GB485593A - Process for imparting hydrophobic properties to fibrous materials or like substances - Google Patents
Process for imparting hydrophobic properties to fibrous materials or like substancesInfo
- Publication number
- GB485593A GB485593A GB32028/36A GB3202836A GB485593A GB 485593 A GB485593 A GB 485593A GB 32028/36 A GB32028/36 A GB 32028/36A GB 3202836 A GB3202836 A GB 3202836A GB 485593 A GB485593 A GB 485593A
- Authority
- GB
- United Kingdom
- Prior art keywords
- wool
- acid
- impregnated
- piece goods
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000126 substance Substances 0.000 title abstract 3
- 239000002657 fibrous material Substances 0.000 title abstract 2
- 230000002209 hydrophobic effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 8
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 7
- 210000002268 wool Anatomy 0.000 abstract 7
- 229950005499 carbon tetrachloride Drugs 0.000 abstract 4
- 239000004310 lactic acid Substances 0.000 abstract 4
- 235000014655 lactic acid Nutrition 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- -1 aliphatic monocarboxylic acid Chemical class 0.000 abstract 3
- 150000003672 ureas Chemical class 0.000 abstract 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 abstract 2
- 229920002955 Art silk Polymers 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- CUEORHYJAFVTBP-UHFFFAOYSA-N N-(hydroxymethyl)octacosanamide Chemical compound C(O)NC(CCCCCCCCCCCCCCCCCCCCCCCCCCC)=O CUEORHYJAFVTBP-UHFFFAOYSA-N 0.000 abstract 2
- 239000005018 casein Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- 238000002203 pretreatment Methods 0.000 abstract 2
- SVJAXDXGMZZFAV-UHFFFAOYSA-N 1-aminodocosan-5-one Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)CCCCN SVJAXDXGMZZFAV-UHFFFAOYSA-N 0.000 abstract 1
- WIVHXBTXQHIXTJ-UHFFFAOYSA-N 1-aminononadecan-2-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)CN WIVHXBTXQHIXTJ-UHFFFAOYSA-N 0.000 abstract 1
- CREJEBKGIOQGHR-UHFFFAOYSA-N 1-heptadecyl-1-(hydroxymethyl)urea Chemical compound C(O)N(C(=O)N)CCCCCCCCCCCCCCCCC CREJEBKGIOQGHR-UHFFFAOYSA-N 0.000 abstract 1
- GVHSESMJDQCNGP-UHFFFAOYSA-N 36-aminohexatriacontan-18-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCCCN GVHSESMJDQCNGP-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- ZFIVKAOQEXOYFY-UHFFFAOYSA-N Diepoxybutane Chemical compound C1OC1C1OC1 ZFIVKAOQEXOYFY-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000001828 Gelatine Substances 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 210000004209 hair Anatomy 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 abstract 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 abstract 1
- AVFLUEGZVZQKTN-UHFFFAOYSA-N octadecyl n-(hydroxymethyl)carbamate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)NCO AVFLUEGZVZQKTN-UHFFFAOYSA-N 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 229920002994 synthetic fiber Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/17—Glyoxal and polyaldehyde treatment of textiles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2907—Staple length fiber with coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
Hydrophobic properties are imparted to fibrous materials comprising nitrogenous substances of high molecular weight and of colloidal character by incorporating with the fibres a urea derivative or an aliphatic monocarboxylic acid amide free from hydroxyl groups containing an alkyl group having at least 11 carbon atoms and then causing the compound on or in the fibres to react with an aliphatic aldehyde. Preformed condensation products may be used and acid substances may also be present in the treating baths. Suitable fibres include wool, natural silk, casein or gelatine artificial silks, animal hair, felts, bodies made from horn, tanned or untanned hides, and acetate artificial silk containing a basic nitrogenous polyvinyl resin. Suitable ureas or amides include lauric acid amide, stearoylmethylamide, stearoylbutylamide, stearoyloctadecylamide, or the corresponding methylol compounds. The process may be applied after a pre-treatment such as the treatment of wool with chlorine or hydrogen peroxide. In examples: (1) wool piece goods are treated in a bath containing lactic acid then in a carbon tetrachloride bath containing montanic acid methylolamide and then heated, (2) wool piece goods are impregnated in an ethyl alcohol-carbon tetrachloride bath containing