GB985070A - Improvements in or relating to the manufacture of 2,3-dichlorobutadiene - Google Patents
Improvements in or relating to the manufacture of 2,3-dichlorobutadieneInfo
- Publication number
- GB985070A GB985070A GB913963A GB913963A GB985070A GB 985070 A GB985070 A GB 985070A GB 913963 A GB913963 A GB 913963A GB 913963 A GB913963 A GB 913963A GB 985070 A GB985070 A GB 985070A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dichlorobutadiene
- ammonia
- polymer
- tetrachlorobutane
- polymerized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
2,3-Dichlorobutadiene is obtained by reacting ammonia with 1,2,3,4-tetrachlorobutane dissolved in an organic polar solvent, such as dimethyl sulphoxide, dimethyl formamide, formamide, acetone or mixtures thereof. The ammonia may be at substantially atmospheric pressure, preferably with a reaction temperature of 60-80 DEG C., or at superatmospheric pressure. Polymerization inhibitors may be present in the reaction mixture. Specification 951,312 is referred to.ALSO:2,3-Dichlorobutadiene obtained from ammonia and 1,2,3,4-tetrachlorobutane (see Division C2) may be polymerized to a polymer soluble in toluene and which can be cast from a suitable solvent or melt-extruded to form articles such as fibres, filaments and films. In an example, 2,3-dichlorobutadiene in solution in nitrobenzene is polymerized in the presence of azo-bis-isobutyronitrile and the polymer precipitated with methanol. Films prepared from the polymer are said to be of use as moisture vapour impermeable wrapping materials. Specification 951,312 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB913964 | 1964-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB985070A true GB985070A (en) | 1965-03-03 |
Family
ID=9866123
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB913963A Expired GB985070A (en) | 1964-02-26 | 1963-03-07 | Improvements in or relating to the manufacture of 2,3-dichlorobutadiene |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1213396B (en) |
GB (1) | GB985070A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4035429A (en) * | 1972-02-01 | 1977-07-12 | Norair Gareginovich Karapetian | Method of producing 2,3-dichlorbutadiene-1,3 |
US4385192A (en) * | 1978-07-05 | 1983-05-24 | Amvac Chemical Corporation | Process for manufacturing DBCP |
WO2009085837A3 (en) * | 2007-12-19 | 2009-10-01 | Dupont Performance Elastomers L.L.C. | Process for production of 2,3-dichlorobutadiene-1,3 |
-
0
- DE DEB75772A patent/DE1213396B/en active Pending
-
1963
- 1963-03-07 GB GB913963A patent/GB985070A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4035429A (en) * | 1972-02-01 | 1977-07-12 | Norair Gareginovich Karapetian | Method of producing 2,3-dichlorbutadiene-1,3 |
US4385192A (en) * | 1978-07-05 | 1983-05-24 | Amvac Chemical Corporation | Process for manufacturing DBCP |
WO2009085837A3 (en) * | 2007-12-19 | 2009-10-01 | Dupont Performance Elastomers L.L.C. | Process for production of 2,3-dichlorobutadiene-1,3 |
CN101903314A (en) * | 2007-12-19 | 2010-12-01 | 杜邦特性弹性体有限责任公司 | Process for production of 2,3-dichlorobutadiene-1,3 |
CN101903314B (en) * | 2007-12-19 | 2014-05-28 | 纳幕尔杜邦公司 | Process for production of 2, 3 - dichloro - 1, 3 - butadiene |
Also Published As
Publication number | Publication date |
---|---|
DE1213396B (en) | 1966-03-31 |
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