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GB976568A - A process for the production of amphoteric ion exchange resins - Google Patents

A process for the production of amphoteric ion exchange resins

Info

Publication number
GB976568A
GB976568A GB54363A GB54363A GB976568A GB 976568 A GB976568 A GB 976568A GB 54363 A GB54363 A GB 54363A GB 54363 A GB54363 A GB 54363A GB 976568 A GB976568 A GB 976568A
Authority
GB
United Kingdom
Prior art keywords
acid
carboxylic acid
specified
halogeno
exchange resins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB54363A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEF30457A external-priority patent/DE1153022B/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB976568A publication Critical patent/GB976568A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/04—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D203/06—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D203/08—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring nitrogen atom
    • C07D203/12—Radicals substituted by nitrogen atoms not forming part of a nitro radical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J43/00—Amphoteric ion-exchange, i.e. using ion-exchangers having cationic and anionic groups; Use of material as amphoteric ion-exchangers; Treatment of material for improving their amphoteric ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/564—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Epoxy Resins (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

Amphoteric ion-exchange resins are produced by reacting polyethylene-imine under mildly alkaline conditions with a halogenoaliphatic carboxylic acid or a halogeno alkyl phosphonic acid or with a salt thereof, in amounts such that not all of the N-atoms of the polyethylene-imine are substituted, and reacting the pre-polymer obtained with a polyhalogenoaliphatic compound or with a aliphatic compound containing at least one halogen atom and at least one epoxy group. The halogeno aliphatic carboxylic acid preferably contains from 2-5 carbon atoms, those specified being chloroacetic acid and b -chloropropionic acid. Specified halogeno alkyl phosphonic acids are chloromethyl and chloroethylphosphonic acid. In the pre-polymer preferably 10-30% of the nitrogen atoms should remain unsubstituted. The mildly alkaline conditions are preferably pH 10-11 at 80-100 DEG C. Specified cross-linking compounds (i.e. halogenoaliphatic compounds) are epichlorohydrin, epibromohydrin, dichlorohydrin, dichloroethyl ether, dichloroethylene, dichloropropylene and di-bromoethylene. The examples describe the preparation of (1) an a -amino carboxylic acid resin, (2) an a -aminophosphonic acid resin. Specification 976,567 also is referred to.
GB54363A 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins Expired GB976568A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEF30460A DE1160183B (en) 1960-02-04 1960-02-04 Process for the production of copolymers of ethyleneimine compounds serving as amphoteric ion exchangers
DEF30457A DE1153022B (en) 1960-02-04 1960-02-04 Process for the preparation of AEthylenimin-N-ethylphosphonic acid dialkyl esters
FR851318A FR1278553A (en) 1960-02-04 1961-02-01 Amphoteric ion exchange resins

Publications (1)

Publication Number Publication Date
GB976568A true GB976568A (en) 1964-11-25

Family

ID=27210163

Family Applications (5)

Application Number Title Priority Date Filing Date
GB402261A Expired GB976566A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins
GB54263A Expired GB976567A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54463A Expired GB976569A (en) 1960-02-04 1961-02-02 A process for the preparation of diesters of n-dihydroxy-phosphinylethyl ethylene imine
GB54363A Expired GB976568A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB3602163A Expired GB976570A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins

Family Applications Before (3)

Application Number Title Priority Date Filing Date
GB402261A Expired GB976566A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins
GB54263A Expired GB976567A (en) 1960-02-04 1961-02-02 A process for the production of amphoteric ion exchange resins
GB54463A Expired GB976569A (en) 1960-02-04 1961-02-02 A process for the preparation of diesters of n-dihydroxy-phosphinylethyl ethylene imine

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB3602163A Expired GB976570A (en) 1960-02-04 1961-02-02 Amphoteric ion exchange resins

Country Status (4)

Country Link
DE (1) DE1160183B (en)
FR (1) FR1278553A (en)
GB (5) GB976566A (en)
NL (1) NL260849A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020019A (en) 1975-01-29 1977-04-26 Gianluigi Soldati Anticaries agents
CN108479713A (en) * 2018-04-10 2018-09-04 浙江农林大学 A kind of aminocarboxylic acid type hydro-thermal bamboo charcoal synthetic method

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1270287B (en) * 1965-09-27 1968-06-12 Max Planck Gesellschaft Process for the production of copolymers of ethyleneimine compounds serving as amphoteric ion exchangers
US3459686A (en) * 1966-06-06 1969-08-05 Dow Chemical Co Aziridine copolymers
US3468818A (en) * 1966-08-01 1969-09-23 Nalco Chemical Co Polymers and process of preparation
GB2075996B (en) * 1975-01-27 1985-04-11 Ramot Plastics Polymers and their preparation
JPS5443292A (en) * 1977-09-12 1979-04-05 Unitika Ltd Etherified phenolic chelate resin* its production* and adsorption treatment
DE4039920A1 (en) * 1990-12-14 1992-06-17 Basf Ag NEW POLYETHYLENIMINE AND POLYVINYLAMINE DERIVATIVES, CARRIER MATERIALS COATED WITH THESE DERIVATIVES ON THE BASIS OF ALUMINUM AND THE USE THEREOF FOR THE PRODUCTION OF OFFSET PRINTING PLATES

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL110743C (en) * 1954-05-17 1900-01-01
DE1056825B (en) * 1956-03-07 1959-05-06 Wolfen Filmfab Veb Process for the preparation of insoluble nitrogen-containing cation exchange resins
DE1056371B (en) * 1956-05-23 1959-04-30 Wolfen Filmfab Veb Process for the production of synthetic resins used as anion exchangers or adsorbents

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020019A (en) 1975-01-29 1977-04-26 Gianluigi Soldati Anticaries agents
CN108479713A (en) * 2018-04-10 2018-09-04 浙江农林大学 A kind of aminocarboxylic acid type hydro-thermal bamboo charcoal synthetic method

Also Published As

Publication number Publication date
FR1278553A (en) 1961-12-08
GB976570A (en) 1964-11-25
GB976567A (en) 1964-11-25
DE1160183B (en) 1963-12-27
GB976566A (en) 1964-11-25
NL260849A (en)
GB976569A (en) 1964-11-25

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