GB820486A - Rubbery polymer-antioxidant compositions - Google Patents
Rubbery polymer-antioxidant compositionsInfo
- Publication number
- GB820486A GB820486A GB25982/55A GB2598255A GB820486A GB 820486 A GB820486 A GB 820486A GB 25982/55 A GB25982/55 A GB 25982/55A GB 2598255 A GB2598255 A GB 2598255A GB 820486 A GB820486 A GB 820486A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- tertiary butyl
- alphaphenylethyl
- phenols
- tertiary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Rubbery polymers contain 0.5 to 5.0% by weight of a phenolic antioxidant of formula: <FORM:0820486/IV (a)/1> in which each R is a tertiary butyl, alphaphenylethyl or alpha-tolylethyl radical, there being at least one tertiary butyl radical and at least one aralkyl radical present and there being at least one tertiary butyl radical ortho to the hydroxyl group (see Group IV (b)). The rubbery polymers are natural rubber, polychloroprene, copolymers of isobutylene with butadiene or isoprene, copolymers of butadiene with styrene or acrylonitrile.ALSO:Tri-substituted phenols of formula <FORM:0820486/IV (a)/1> in which each R is a tertiary butyl radical or an alphaphenylethyl or alphatolylethyl radical, there being at least one tertiary butyl radical and at least one aralkyl radical present and there being at least one tertiary butyl radical ortho to the hydroxyl group, are used as anti-oxidants in rubber compositions (see Group IV (a)). The preparation of di-tertiary-butyl-alphaphenylethyl-phenols and ditertiary-butylalphatolyethyl-phenols is specified.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US820486XA | 1955-03-02 | 1955-03-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB820486A true GB820486A (en) | 1959-09-23 |
Family
ID=22168710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25982/55A Expired GB820486A (en) | 1955-03-02 | 1955-09-12 | Rubbery polymer-antioxidant compositions |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE545693A (en) |
GB (1) | GB820486A (en) |
LU (1) | LU33823A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3989665A (en) * | 1975-01-20 | 1976-11-02 | The Goodyear Tire & Rubber Company | Butylated, α-methyl styrenated phenolic antioxidants for polymers |
-
0
- LU LU33823D patent/LU33823A1/xx unknown
- BE BE545693D patent/BE545693A/xx unknown
-
1955
- 1955-09-12 GB GB25982/55A patent/GB820486A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
LU33823A1 (en) | |
BE545693A (en) |
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