GB864618A - A process for the production of alkali metal and alkaline earth metal borohydrides - Google Patents
A process for the production of alkali metal and alkaline earth metal borohydridesInfo
- Publication number
- GB864618A GB864618A GB41226/60A GB4122660A GB864618A GB 864618 A GB864618 A GB 864618A GB 41226/60 A GB41226/60 A GB 41226/60A GB 4122660 A GB4122660 A GB 4122660A GB 864618 A GB864618 A GB 864618A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- hydrocarbon
- substituted
- alkaline earth
- borine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052784 alkaline earth metal Inorganic materials 0.000 title abstract 5
- 150000001342 alkaline earth metals Chemical class 0.000 title abstract 3
- 229910052783 alkali metal Inorganic materials 0.000 title 1
- 150000001340 alkali metals Chemical class 0.000 title 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- -1 alkaline earth metal hydrocarbon Chemical class 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 229910000085 borane Inorganic materials 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 150000003512 tertiary amines Chemical class 0.000 abstract 2
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- GWESVXSMPKAFAS-UHFFFAOYSA-N Isopropylcyclohexane Chemical compound CC(C)C1CCCCC1 GWESVXSMPKAFAS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
Abstract
Alkali or alkaline earth metal borohydrides are prepared by reacting an alkali or alkaline earth metal hydrocarbon with a substituted diborane containing up to 4 hydrocarbon radicals, or a substituted borine BRR12 where, R is a hydrocarbon radical and R1 is hydrocarbon or H. Where the substituted borine contains no H, then H2 must be present for reaction. Reaction may be effected in inert organic liquid aliphatic or aromatic hydrocarbons, ethers, or tertiary amines, e.g. hexane, benzene, perhydrocumene, tetrahydrofuran, or diglycol dimethyl-or triglycol trimethylethers. If reactants and products are insoluble in the liquid, reaction may be effected with simultaneous comminution, e.g. in a ball mill. Where ethers are used the borohydride is formed as an etherate, and with tertiary amines the reaction may be under pressure at above 160 DEG C. Reaction may be in inert gas, e.g. N2 or A, with heat, with, or without, distilling or filtering off the boron hydrocarbon also formed, and the substituted borine, or diborane, should be in excess. The boron trihydrocarbons formed may be hydrogenated to borines as in Specification 854,919. Colloidal B formed in the p reaction may be washed out with solvent. In examples:- (1) Mg(CH3)2 is reacted with B(C2H5)3 an H2; and (2) Li C6H5 is reacted with B(n-C4H9)3 and H2.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE864618X | 1957-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB864618A true GB864618A (en) | 1961-04-06 |
Family
ID=6801699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB41226/60A Expired GB864618A (en) | 1957-03-08 | 1957-03-28 | A process for the production of alkali metal and alkaline earth metal borohydrides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB864618A (en) |
-
1957
- 1957-03-28 GB GB41226/60A patent/GB864618A/en not_active Expired
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