GB951930A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- GB951930A GB951930A GB14304/60A GB1430460A GB951930A GB 951930 A GB951930 A GB 951930A GB 14304/60 A GB14304/60 A GB 14304/60A GB 1430460 A GB1430460 A GB 1430460A GB 951930 A GB951930 A GB 951930A
- Authority
- GB
- United Kingdom
- Prior art keywords
- potassium
- sodium
- alkyl
- pyrophosphate
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 title 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 5
- 229910052708 sodium Inorganic materials 0.000 abstract 5
- 239000011734 sodium Substances 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 3
- -1 ethanol-ammonium cations Chemical class 0.000 abstract 3
- 229910052700 potassium Inorganic materials 0.000 abstract 3
- 239000011591 potassium Substances 0.000 abstract 3
- 150000001412 amines Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 235000011180 diphosphates Nutrition 0.000 abstract 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 abstract 2
- BGHJOVPDUCMEAT-UHFFFAOYSA-M potassium;phenylmethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)CC1=CC=CC=C1 BGHJOVPDUCMEAT-UHFFFAOYSA-M 0.000 abstract 2
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000003827 glycol group Chemical group 0.000 abstract 1
- 239000003752 hydrotrope Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical class [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000271 synthetic detergent Substances 0.000 abstract 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 abstract 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A concentrated aqueous detergent composition comprises by weight (a) 3-10% amine oxide of formula R1R1R3N --> O, where R1 is C10- 16 alkyl radical, preferably at least 50% of the amine oxide being such that R1 contains 12 carbon atoms, and R2 and R3 are both methyl or ethyl, (b) 3-15% of an anionic synthetic detergent containing a C9-16 alkyl group which is soluble to the extent of at least 3% in an aqueous solution containing 3% dodecyl dimethyl amine oxide, 3% potassium toluene sulphonate and 10% potassium pyrophosphate, and being stable in alkaline solution, (c) 3-10% of non-detergent a hydrotrope salt, and (d) 10-30% of a pyrophosphate, the cations present in (b), (c) and (d) being potassium, sodium, or mono-, di-, or tri-ethanolammonium, and the mole ratio of potassium and ethanol-ammonium cations to sodium being greater than 3 : 1, and preferably above 3.5 : 1; (a) is preferably dimethyldodecylamine oxide or dimethylcoconutamine oxide. The preferred detergents (b) are alkylbenzene sulphonates, alkyl sulphates, and alkyl polyglycol ether sulphates in which there are present 1-5 glycol residues per molecule, the alkyl groups suitably containing 12 carbon atoms and the detergents or mixtures thereof being used in the form of the sodium or triethanolamine salts. Suitable hydrotropes (c) are benzene, toluene, and xylene sulphonates, sodium or potassium toluene sulphonate being preferred. The preferred pyrophosphate (d) is the potassium salt. The compositions generally also contain 3.5-6% silicate solids of formula M2O : nSiO2 in which M is sodium or potassium and n is 1-2.6, preferably 1.6-2.6. In addition, sodium carboxymethylcellulose in amounts up to 2%, tarnish inhibitor such as benztriazole or ethylenethiourea in amounts up to 1%, and less than 1% of fluorescers, perfume and colour may also be incorporated. The final composition should contain 45-70% water, and should contain a total of 10-25% of (a) and (b) and 25-40% of (b) and (d). Specifications 848,224, 848,225, 850,274 and 938,988 are referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US808022A US3085982A (en) | 1959-04-22 | 1959-04-22 | Liquid detergent composition |
GB39183/65A GB1091517A (en) | 1959-04-22 | 1965-09-14 | Liquid detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB951930A true GB951930A (en) | 1964-03-11 |
Family
ID=26264028
