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GB855720A - Method of making oriented graft polymer structures containing polymerized olefins - Google Patents

Method of making oriented graft polymer structures containing polymerized olefins

Info

Publication number
GB855720A
GB855720A GB8850/59A GB885059A GB855720A GB 855720 A GB855720 A GB 855720A GB 8850/59 A GB8850/59 A GB 8850/59A GB 885059 A GB885059 A GB 885059A GB 855720 A GB855720 A GB 855720A
Authority
GB
United Kingdom
Prior art keywords
graft copolymer
fluid medium
ozone
dimension
graft polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8850/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB855720A publication Critical patent/GB855720A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/10Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Abstract

Oriented graft copolymer structures, e.g. fibres, filaments and films, are made by subjecting a structure made from polyethylene or polypropylene in the form of a thin elongated body having one dimension not exceeding 0,1 inch and at least one dimension greater than 2 inches to the action of ozone in an inert fluid medium containing at least 0,05% by volume of ozone gas per unit volume of inert fluid medium, then reacting the ozonised structure with acrylonitrile at temperatures between 25 DEG and 220 DEG C. whereby a graft copolymer having polymer chains of acrylonitrile attached to the polyolefin is formed, and orienting the resulting graft copolymer structure by stretching it in at least one of its dimensions by an amount of at least 10% of the initial dimension. The fluid medium in which the ozone is contained may be gaseous, e.g. air or oxygen, or liquid, e.g. an organic liquid such as carbon tetrachloride, chloroform, methylene chloride or ethyl alcohol which swells but does not dissolve the polymer. Reference has been directed by the Comptroller to Specifications 791,453 and 825,680.
GB8850/59A 1958-04-07 1959-03-13 Method of making oriented graft polymer structures containing polymerized olefins Expired GB855720A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US855720XA 1958-04-07 1958-04-07

Publications (1)

Publication Number Publication Date
GB855720A true GB855720A (en) 1960-12-07

Family

ID=22192516

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8850/59A Expired GB855720A (en) 1958-04-07 1959-03-13 Method of making oriented graft polymer structures containing polymerized olefins

Country Status (2)

Country Link
FR (1) FR1222101A (en)
GB (1) GB855720A (en)

Also Published As

Publication number Publication date
FR1222101A (en) 1960-06-08

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