stearic acid methylolamide and lactic acid and then heated, (3) wool piece goods are impregnated in a hot solution of montanic acid methylolamide in tetrachlorethane, (4) artificial fibres from rennet-casein are impregnated with a solution of N-heptadecyl-N1-methylolurea and lactic acid in alcohol and carbon tetrachloride and heated, (5) wool gabardine is impregnated with a solution of stearic acid amide in carbontetrachloride, dried, and impregnated with aqueous formaldehyde containing lactic acid and finally heated. The Specification as open to inspection under Sect. 91 refers also to pre-treatment of the fibre with ethylene oxide, propylene oxide, epichlorhydrin or similar compounds and contains examples of pretreating wool piece goods with ethylene oxide followed by treatment as in example (2) of the Specification as accepted and of pretreated dyed natural silk piece goods with butadiene dioxide followed by impregnation in a bath containing methylolcarbamic acid octadecyl ester in tetrachlorethane followed by drying. The Specification also refers to the use as urea derivative of mono-iso-butylurea. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI52329D DE762964C (en) | 1935-05-12 | 1935-05-12 | Process for making cellulose fibers water repellent |
| DE2111698X | 1935-09-28 | ||
| DE485593X | 1935-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB485593A true GB485593A (en) | 1938-05-23 |
Family
ID=32045547
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17898/35A Expired GB463300A (en) | 1935-05-12 | 1935-06-21 | Process of imparting hydrophobic properties to cellulose fibres |
| GB4212/37A Expired GB463472A (en) | 1935-05-12 | 1935-06-21 | Process of imparting hydrophobic properties to cellulose fibres |
| GB30934/35A Expired GB467166A (en) | 1935-05-12 | 1935-11-08 | Process of imparting hydrophobic properties to cellulose fibres |
| GB32028/36A Expired GB485593A (en) | 1935-05-12 | 1936-11-23 | Process for imparting hydrophobic properties to fibrous materials or like substances |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17898/35A Expired GB463300A (en) | 1935-05-12 | 1935-06-21 | Process of imparting hydrophobic properties to cellulose fibres |
| GB4212/37A Expired GB463472A (en) | 1935-05-12 | 1935-06-21 | Process of imparting hydrophobic properties to cellulose fibres |
| GB30934/35A Expired GB467166A (en) | 1935-05-12 | 1935-11-08 | Process of imparting hydrophobic properties to cellulose fibres |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US2165265A (en) |
| BE (3) | BE415480A (en) |
| DE (1) | DE762964C (en) |
| FR (3) | FR806170A (en) |
| GB (4) | GB463300A (en) |
| NL (3) | NL45055C (en) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE907163C (en) * | 1938-06-07 | 1954-03-22 | Hoechst Ag | Process for making natural fibers of animal or vegetable origin or artificial fibers water-repellent |
| US2423185A (en) * | 1939-07-08 | 1947-07-01 | Hydronapthene Corp | Process for the manufacture of coated and impregnated materials |
| DE766083C (en) * | 1940-01-26 | 1954-02-01 | Ig Farbenindustrie Ag | Preparations for refining fiber materials |
| US2418696A (en) * | 1942-03-09 | 1947-04-08 | Courtaulds Ltd | Modifying the dyeing properties of cellulose or cellulose derivative textile materials |
| US2451426A (en) * | 1943-11-25 | 1948-10-12 | Du Pont | Bright zinc plating |
| US2446864A (en) * | 1944-06-26 | 1948-08-10 | Quaker Chemical Products Corp | Composition and process for imparting durable water repellent finish to textiles |
| NL60268C (en) * | 1944-08-14 | 1947-11-15 | ||
| US2510522A (en) * | 1944-12-09 | 1950-06-06 | Montclair Res Corp | Textile treating products and process of making |
| US2431202A (en) * | 1945-03-01 | 1947-11-18 | Gen Aniline & Film Corp | Self-dispersing methylolstear-amides |
| US2594384A (en) * | 1946-11-12 | 1952-04-29 | Monsanto Chemicals | Fungi and bacteria resistant papermakers' felts and process for preparing same |
| US2507700A (en) * | 1946-11-27 | 1950-05-16 | Monsanto Chemicals | N, n', n''-triacylmelamines |
| US2540726A (en) * | 1946-12-03 | 1951-02-06 | Du Pont | Treatment of a heat set, oriented nylon fabric with formaldehyde |
| US2565194A (en) * | 1947-03-27 | 1951-08-21 | American Cyanamid Co | Chlorotriazine resins and process of making the same |
| NL71674C (en) * | 1947-08-14 | |||