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14304/60A Expired GB951930A (en) | 1959-04-22 | 1960-04-22 | Liquid detergent composition |
GB39183/65A Expired GB1091517A (en) | 1959-04-22 | 1965-09-14 | Liquid detergent composition |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB39183/65A Expired GB1091517A (en) | 1959-04-22 | 1965-09-14 | Liquid detergent composition |
Country Status (5)
Country | Link |
---|---|
US (1) | US3085982A (en) |
BE (1) | BE622462A (en) |
DE (1) | DE1185756B (en) |
GB (2) | GB951930A (en) |
NL (1) | NL250715A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4436653A (en) | 1981-04-06 | 1984-03-13 | The Procter & Gamble Company | Stable liquid detergent compositions |
US4438024A (en) | 1982-05-10 | 1984-03-20 | The Procter & Gamble Company | Stable liquid detergent compositions |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE610313A (en) * | 1960-11-14 | |||
NL286242A (en) * | 1961-12-04 | |||
US3194840A (en) * | 1961-12-18 | 1965-07-13 | Procter & Gamble | N, n-diloweralkyl, 1, 1-dihydrogen perfluoroalkyl amine oxides |
BE626346A (en) * | 1961-12-21 | |||
GB1054217A (en) * | 1963-06-05 | |||
US3400198A (en) * | 1963-08-28 | 1968-09-03 | Procter & Gamble | Wave set retention shampoo containing polyethylenimine polymers |
US3330327A (en) * | 1964-03-30 | 1967-07-11 | Continental Oil Co | Drying tertiary amine oxides on extended heated surfaces at elevated temperatures |
US3320078A (en) * | 1965-01-18 | 1967-05-16 | Archer Daniels Midland Co | Process for insolubilizing protein |
US3296145A (en) * | 1965-10-21 | 1967-01-03 | Millmaster Onyx Corp | Quaternary ammonium-tertiary amine oxide compositions |
US4304680A (en) * | 1973-02-05 | 1981-12-08 | Colgate-Palmolive Company | Laundry soap |
JPS51109002A (en) | 1975-03-20 | 1976-09-27 | Kao Corp | Senjozaisoseibutsu |
US4024078A (en) * | 1975-03-31 | 1977-05-17 | The Procter & Gamble Company | Liquid detergent composition |
US4018720A (en) * | 1975-07-14 | 1977-04-19 | The Procter & Gamble Company | Laundry detergent compositions in emulsion/suspension |
JPS5655499A (en) * | 1979-10-11 | 1981-05-16 | Lion Corp | Manufacture of liquid detergent composition |
US4284532A (en) * | 1979-10-11 | 1981-08-18 | The Procter & Gamble Company | Stable liquid detergent compositions |
EP0068520B1 (en) * | 1981-04-06 | 1986-12-03 | THE PROCTER & GAMBLE COMPANY | Built liquid detergent compositions containing ternary active systems |
GB8305790D0 (en) * | 1983-03-02 | 1983-04-07 | Unilever Plc | Liquid detergent composition |
US5399285A (en) * | 1992-10-30 | 1995-03-21 | Diversey Corporation | Non-chlorinated low alkalinity high retention cleaners |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2581677A (en) * | 1952-01-08 | Phosphate detergent composition in | ||
US2169976A (en) * | 1934-01-26 | 1939-08-15 | Ig Farbenindustrie Ag | Process of producing assistants in the textile and related industries |
NL40691C (en) * | 1934-02-16 | |||
CH177545A (en) * | 1934-06-23 | 1935-06-15 | Chem Ind Basel | Wetting agent to increase the wetting ability of mercerising liquors |
BE558422A (en) * | 1956-06-29 |
-
0
- BE BE622462D patent/BE622462A/xx unknown
- DE DENDAT1185756D patent/DE1185756B/de active Pending
- NL NL250715D patent/NL250715A/xx unknown
-
1959
- 1959-04-22 US US808022A patent/US3085982A/en not_active Expired - Lifetime
-
1960
- 1960-04-22 GB GB14304/60A patent/GB951930A/en not_active Expired
-
1965
- 1965-09-14 GB GB39183/65A patent/GB1091517A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4436653A (en) | 1981-04-06 | 1984-03-13 | The Procter & Gamble Company | Stable liquid detergent compositions |
US4438024A (en) | 1982-05-10 | 1984-03-20 | The Procter & Gamble Company | Stable liquid detergent compositions |
Also Published As
Publication number | Publication date |
---|---|
NL250715A (en) | |
DE1185756B (en) | |
BE622462A (en) | |
GB1091517A (en) | 1967-11-15 |
US3085982A (en) | 1963-04-16 |
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