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GB969133A - A process for the hydrogenation of hydrocarbons in the gasoline boiling range - Google Patents

A process for the hydrogenation of hydrocarbons in the gasoline boiling range

Info

Publication number
GB969133A
GB969133A GB45809/62A GB4580962A GB969133A GB 969133 A GB969133 A GB 969133A GB 45809/62 A GB45809/62 A GB 45809/62A GB 4580962 A GB4580962 A GB 4580962A GB 969133 A GB969133 A GB 969133A
Authority
GB
United Kingdom
Prior art keywords
alumina
metal
hydrocarbons
hydrocarbon
liquid phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB45809/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB969133A publication Critical patent/GB969133A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/10—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Hydrocarbons in the gasoline boiling point range and containing undesired unsaturated hydrocarbons are hydrogenated in two stages. In the first stage the hydrocarbon is trickled in the liquid phase over a noble metal of Group VIII of the Periodic Table supported on a macroporous support, having an intrinsic surface of less than 100 m.2/g. and a water absorption capacity of at least 10% by weight, at a temperature below 100 DEG C., and then trickling in the liquid phase over a noble metal of Group VIII at 125 DEG C. to 250 DEG C. The metal in the second stage may be on a carrier having an intimate surface above 50 m.2/g. The catalysts may be treated with sulphur-containing gases and then with hydrogen before they are used. The metal is preferably palladium, and the hydrocarbon is preferably free from hydrogen sulphide and readily decomposable organic sulphur compounds. Preferred carriers are:-alumina, alumina-silica, alumina-chromia, low-silica bauxites, preferably thermally treated, magnesia, baria, calcium oxide, alkaline-earth metal carbonates, titania, zirconia or thoria. Specifications 916,683 and 927,631 are referred to.
GB45809/62A 1961-12-08 1962-12-04 A process for the hydrogenation of hydrocarbons in the gasoline boiling range Expired GB969133A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF35498A DE1278052B (en) 1961-12-08 1961-12-08 Process for the hydrogenation treatment of hydrocarbons in the gasoline boiling range

Publications (1)

Publication Number Publication Date
GB969133A true GB969133A (en) 1964-09-09

Family

ID=7096028

Family Applications (1)

Application Number Title Priority Date Filing Date
GB45809/62A Expired GB969133A (en) 1961-12-08 1962-12-04 A process for the hydrogenation of hydrocarbons in the gasoline boiling range

Country Status (6)

Country Link
US (1) US3167498A (en)
BE (1) BE625810A (en)
DE (1) DE1278052B (en)
FR (1) FR1342470A (en)
GB (1) GB969133A (en)
NL (2) NL133842C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008135582A1 (en) * 2007-05-08 2008-11-13 Basf Se Iridium-palladium catalysts for converting hydrocarbons in the presence of water vapour and especially for the steam dealkylation of alkyl-substituted aromatic hydrocarbons

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3243387A (en) * 1963-04-25 1966-03-29 Leuna Werke Veb Palladium-silver-iron oxide on alphaalumina catalyst composition for the selective hydrogenation of acetylene
US3309307A (en) * 1964-02-13 1967-03-14 Mobil Oil Corp Selective hydrogenation of hydrocarbons
US3493492A (en) * 1964-06-19 1970-02-03 Lummus Co Hydrotreating of pyrolysis gasoline (dripolene)
US3494859A (en) * 1967-06-07 1970-02-10 Universal Oil Prod Co Two-stage hydrogenation of an aromatic hydrocarbon feedstock containing diolefins,monoolefins and sulfur compounds
FR2077907A1 (en) * 1970-02-23 1971-11-05 Inst Francais Du Petrole
US5894076A (en) * 1997-05-12 1999-04-13 Catalytic Distillation Technologies Process for alkylation of benzene
FR2764210B1 (en) 1997-06-09 1999-07-16 Inst Francais Du Petrole SELECTIVE HYDROGENATION CATALYST FOR USE IN THE TREATMENT OF ESSENCE CUTTINGS CONTAINING DIOLEFINS AND STYRENIC COMPOUNDS
EP1753532A1 (en) * 2004-05-14 2007-02-21 Dow Gloval Technologies Inc. High selectivity catalyst for the conversion of carbon tetrachloride to chloroform
US20060178262A1 (en) * 2005-01-20 2006-08-10 Andrzej Rokicki Hydrogenation catalyst
EP2670502B1 (en) * 2011-02-02 2020-11-18 Basf Se Process for separation of water from pyrolysis gasoline

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1067160B (en) *
US2365751A (en) * 1941-06-07 1944-12-26 Phillips Petroleum Co Process for hydrogenating hydrocarbon oils
BE538628A (en) * 1954-06-02
US3075915A (en) * 1958-06-09 1963-01-29 Chemetron Corp Hydrodesulfurization catalyst and the method of manufacture
NL134507C (en) * 1959-04-17

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008135582A1 (en) * 2007-05-08 2008-11-13 Basf Se Iridium-palladium catalysts for converting hydrocarbons in the presence of water vapour and especially for the steam dealkylation of alkyl-substituted aromatic hydrocarbons

Also Published As

Publication number Publication date
DE1278052B (en) 1968-09-19
NL286390A (en)
FR1342470A (en) 1963-11-08
NL133842C (en)
BE625810A (en) 1965-06-01
US3167498A (en) 1965-01-26

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