GB835771A - Improvements in or relating to the preparation of olefine addition compounds containing mercury - Google Patents
Improvements in or relating to the preparation of olefine addition compounds containing mercuryInfo
- Publication number
- GB835771A GB835771A GB26665/58A GB2666558A GB835771A GB 835771 A GB835771 A GB 835771A GB 26665/58 A GB26665/58 A GB 26665/58A GB 2666558 A GB2666558 A GB 2666558A GB 835771 A GB835771 A GB 835771A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- alcohol
- carbon atoms
- aliphatic
- olefine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052753 mercury Inorganic materials 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 125000001931 aliphatic group Chemical group 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 abstract 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 4
- 150000002085 enols Chemical class 0.000 abstract 4
- 150000001261 hydroxy acids Chemical class 0.000 abstract 4
- 150000004715 keto acids Chemical class 0.000 abstract 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 125000003263 primary aromatic amine group Chemical group 0.000 abstract 3
- 150000003336 secondary aromatic amines Chemical class 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229930194542 Keto Natural products 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 238000006136 alcoholysis reaction Methods 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 159000000032 aromatic acids Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 125000000468 ketone group Chemical group 0.000 abstract 1
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 125000003367 polycyclic group Chemical group 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Olefine addition compounds containing mercury are made by reacting an olefin with a mercuric salt of an organic acid and an aliphatic alcohol having at least four carbon atoms (other than an ether alcohol or a semi-acetal), an aliphatic or aromatic acid, an enol or a primary or secondary aromatic amine. The olefine may be straight or branched chain, cyclic or polycyclic, and may contain substituents such as hydroxyl, carboxyl, ester, aryl, alkyl, alkaryl, aralkyl, alkoxy or acyloxy groups. Mercuric acetate or propionate may be reacted with the olefine and a monohydric or polyhydric aliphatic alcohol having at least four carbon atoms (other than an ether alcohol or a semiacetal), a monobasic or polybasic aliphatic or aromatic acid (which may be a halogen substituted, hydroxy- or keto-acid), an enol or a primary or secondary aromatic amine. Mercuric salts of monobasic or dibasic organic halo-, hydroxy- or keto-acids having not more than three carbon atoms may be reacted with the olefin and a monohydric or polyhydric alcohol having at least four carbon atoms (other than an ether alcohol or a semi-acetal), a monobasic or polybasic aliphatic or aromatic acid (which may be a halogen-substituted, hydroxy- or keto-acid), an enol or a primary or secondary aromatic amine. Mercuric salts of monobasic or polybasic aliphatic acids (having at least four carbon atoms) or of aromatic acids (which may be halogen, hydroxy- or keto substituted) may be reacted with the olefine and a monohydric or polyhydric aliphatic alcohol having at least four carbon atoms (other than an ether alcohol or a semi-acetal), a monobasic or polybasic aliphatic or aromatic acid (which may be halogen-substituted, hydroxy- or keto-acid) an enol or a primary or secondary amine. The reaction medium should be acidic when using an alcohol in order to prevent alcoholysis of the mercuric salt, and preferably the acid from which the salt is derived is used. An inert solvent such as benzene or cyclohexane, a halogenated hydrocarbon, a p mineral oil product or dioxane may be added to the reaction mixture.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE835771X | 1955-10-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB835771A true GB835771A (en) | 1960-05-25 |
Family
ID=6761002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26665/58A Expired GB835771A (en) | 1955-10-29 | 1956-10-25 | Improvements in or relating to the preparation of olefine addition compounds containing mercury |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB835771A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3184491A (en) * | 1961-02-23 | 1965-05-18 | Rhone Poulenc Sa | Preparation of 1-halomercuri-2-alkoxycyclododeca-5, 9-cis, trans-diene |
| US3294830A (en) * | 1963-12-10 | 1966-12-27 | Nat Distillers Chem Corp | Addition and telomerization reactions of olefins with organomercury compounds |
-
1956
- 1956-10-25 GB GB26665/58A patent/GB835771A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3184491A (en) * | 1961-02-23 | 1965-05-18 | Rhone Poulenc Sa | Preparation of 1-halomercuri-2-alkoxycyclododeca-5, 9-cis, trans-diene |
| US3294830A (en) * | 1963-12-10 | 1966-12-27 | Nat Distillers Chem Corp | Addition and telomerization reactions of olefins with organomercury compounds |
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