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GB911791A - Process for modifying the properties of fibres and foils of aromatic polyesters - Google Patents

Process for modifying the properties of fibres and foils of aromatic polyesters

Info

Publication number
GB911791A
GB911791A GB8870/59A GB887059A GB911791A GB 911791 A GB911791 A GB 911791A GB 8870/59 A GB8870/59 A GB 8870/59A GB 887059 A GB887059 A GB 887059A GB 911791 A GB911791 A GB 911791A
Authority
GB
United Kingdom
Prior art keywords
swelling agent
fibres
foils
treated
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8870/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB911791A publication Critical patent/GB911791A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/02Chemical treatment or coating of shaped articles made of macromolecular substances with solvents, e.g. swelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
    • C09B1/34Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/08Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • D06M13/127Mono-aldehydes, e.g. formaldehyde; Monoketones
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845Aromatic mono- or polycarboxylic acids
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/345Nitriles
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/52Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
    • D06M13/53Cooling; Steaming or heating, e.g. in fluidised beds; with molten metals
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    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
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    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066Thermic treatments of textile materials
    • D06P5/2072Thermic treatments of textile materials before dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The properties of fibres and foils made from linear aromatic polyesters, e.g. polyethylene terephthalate, are modified by treating them for a period within the range of 10-4 seconds to 5 seconds at a temperature above 200 DEG C., e.g. 200 DEG -350 DEG C., with a chemical substance which acts as a swelling agent for the polyester under the conditions of the process but does not react chemically therewith, either as such or in the presence of an organic solvent. The swelling agent may be an ester, ether, ketone or nitrile, e.g. the dimethyl and diethyl esters of sebacic, azeloic and suberic acids, benzophenone, adipic acid dinitrile, ethyl-b -naphthol ether and diphenyl ether. The fibres or foils may be passed at a draw-off speed of 10-2,000 metres per minute with a path of immersion of 0,5-10 cm. through a bath containing the swelling agent at the required temperature. Excess swelling agent may then be removed by passing the fibres and foils over a surface heated to 200 DEG -350 DEG C., by passing them through a current of air at a corresponding temperature, by subjecting them to infra-red radiations or by washing, and they may then be chilled in a bath of cold water. Alternatively the fibres or foils may be treated with the swelling agent and heated to the required temperature or the swelling agent may be applied in the gaseous state. The stiffness and pulling resistance of fibres may be modified by regulating the tension in the fibres during treatment with the swelling agent. Unfixed polyester continuous filaments which are allowed to shrink during the treatment with the swelling agent may be treated. Specifications 609,943, 609,944, 609,945, 609,946, 609,947, 697,983, 697,984, 697,985 and 697,986 also are referred to.ALSO:Fibres and foils made from linear aromatic polyesters, e.g polyethylene glycol terephthalate, are treated for a period within the range of 10-4 second to 5 seconds at a temperature above 200 DEG C., e.g. 200 DEG C.,350 DEG C., with a chemical substance which acts as a swelling agent for the polyester under the conditions of the process but does not react chemically therewith, either as such or in the presence of an organic solvent, to improve their dyeing capacity, especially with dispersion dyestuffs. The swelling agent may be an ester, ether, ketone or nitrile, e.g. the dimethyl and diethyl esters of sebacic, azelaic and suberic acids, benzophenone, adipic acid dinitrile, ethyl-b -naphthol ether and diphenyl ether. The fibres or foils may be passed at a drawoff speed of 10-2000 metres per minute with a path of immersion of 0.5-10 cm. through a bath containing the swelling agent at the required temperature. Excess swelling agent may then be removed by passing the fibres and foils over a surface heated to 200 DEG -350 DEG C., by passing them through a current of air at a corresponding temperature, by subjecting them to infra-red radiations or by washing, and they may then be chilled in a bath of cold water. Alternatively the fibres or foils may be treated with the swelling agent and heated to the required temperature or the swelling agent may be applied in the gaseous state. The stiffness and pulling resistance of fibres may be modified by regulating the tension in the fibres during treatment with the swelling agent. Unfixed polyester continuous filaments which are allowed to shrink during the treatment with the swelling agent may be treated. Specifications 609,943, 609,944, 609,945, 609,946, 609,947, 609,948, 697,983, 697,984, 697,985 and 697,986 are referred to.
GB8870/59A 1954-09-09 1959-03-13 Process for modifying the properties of fibres and foils of aromatic polyesters Expired GB911791A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEF15668A DE1044756B (en) 1954-09-09 1954-09-09 Process for changing the properties of molded structures made from high-polymer polymethylene terephthalates
DEF25242A DE1151780B (en) 1954-09-09 1958-03-13 Process for changing the properties of molded articles made from high polymer polyesters
DEF33508A DE1217915B (en) 1954-09-09 1961-03-25 Process for changing the properties of molded articles made from high polymer polyesters

Publications (1)

Publication Number Publication Date
GB911791A true GB911791A (en) 1962-11-28

Family

ID=27210034

Family Applications (3)

Application Number Title Priority Date Filing Date
GB25790/55A Expired GB822483A (en) 1954-09-09 1955-09-08 Process for modifying the properties of fibres and foils of aromatic polyesters
GB8870/59A Expired GB911791A (en) 1954-09-09 1959-03-13 Process for modifying the properties of fibres and foils of aromatic polyesters
GB11503/62A Expired GB985143A (en) 1954-09-09 1962-03-26 Process for modifying the properties of fibres and films made from polymeric polyesters