| US2562161A (en) * | 1948-02-06 | 1951-07-31 | Cluett Peabody & Co Inc | Stabilization of regenerated cellulose fabric with glyoxal-amide reaction product |
| US2574114A (en) * | 1948-04-26 | 1951-11-06 | Bozel Maletra Prod Chimiques | Amide-glyoxal-formaldehyde reaction product and shrinkproofing cellulose textile fibers therewith |
| US2608494A (en) * | 1948-08-28 | 1952-08-26 | Walkden Makin & Co Ltd | Treatment of textile fabrics for imparting antishrink properties thereto |
| US2600698A (en) * | 1948-11-13 | 1952-06-17 | Monsanto Chemicals | Reaction products from an aldehyde, an aminotriazine, and a mono-nheterocyclic compound |
| US2641558A (en) * | 1948-12-24 | 1953-06-09 | Nat Lead Co | Water repellence fixative treatment |
| US2805196A (en) * | 1952-02-11 | 1957-09-03 | Tno | Permselective electrodialysis |
| US3128272A (en) * | 1957-06-11 | 1964-04-07 | Minnesota Mining & Mfg | Perfluoroalkyl-substituted triazines |
| NL114029C (en) * | 1958-02-20 | |||
| US3232697A (en) * | 1959-07-01 | 1966-02-01 | Nalco Chemical Co | Textile treatment |
| NL272600A (en) * | 1960-12-17 | |||
| US3112155A (en) * | 1962-02-02 | 1963-11-26 | Sidney L Vail | Glyoxal-amide reaction products |
| US4103051A (en) * | 1975-11-03 | 1978-07-25 | Milliken Research Corporation | Pilling reduction in textiles |
| DE2757582A1 (en) * | 1977-12-23 | 1979-06-28 | Cassella Ag | METHOD FOR THE PRODUCTION OF STORAGE-STABLE AQUEOUS EMULSIONS OF N.ALKYL-N'-ALKYLOL UREAS AND THEIR APPLICATION FOR SOFTENING LEATHER AND TEXTILE MATERIAL |
| US4295930A (en) * | 1980-03-17 | 1981-10-20 | Nalco Chemical Company | Alkoxylated dioxolanes as paper sizing agents |
| US4563288A (en) * | 1982-08-03 | 1986-01-07 | Colgate-Palmolive Company | N-Alkyl isostearamide antistatic agents, detergent compositions containing such agents, and processes for washing laundry in the presence of such agents, and with such compositions |
| US4497715A (en) * | 1982-08-03 | 1985-02-05 | Colgate-Palmolive Company | N-Alkylisostearamides as antistatic agents |
| US7713215B2 (en) * | 2008-01-31 | 2010-05-11 | Shriver Edgar L | Steering, piercing, anchoring, distending extravascular guidewire |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE219848C (en) * | 1906-04-24 | |||
| AT118595B (en) * | 1926-12-01 | 1930-07-25 | Tootal Broadhurst Lee Co Ltd | Process for impregnating textile yarns, fabrics and fabrics with synthetic resins. |
| DE542186C (en) * | 1929-06-14 | 1932-01-21 | Alexander Nathansohn Dr | Process for waterproofing raw, chemically uncleaned textile fibers |
| FR751641A (en) * | 1932-02-29 | 1933-09-07 | Ig Farbenindustrie Ag | Process for the preparation of auxiliary condensation products |
| AT136377B (en) * | 1933-01-13 | 1934-01-25 | Heberlein & Co Ag | Finishing process for vegetable textiles. |
-
0
- BE BE417657D patent/BE417657A/xx unknown
- BE BE418549D patent/BE418549A/xx unknown
-
1935
- 1935-05-12 DE DEI52329D patent/DE762964C/en not_active Expired
- 1935-06-21 GB GB17898/35A patent/GB463300A/en not_active Expired
- 1935-06-21 GB GB4212/37A patent/GB463472A/en not_active Expired
- 1935-11-08 GB GB30934/35A patent/GB467166A/en not_active Expired
-
1936
- 1936-05-06 NL NL77672A patent/NL45055C/xx active
- 1936-05-11 FR FR806170D patent/FR806170A/en not_active Expired
- 1936-05-11 BE BE415480D patent/BE415480A/xx unknown
- 1936-05-21 US US81122A patent/US2165265A/en not_active Expired - Lifetime
- 1936-09-22 NL NL79327A patent/NL44056C/xx active
- 1936-09-24 US US102300A patent/US2111698A/en not_active Expired - Lifetime
- 1936-09-28 FR FR47692D patent/FR47692E/en not_active Expired
- 1936-11-23 GB GB32028/36A patent/GB485593A/en not_active Expired
- 1936-11-23 FR FR813868D patent/FR813868A/en not_active Expired
-
1937
- 1937-09-28 US US166224A patent/US2211976A/en not_active Expired - Lifetime
-
1938
- 1938-03-31 NL NL87184A patent/NL50083C/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| BE418549A (en) | |
| US2111698A (en) | 1938-03-22 |
| NL45055C (en) | 1939-02-15 |
| FR813868A (en) | 1937-06-10 |
| BE415480A (en) | 1936-06-30 |
| GB463300A (en) | 1937-03-22 |
| NL44056C (en) | 1938-09-15 |
| US2211976A (en) | 1940-08-20 |
| NL50083C (en) | 1941-04-15 |
| FR806170A (en) | 1936-12-09 |
| DE762964C (en) | 1953-11-30 |
| FR47692E (en) | 1937-06-16 |
| BE417657A (en) | |
| US2165265A (en) | 1939-07-11 |
| GB463472A (en) | 1937-03-22 |
| GB467166A (en) | 1937-06-08 |
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