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GB824622A - Improvements in the thermal cracking of liquid hydrocarbons - Google Patents

Improvements in the thermal cracking of liquid hydrocarbons

Info

Publication number
GB824622A
GB824622A GB998158A GB998158A GB824622A GB 824622 A GB824622 A GB 824622A GB 998158 A GB998158 A GB 998158A GB 998158 A GB998158 A GB 998158A GB 824622 A GB824622 A GB 824622A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
liquid
oxygen
cracking
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB998158A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of GB824622A publication Critical patent/GB824622A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C10G9/38Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A process for cracking liquid hydrocarbons to produce acetylene in which the heat necessary for the cracking is produced in the hydrocarbons by burning a part of the hydrocarbons with oxygen or an oxygen containing gas comprises supplying the gas to a cracking space above the surface of the liquid and so directing the liquid on to the surface that a part of the liquid situated at the surface is burnt by the flame formed by ignition. In a preferred embodiment a diesel oil having boiling limits of 200-325 DEG C. is maintained in a reaction vessel 1 at a desired level by means of a level indicator 3. Oxygen is supplied through a nozzle 2 which is at a distance of 4 cms. above the surface of the liquid and is caused to ignite in the space above the liquid hydrocarbon by means of a small methane-oxygen auxiliary burner (not shown). Cracked gas leaves the reaction chamber at 126 DEG C. and passes to a condensing system in which the hydrocarbons, steam and carbon black are separated and the condensed hydrocarbons are returned to the reaction vessel <PICT:0824622/IV (b)/1> through a pipe 5. About 30% of the carbon black remains in the reaction vessel and this is removed by constantly withdrawing a portion of the oil through pipe 6. Additional diesel oil is added through a pipe 7. The cracked gas contains 5.8% of acetylene, 8.5% of olefines and 5.9% of saturated hydrocarbons. Steam or nitrogen may also be added to the oxygen. Specification 804,595 is referred to.
GB998158A 1957-08-27 1958-03-28 Improvements in the thermal cracking of liquid hydrocarbons Expired GB824622A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1957C0015384 DE1052978B (en) 1957-08-27 1957-08-27 Process for the thermal cracking of liquid hydrocarbons

Publications (1)

Publication Number Publication Date
GB824622A true GB824622A (en) 1959-12-02

Family

ID=25949392

Family Applications (1)

Application Number Title Priority Date Filing Date
GB998158A Expired GB824622A (en) 1957-08-27 1958-03-28 Improvements in the thermal cracking of liquid hydrocarbons

Country Status (3)

Country Link
DE (1) DE1052978B (en)
FR (1) FR1200862A (en)
GB (1) GB824622A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1148997B (en) * 1959-03-26 1963-05-22 Basf Ag Process for removing and utilizing the soot that is produced when hydrocarbons are split into flames

Also Published As

Publication number Publication date
FR1200862A (en) 1959-12-24
DE1052978B (en) 1959-03-19

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