GB982264A - Manufacture of bicyclo-(3.2.1)-octene-(2) - Google Patents
Manufacture of bicyclo-(3.2.1)-octene-(2)Info
- Publication number
- GB982264A GB982264A GB5912/63A GB591263A GB982264A GB 982264 A GB982264 A GB 982264A GB 5912/63 A GB5912/63 A GB 5912/63A GB 591263 A GB591263 A GB 591263A GB 982264 A GB982264 A GB 982264A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- vinylcyclohexene
- bicyclo
- octene
- trihydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 4
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- -1 beta - cyclohex - 2 - enylethyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 abstract 1
- SSPNLRVPYROWLU-UHFFFAOYSA-N bicyclo[3.2.1]oct-4-ene Chemical compound C1CC(C2)CCC2=C1 SSPNLRVPYROWLU-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N diisobutylaluminium hydride Substances CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
- C07C1/327—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being an aluminium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/44—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing eight carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Bicyclo - [3.2.1] - octene - 2 is obtained by heating to above 130 DEG C. either an aluminium trihydrocarbon compound containing at least one beta - cyclohex - 2 - enylethyl group, any other groups being alkyl groups, preferably in the presence of an alpha-olefin or a mixture of 4-vinylcyclohexene and an aluminium alkyl compound capable of forming said aluminium trihydrocarbon. Suitable reaction mixtures include tricyclohexenylethyl aluminium with isobutene or 4-vinylcyclohexene or triisobutyl aluminium or diisobutyl aluminium hydride with 4-vinylcyclohexene. The product is distilled to separate products from aluminium compounds which are reused.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH31020A DE1190459B (en) | 1962-02-21 | 1962-02-21 | Process for the preparation of bicyclo- [3, 2, 1] octene- (2) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB982264A true GB982264A (en) | 1965-02-03 |
Family
ID=7431948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5912/63A Expired GB982264A (en) | 1962-02-21 | 1963-02-13 | Manufacture of bicyclo-(3.2.1)-octene-(2) |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3274271A (en) |
| DE (1) | DE1190459B (en) |
| GB (1) | GB982264A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361837A (en) * | 1965-10-18 | 1968-01-02 | Phillips Petroleum Co | Bicyclization |
| US4398978A (en) * | 1982-04-26 | 1983-08-16 | The United States Of America As Represented By The Secretary Of The Navy | High density, low viscosity airbreather fuel (RJ-4-I) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2826598A (en) * | 1951-06-21 | 1958-03-11 | Ziegler Karl | Production of organic compounds of aluminum and beryllium |
-
1962
- 1962-02-21 DE DESCH31020A patent/DE1190459B/en active Pending
-
1963
- 1963-02-11 US US257738A patent/US3274271A/en not_active Expired - Lifetime
- 1963-02-13 GB GB5912/63A patent/GB982264A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1190459B (en) | 1965-04-08 |
| US3274271A (en) | 1966-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB819867A (en) | Process for the production of polyethylenes and catalysts therefor | |
| GB1021769A (en) | Improvements relating to bis(4-aminocyclohexyl)methane | |
| ES326906A1 (en) | Procedure for obtaining lubricants for leather (Machine-translation by Google Translate, not legally binding) | |
| GB930433A (en) | Preparation of olefins | |
| GB982264A (en) | Manufacture of bicyclo-(3.2.1)-octene-(2) | |
| GB980756A (en) | Improvements in and relating to copolymers | |
| GB868170A (en) | Improvements in or relating to plastic containers | |
| ES376523A1 (en) | Low temperature lubricants | |
| GB853098A (en) | Preparation of alkyl borate esters | |
| CA629845A (en) | Process for improving dyeability of synthetic materials obtained by polymerizing mono-olefin hydrocarbons | |
| GB605456A (en) | Improvements in or relating to synthetic hydrocarbons, lubricating oils derived therefrom and manufacture of the same | |
| GB829628A (en) | Production of high molecular weight polyethylenes and compositions suitable for use as catalysts therein | |
| CA633330A (en) | Composition of matter having catalytic properties for the polymerization of unsaturated organic compounds | |
| CA462560A (en) | Polymerization of highly reactive unsaturated compounds to rubber-like products | |
| GB954112A (en) | Improvements in or relating to the treatment of hydrocarbons | |
| CA596601A (en) | Process for treating textiles with ethylene urea-formaldehyde reaction products | |
| GB1004936A (en) | Process for the manufacture of 2:2:2-trifluoro-1-chloro-1-bromethane | |
| AU151308B2 (en) | The pearl polymerisation of unsaturated organic compounds which contain a chic group in the molecule | |
| GB859850A (en) | Improvements in the production of 1-phenylcyclohexane-1-hydroperoxide | |
| CA495703A (en) | Reaction of alpha-beta unsaturated compounds with aromatic hydrocarbons and products obtained | |
| AU6114360A (en) | Improvements inthe polymerisation of olefine compounds inthe presence of catalysts based ona boron trialkyl | |
| CA560269A (en) | Bitumen emulsion containing ethylene oxide-amine reaction product | |
| AU232951A (en) | The pearl polymerisation of unsaturated organic compounds which contain a chic group in the molecule | |
| AU274066B2 (en) | New polymeric compositions, process of producing them from ethylene polymers and articles resistant to cracking made therefrom | |
| ES249764A1 (en) | Procedure for the preparation of a new adequate composition as a component of a useful catalyst for the polymerization of olefins (Machine-translation by Google Translate, not legally binding) |