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GB884673A - Dihydrazide-formaldehyde condensates suitable for treating textiles - Google Patents

Dihydrazide-formaldehyde condensates suitable for treating textiles

Info

Publication number
GB884673A
GB884673A GB15020/58A GB1502058A GB884673A GB 884673 A GB884673 A GB 884673A GB 15020/58 A GB15020/58 A GB 15020/58A GB 1502058 A GB1502058 A GB 1502058A GB 884673 A GB884673 A GB 884673A
Authority
GB
United Kingdom
Prior art keywords
acid
dihydrazide
formaldehyde
conhnh2
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15020/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olin Corp
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olin Corp filed Critical Olin Corp
Publication of GB884673A publication Critical patent/GB884673A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423Amino-aldehyde resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/22Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with carboxylic acid amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

An aqueous solution for treating textiles contains at least 2% by weight of a condensate made by reacting 4-20 mols. of formaldehyde at a pH of 6-11 with one mol. of a dihydrazide-R(CONHNH2)2, where R is an alkylene radical of 2-6 carbon atoms interrupted by 1 or 2 oxygen or sulphur atoms. Suitable dihydrazides are those of diglycollic acid, thiodiglycollic acid, oxy-dipropionic acid, HOOCCH2OCH2CH2 OCH2COOH, or of 3-(2-carboxy-ethoxy)-propionic acid. Mixtures of dihydrazides may be used. Catalysts may be added to the treating bath to facilitate curing of the resin on the textile. Suitable catalysts are magnesium chloride-, aluminium chloride formate or tartrate; p-toluene sulphonic acid or its ammonium or amine salts; methylamine or piperidine hydrochloride. Specification 882,998 is referred to.ALSO:Cellulosic textile materials are rendered resistant to creasing and wrinkling by impregnation with an aqueous condensate of formaldehyde with a dihydrazide, R(CONHNH2)2 in which R is alkylene with 2-6 carbon atoms interrupted by 1 or 2 oxygen or sulphur atoms (see Group IV (a) ), followed by heating to dry and cure the polymer. About 0.1% to 2% of catalyst may be incorporated in the treating bath. A number of detailed examples of treatment of cotton, linen and regenerated cellulose fabrics are given, with comparative figures for physical properties of the treated fabrics. Specification 882,998 is referred to.
GB15020/58A 1957-05-10 1958-05-09 Dihydrazide-formaldehyde condensates suitable for treating textiles Expired GB884673A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US884673XA 1957-05-10 1957-05-10

Publications (1)

Publication Number Publication Date
GB884673A true GB884673A (en) 1961-12-13

Family

ID=22211548

Family Applications (1)

Application Number Title Priority Date Filing Date
GB15020/58A Expired GB884673A (en) 1957-05-10 1958-05-09 Dihydrazide-formaldehyde condensates suitable for treating textiles

Country Status (1)

Country Link
GB (1) GB884673A (en)

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