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB25790/55A Expired GB822483A (en) 1954-09-09 1955-09-08 Process for modifying the properties of fibres and foils of aromatic polyesters

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB11503/62A Expired GB985143A (en) 1954-09-09 1962-03-26 Process for modifying the properties of fibres and films made from polymeric polyesters

Country Status (7)

Country Link
US (1) US3154374A (en)
AT (1) AT281753B (en)
CH (3) CH348462A (en)
DE (3) DE1044756B (en)
FR (2) FR1145163A (en)
GB (3) GB822483A (en)
NL (3) NL276197A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1285665B (en) * 1963-09-23 1968-12-19 Ici Ltd Synthetic linear polymer fiber and process for their manufacture

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NL109801C (en) * 1954-09-09
BE586792A (en) * 1959-01-21
US3099515A (en) * 1959-07-08 1963-07-30 Ici Ltd Silicon chloride treated polyolefin article and its production
BE604582A (en) * 1960-06-03 1900-01-01
BE632939A (en) * 1962-08-08
US3704322A (en) * 1969-09-24 1972-11-28 Malesci S A S Inst Farmacobiol N-alkyl-n'-(1-naphthoyl) ethylene diamines
CA962158A (en) * 1971-03-11 1975-02-04 Unilever Limited Detergent compositions
US3957434A (en) * 1974-12-16 1976-05-18 Ciba-Geigy Corporation Coloring synthetic fibers with diphenylcarbinol dyeing assistants
US4421513A (en) * 1979-01-08 1983-12-20 Milliken Research Corporation Process for producing fibrillated polyester
US4238191A (en) * 1979-11-26 1980-12-09 Burlington Industries, Inc. Bulking of polycarbonamides: qiana
US4308025A (en) * 1979-11-26 1981-12-29 Burlington Industries, Inc. Simultaneous bulking and dyeing process
DE3347684A1 (en) * 1983-12-31 1985-08-29 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING PLASTIC FILMS WITH IMPROVED OPTICAL PROPERTIES
US6228488B1 (en) 1998-05-22 2001-05-08 Alliedsignal Inc. Process for making load limiting yarn
US6071835A (en) * 1998-06-16 2000-06-06 Alliedsignal Inc. Load limiting webbing
US8372912B2 (en) 2005-08-12 2013-02-12 Eastman Chemical Company Polyvinyl chloride compositions
EP2377905A1 (en) 2006-08-30 2011-10-19 Eastman Chemical Company Terephthalates as plasticizers in vinyl acetate polymer compositions
EP2057243B1 (en) 2006-08-30 2013-01-23 Eastman Chemical Company Sealant compositions having a novel plasticizer

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
GB609943A (en) * 1946-03-26 1948-10-08 Alan Stanley Fern Dyeing of highly polymeric linear esters
GB609948A (en) * 1946-06-06 1948-10-08 Alan Stanley Fern Dyeing of highly polymeric linear esters
BE491101A (en) * 1948-09-15
GB684046A (en) * 1950-06-12 1952-12-10 Richard Hardwick Improvements in or relating to the dyeing of aromatic polyester fibres, filaments, yarns, fabrics, films and like shaped articles
GB697986A (en) * 1950-11-27 1953-10-07 Denys Nicol Marvin Improvements in dyeing polyester filaments, yarns and fabrics
GB697983A (en) * 1950-11-27 1953-10-07 Denys Nicol Marvin Improvements in dyeing polyester filaments, yarns and fabrics
NL188863B (en) * 1953-08-03 Rheinhold & Mahla Gmbh SOUND-DAMPING AND PROTECTIVE CONNECTION OF PLATES.
US2881045A (en) * 1954-06-17 1959-04-07 American Cyanamid Co Method of dyeing synthetic fibrous materials
US2856638A (en) * 1954-07-20 1958-10-21 Eastman Kodak Co Process for the after-treatment of polymeric articles
NL109801C (en) * 1954-09-09
US2901311A (en) * 1955-03-04 1959-08-25 Hoechst Ag Process for the printing of fibrous textile material made of polyester fibres
US3034847A (en) * 1957-10-01 1962-05-15 Du Pont Dyeing polyethylene terephthalate films with hot disperse dye-organic solvent mixture
US2938811A (en) * 1959-11-09 1960-05-31 Martin Proc Company Inc Method of conditioning polyester textile material and the resulting products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1285665B (en) * 1963-09-23 1968-12-19 Ici Ltd Synthetic linear polymer fiber and process for their manufacture
DE1297281B (en) * 1963-09-23 1969-06-12 Ici Ltd Synthetic linear polymer fiber and process for their manufacture

Also Published As

Publication number Publication date
FR69375E (en) 1958-11-06
DE1044756B (en) 1958-11-27
US3154374A (en) 1964-10-27
GB985143A (en) 1965-03-03
CH348462A (en) 1960-08-31
AT281753B (en) 1970-06-10
FR1145163A (en) 1957-10-23
CH7056859A4 (en) 1964-02-28
NL200307A (en)
GB822483A (en) 1959-10-28
CH440695A (en) 1967-07-31
NL109801C (en)
DE1151780B (en) 1963-07-25
DE1217915B (en) 1966-06-02
NL276197A (en)
CH378278A (en) 1964-07-31

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