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GB888669A - Sulphides and sulphoxides and method of preparation - Google Patents

Sulphides and sulphoxides and method of preparation

Info

Publication number
GB888669A
GB888669A GB25657/59A GB2565759A GB888669A GB 888669 A GB888669 A GB 888669A GB 25657/59 A GB25657/59 A GB 25657/59A GB 2565759 A GB2565759 A GB 2565759A GB 888669 A GB888669 A GB 888669A
Authority
GB
United Kingdom
Prior art keywords
reacting
sulphides
give
allyl
cyclo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25657/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of GB888669A publication Critical patent/GB888669A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/12—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/22—Thiols, sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises compounds of the formula R1XR2, where X is S or SO, R1 is an alkyl or octyl radical and R2 is one of the radicals <FORM:0888669/IV (b)/1> <FORM:0888669/IV (b)/2> <FORM:0888669/IV (b)/3> <FORM:0888669/IV (b)/4> <FORM:0888669/IV (b)/5> <FORM:0888669/IV (b)/6> where Y is S or SO and represents the same radical as X in any particular compound. The compounds may be prepared by (1) reacting 4-vinyl-cyclohexane or 1,5-cyclo-octadiene with allyl or octyl mercaptan in the presence of ultra-violet or ionising rays to give sulphides; (2) reacting 4-vinyl-cyclohexene or 1,5-cyclooctadiene with hydrogen sulphide in the presence of ultra-violet or ionising rays and then reacting the mono- or di-adduct thus formed with allyl or octyl bromide in the presence of an alkali metal base to give sulphides; (3) reacting 4-cyclo-octene-1-thiol with allyl bromide in the presence of an alkali metal base to give allyl-5-cyclo-octenyl sulphide; and (4) reacting sulphides prepared by any of these methods with an oxidising agent, e.g. hydrogen peroxide, to give sulphoxides. Examples are given.
GB25657/59A 1958-10-10 1959-07-27 Sulphides and sulphoxides and method of preparation Expired GB888669A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US888669XA 1958-10-10 1958-10-10

Publications (1)

Publication Number Publication Date
GB888669A true GB888669A (en) 1962-01-31

Family

ID=22213945

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25657/59A Expired GB888669A (en) 1958-10-10 1959-07-27 Sulphides and sulphoxides and method of preparation

Country Status (1)

Country Link
GB (1) GB888669A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2039356A1 (en) * 1969-08-08 1971-02-18 Pennwalt Corp Cycloaliphatic sulfides to stabilize polyolines
FR2478091A1 (en) * 1980-03-11 1981-09-18 Mitsui Toatsu Chemicals 2,2-Bisphenol sulphoxide derivs. prepn. - by oxidn. of 2,2-bisphenol sulphide with hydrogen peroxide in organic solvent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2039356A1 (en) * 1969-08-08 1971-02-18 Pennwalt Corp Cycloaliphatic sulfides to stabilize polyolines
FR2478091A1 (en) * 1980-03-11 1981-09-18 Mitsui Toatsu Chemicals 2,2-Bisphenol sulphoxide derivs. prepn. - by oxidn. of 2,2-bisphenol sulphide with hydrogen peroxide in organic solvent

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