GB835847A - Method of preparing boro-organic compounds - Google Patents
Method of preparing boro-organic compoundsInfo
- Publication number
- GB835847A GB835847A GB7998/58A GB799858A GB835847A GB 835847 A GB835847 A GB 835847A GB 7998/58 A GB7998/58 A GB 7998/58A GB 799858 A GB799858 A GB 799858A GB 835847 A GB835847 A GB 835847A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron
- organic
- compounds
- alkali metal
- metal hydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052796 boron Inorganic materials 0.000 abstract 7
- -1 boron halide Chemical class 0.000 abstract 5
- 229910000102 alkali metal hydride Inorganic materials 0.000 abstract 4
- 150000008046 alkali metal hydrides Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical group ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- PPWPWBNSKBDSPK-UHFFFAOYSA-N [B].[C] Chemical group [B].[C] PPWPWBNSKBDSPK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- LCWVIHDXYOFGEG-UHFFFAOYSA-N diboron tetrachloride Chemical compound ClB(Cl)B(Cl)Cl LCWVIHDXYOFGEG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229910000765 intermetallic Inorganic materials 0.000 abstract 1
- 229910052740 iodine Chemical group 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 125000005270 trialkylamine group Chemical group 0.000 abstract 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Organoboron compounds, containing at least one boron-carbon linkage, are prepared by reacting a boron halide (as hereinafter defined) with an alkali metal hydride and an olefinic or cyclic olefinic compound in the presence of an organic amine and of an organic boron or organic metallic compound capable of activating the alkali metal hydride. The term boron halide is defined as meaning any compound in which at least one chlorine, bromine or iodine atom is bound to a boron atom, examples being boron trichloride, diboron tetrachloride, alkyl boron halides or alkoxyboron halides. The alkali metal hydride is introduced in an inert dispersant and must be first transformed into an active soluble form. Suitable activators are the organic compounds of boron, aluminium or gallium, particularly the alkyls, alkyl hydrides and alcoholates thereof, and the presence of only 0.2% of these compounds, based on the alkali metal hydride, is sufficient, but 5 to 30% is preferred. If other organometallic compounds are employed, they will react with the boron halide to form boro-organic compounds. The organic amine used is preferably a tertiary amine such as trialkylamines, morpholine or piperidine. The reaction may be effected at temperatures up to 220 DEG C. in the presence of inert solvents, and at slightly elevated pressure. Specification 830,768 is referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK31389D DE1052986B (en) | 1957-03-13 | 1957-03-13 | Process for the preparation of organoboron compounds |
| DEK42484D DE1151800B (en) | 1957-03-13 | 1960-12-22 | Process for the preparation of organoboron compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB835847A true GB835847A (en) | 1960-05-25 |
Family
ID=33030654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7998/58A Expired GB835847A (en) | 1957-03-13 | 1958-03-12 | Method of preparing boro-organic compounds |
Country Status (2)
| Country | Link |
|---|---|
| DE (2) | DE1052986B (en) |
| GB (1) | GB835847A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178770A (en) * | 2017-12-11 | 2018-06-19 | 华南理工大学 | A kind of method for synthesizing alpha-amido boron compound |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1115250B (en) * | 1959-11-13 | 1961-10-19 | Kali Chemie Ag | Process for the preparation of organoboron compounds |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1038019B (en) * | 1957-03-20 | 1958-09-04 | Kali Chemie Ag | Process for the preparation of hydrogen boride compounds |
| FR1222316A (en) * | 1958-04-25 | 1960-06-09 | Purdue Research Foundation | Process for the preparation of organic boron compounds |
-
1957
- 1957-03-13 DE DEK31389D patent/DE1052986B/en active Pending
-
1958
- 1958-03-12 GB GB7998/58A patent/GB835847A/en not_active Expired
-
1960
- 1960-12-22 DE DEK42484D patent/DE1151800B/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178770A (en) * | 2017-12-11 | 2018-06-19 | 华南理工大学 | A kind of method for synthesizing alpha-amido boron compound |
| CN108178770B (en) * | 2017-12-11 | 2020-04-28 | 华南理工大学 | A kind of method of synthesizing α-amino boron compound |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1052986B (en) | 1959-03-19 |
| DE1151800B (en) | 1963-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB762200A (en) | Improvements in and relating to the production of aluminium alkyls | |
| GB767400A (en) | Process for the manufacture of trialkylaluminium compounds | |
| GB958085A (en) | Process for the manufacture of alkyl tin trihalides | |
| GB835847A (en) | Method of preparing boro-organic compounds | |
| ES389497A1 (en) | Fastener retainer | |
| GB802796A (en) | Method of preparing hydrocarbon-tin compounds | |
| GB1015227A (en) | Process for making tetramethyl lead | |
| GB900132A (en) | Method of producing alkyls | |
| US3042723A (en) | Preparation of boron alkyls | |
| Cole et al. | Simple conversion of anhydrides of boronic and borinic acids to the corresponding organodihaloboranes and diorganohaloboranes | |
| GB824428A (en) | Improvements in and relating to the production of aluminium alkyls | |
| GB907463A (en) | Method of producing sodium borohydrides | |
| GB1104200A (en) | Method of preparing lithium borohydride | |
| GB861760A (en) | Improvements in and relating to the production of boron compounds | |
| GB1005466A (en) | Process for the preparation of alkyl aluminium halides | |
| GB900614A (en) | Method of producing boron alkyls | |
| GB757524A (en) | Improvements in and relating to the production of complex metal alkyls | |
| GB979271A (en) | Process for the manufacture of organic fluorine compounds | |
| US3594426A (en) | Process for the preparation of tri-organo-boron compounds | |
| GB1003090A (en) | Process for the production of n,n,n-triorgano-substituted borazoles | |
| GB973076A (en) | Improvements relating to the production of alkylated boranes | |
| GB911387A (en) | Process for the production of alkali metal boron tetraalkyls | |
| GB887370A (en) | Organo boron compounds | |
| GB623760A (en) | Improvements in and relating to the preparation of boron hydrides | |
| GB873661A (en) | Metal exchange process |