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GB842586A - Production of cumene hydroperoxide - Google Patents

Production of cumene hydroperoxide

Info

Publication number
GB842586A
GB842586A GB204058A GB204058A GB842586A GB 842586 A GB842586 A GB 842586A GB 204058 A GB204058 A GB 204058A GB 204058 A GB204058 A GB 204058A GB 842586 A GB842586 A GB 842586A
Authority
GB
United Kingdom
Prior art keywords
cumene
oxidation
acid
cumene hydroperoxide
overhead fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB204058A
Inventor
Maurice Dudley Cooke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB204058A priority Critical patent/GB842586A/en
Priority to DED29739A priority patent/DE1114817B/en
Priority to FR1214012D priority patent/FR1214012A/en
Publication of GB842586A publication Critical patent/GB842586A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Cumene hydroperoxide, obtained by the oxidation of cumene, is concentrated by submitting the crude oxidate to fractional distillation, withdrawing an overhead fraction containing unreacted cumene and acid by-products and recycling this acidic fraction to the oxidation, adding "fresh cumene" (i.e. cumene which contains substantially no acid or water) to the fractionator as liquid reflux, and withdrawing concentrated cumene hydroperoxide from the still. The overhead fraction is preferably separated from aqueous liquid and washed with alkali, in order to remove acid, before it is recycled to the oxidation. In a preferred embodiment, the concentration is carried out in two stages in series, the overhead fraction from the first stage being recycled to the oxidation, and part of the overhead fraction from the second stage (i.e. dry cumene substantially free from acid) being used as reflux liquid for both stages. In an example, a cumene oxidation product containing 23,4% by weight of cumene hydroperoxide and having a pH of 9 is concentrated in two stages, both of which consist of a climbing film evaporator combined with a fractionator. The final concentrate contains 82,5% by weight of cumene hydroperoxide and has a pH of 6,5.
GB204058A 1958-01-21 1958-01-21 Production of cumene hydroperoxide Expired GB842586A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB204058A GB842586A (en) 1958-01-21 1958-01-21 Production of cumene hydroperoxide
DED29739A DE1114817B (en) 1958-01-21 1959-01-10 Process for the enrichment of cumene hydroperoxide
FR1214012D FR1214012A (en) 1958-01-21 1959-01-14 Production of cumene hydroperoxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB204058A GB842586A (en) 1958-01-21 1958-01-21 Production of cumene hydroperoxide

Publications (1)

Publication Number Publication Date
GB842586A true GB842586A (en) 1960-07-27

Family

ID=9732547

Family Applications (1)

Application Number Title Priority Date Filing Date
GB204058A Expired GB842586A (en) 1958-01-21 1958-01-21 Production of cumene hydroperoxide

Country Status (3)

Country Link
DE (1) DE1114817B (en)
FR (1) FR1214012A (en)
GB (1) GB842586A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2612849A1 (en) * 2012-01-05 2013-07-10 Borealis AG Improved cumene hydroperoxide concentration process
WO2014195746A1 (en) * 2013-06-07 2014-12-11 Rhodia Poliamida E Especialidades Ltda Process for the preparation of phenol/acetone from cumene
WO2014209578A1 (en) * 2013-06-28 2014-12-31 Exxonmobil Chemical Patents Inc. Process for concentrating a mixture containing organic hydroperoxide

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2722506A (en) * 1952-05-20 1955-11-01 California Research Corp Separation of cumene or cymene from its respective hydroperoxide by distillation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2612849A1 (en) * 2012-01-05 2013-07-10 Borealis AG Improved cumene hydroperoxide concentration process
WO2014195746A1 (en) * 2013-06-07 2014-12-11 Rhodia Poliamida E Especialidades Ltda Process for the preparation of phenol/acetone from cumene
WO2014209578A1 (en) * 2013-06-28 2014-12-31 Exxonmobil Chemical Patents Inc. Process for concentrating a mixture containing organic hydroperoxide
CN104250221A (en) * 2013-06-28 2014-12-31 埃克森美孚化学专利公司 Process for concentrating a mixture containing organic hydroperoxide
CN104250221B (en) * 2013-06-28 2016-04-27 埃克森美孚化学专利公司 The method of the concentrated mixture containing organic hydroperoxide
US9464047B2 (en) 2013-06-28 2016-10-11 Exxonmobil Chemical Patents Inc. Process for concentrating a mixture containing organic hydroperoxide
EP3327003A1 (en) * 2013-06-28 2018-05-30 ExxonMobil Chemical Patents Inc. Process for concentrating a mixture containing organic hydroperoxide

Also Published As

Publication number Publication date
DE1114817B (en) 1961-10-12
FR1214012A (en) 1960-04-05

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