GB888337A - Improvements in fluorescent lamps and phosphor compositions therefor - Google Patents
Improvements in fluorescent lamps and phosphor compositions thereforInfo
- Publication number
- GB888337A GB888337A GB2210159A GB2210159A GB888337A GB 888337 A GB888337 A GB 888337A GB 2210159 A GB2210159 A GB 2210159A GB 2210159 A GB2210159 A GB 2210159A GB 888337 A GB888337 A GB 888337A
- Authority
- GB
- United Kingdom
- Prior art keywords
- activated
- manganese
- luminescent material
- region
- emission peak
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000000463 material Substances 0.000 abstract 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 8
- 229910052748 manganese Inorganic materials 0.000 abstract 8
- 239000011572 manganese Substances 0.000 abstract 8
- 239000011248 coating agent Substances 0.000 abstract 4
- 238000000576 coating method Methods 0.000 abstract 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004110 Zinc silicate Substances 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- QWTSUIVNFZQZJV-UHFFFAOYSA-H barium(2+);titanium(4+);diphosphate Chemical compound [Ti+4].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QWTSUIVNFZQZJV-UHFFFAOYSA-H 0.000 abstract 1
- HVCJNUXSXRYNNS-UHFFFAOYSA-N beryllium;zinc;silicate Chemical compound [Be+2].[Zn+2].[O-][Si]([O-])([O-])[O-] HVCJNUXSXRYNNS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- QGKBPWOLFJRLKE-UHFFFAOYSA-J distrontium;phosphonato phosphate Chemical compound [Sr+2].[Sr+2].[O-]P([O-])(=O)OP([O-])([O-])=O QGKBPWOLFJRLKE-UHFFFAOYSA-J 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- -1 magnesium fluoroborate Chemical compound 0.000 abstract 1
- DJZHPOJZOWHJPP-UHFFFAOYSA-N magnesium;dioxido(dioxo)tungsten Chemical compound [Mg+2].[O-][W]([O-])(=O)=O DJZHPOJZOWHJPP-UHFFFAOYSA-N 0.000 abstract 1
- WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000001228 spectrum Methods 0.000 abstract 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 abstract 1
- 238000001429 visible spectrum Methods 0.000 abstract 1
- 235000019352 zinc silicate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/66—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/67—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals
- C09K11/68—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals containing chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/74—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/74—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing arsenic, antimony or bismuth
- C09K11/75—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing arsenic, antimony or bismuth containing antimony
- C09K11/76—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing arsenic, antimony or bismuth containing antimony also containing phosphorus and halogen, e.g. halophosphates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7715—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing cerium
- C09K11/7726—Borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/38—Devices for influencing the colour or wavelength of the light
- H01J61/42—Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
- H01J61/44—Devices characterised by the luminescent material
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
Abstract
888,337. Discharge lamps; luminescent materials. THORN ELECTRICAL INDUSTRIES Ltd. June 23, 1960 [June 26, 1959], No. 22101/59. Drawings to Specification. Class 39(1) A low pressure fluorescent discharge lamp, containing mercury and argon or other rare gas or mixture of such gases, has a phosphor coating which includes at least 15% by weight of a first luminescent material having in operation of the lamp an emission peak in the region 6500-6700A, at least 15% of a second luminescent material having an emission peak in the region 6000-6500Š, the first and second materials amounting in total to not more than 70% by weight of the coating, and at least one further luminescent material emitting over a wide band of the visible spectrum including the blue region of the spectrum. The first material can be activated by manganese alone, e.g. magnesium arsenate or fluorogermanate; the second material can be activated by manganese and a second metal, e.g. calcium silicate activated by lead and manganese or magnesium fluoroborate activated by cerium and manganese; and the further luminescent material can be manganese free, e.g. barium titanium phosphate, magnesium tungstate or a mixture thereof, calcium halophosphate activated by antimony, or strontium pyrophosphate activated by tin. Cardmium borate activated by manganese or zinc beryllium silicate activated by manganese may also be used as the second luminescent material. The phosphor coating can include an additional further luminescent material having an emission peak in the region of 5900Š, e.g. calcium halophosphate activated by antimony and manganese zinc silicate activated by manganese can also be added. Several specific examples of the composition of the phosphor coating are described.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2210159A GB888337A (en) | 1959-06-26 | 1959-06-26 | Improvements in fluorescent lamps and phosphor compositions therefor |
| BE592264A BE592264A (en) | 1959-06-26 | 1960-06-24 | Fluorescent Lamp Improvements |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2210159A GB888337A (en) | 1959-06-26 | 1959-06-26 | Improvements in fluorescent lamps and phosphor compositions therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB888337A true GB888337A (en) | 1962-01-31 |
Family
ID=10173918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2210159A Expired GB888337A (en) | 1959-06-26 | 1959-06-26 | Improvements in fluorescent lamps and phosphor compositions therefor |
Country Status (2)
| Country | Link |
|---|---|
| BE (1) | BE592264A (en) |
| GB (1) | GB888337A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4296353A (en) * | 1979-10-29 | 1981-10-20 | Gte Products Corporation | Fluorescent lamp having high color rendering index |
-
1959
- 1959-06-26 GB GB2210159A patent/GB888337A/en not_active Expired
-
1960
- 1960-06-24 BE BE592264A patent/BE592264A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4296353A (en) * | 1979-10-29 | 1981-10-20 | Gte Products Corporation | Fluorescent lamp having high color rendering index |
Also Published As
| Publication number | Publication date |
|---|---|
| BE592264A (en) | 1960-10-17 |
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