB985070A (en) 1964-02-26 1963-03-07 Improvements in or relating to the manufacture of 2,3-dichlorobutadiene

Country Status (2)

Country Link
DE (1) DE1213396B (en)
GB (1) GB985070A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4035429A (en) * 1972-02-01 1977-07-12 Norair Gareginovich Karapetian Method of producing 2,3-dichlorbutadiene-1,3
US4385192A (en) * 1978-07-05 1983-05-24 Amvac Chemical Corporation Process for manufacturing DBCP
WO2009085837A3 (en) * 2007-12-19 2009-10-01 Dupont Performance Elastomers L.L.C. Process for production of 2,3-dichlorobutadiene-1,3

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4035429A (en) * 1972-02-01 1977-07-12 Norair Gareginovich Karapetian Method of producing 2,3-dichlorbutadiene-1,3
US4385192A (en) * 1978-07-05 1983-05-24 Amvac Chemical Corporation Process for manufacturing DBCP
WO2009085837A3 (en) * 2007-12-19 2009-10-01 Dupont Performance Elastomers L.L.C. Process for production of 2,3-dichlorobutadiene-1,3
CN101903314A (en) * 2007-12-19 2010-12-01 杜邦特性弹性体有限责任公司 Process for production of 2,3-dichlorobutadiene-1,3
CN101903314B (en) * 2007-12-19 2014-05-28 纳幕尔杜邦公司 Process for production of 2, 3 - dichloro - 1, 3 - butadiene

Also Published As

Publication number Publication date
DE1213396B (en) 1966-03-31

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