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GB813120A - Production of a hard metal coating of carbides on a ferrous mass - Google Patents

Production of a hard metal coating of carbides on a ferrous mass

Info

Publication number
GB813120A
GB813120A GB3285755A GB3285755A GB813120A GB 813120 A GB813120 A GB 813120A GB 3285755 A GB3285755 A GB 3285755A GB 3285755 A GB3285755 A GB 3285755A GB 813120 A GB813120 A GB 813120A
Authority
GB
United Kingdom
Prior art keywords
per cent
layer
carbides
layers
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3285755A
Inventor
Leon Nussbaum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Titanium Products Corp Ltd
Original Assignee
Titanium Products Corp Ltd
Filing date
Publication date
Application filed by Titanium Products Corp Ltd filed Critical Titanium Products Corp Ltd
Publication of GB813120A publication Critical patent/GB813120A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

A coating of at least one carbide of one or more of Ti, Zr, V, Cb, Ta, Mo and Cr is produced on a ferrous metal mass by applying successive layers of "asymmetric particles" of one or more of the said carbides with or without binder metal(s), and each time a layer is applied heating under non-oxidising conditions both the layer and the underlying surface to which the layer is applied, sufficiently to effect welding of the layer to the underlying surface but insufficient, at least in the case of the last layer(s), to alter materially the asymmetric nature of the carbide particles. "Asymmetric particles" are irregularly shaped incomplete crystals such as obtained by ball-milling. The layers may be applied as pre-formed laminae, or as powder; heating may be by a gas welding torch or a shrouded arc using carton or tungsten electrodes. The coating, while still plastic, may be shaped by pressure between metal or carbon formers. In an Example, 85 per cent re-crystallized carbides (87 1/2 parts Ti C, 11 parts Cb C, 1 1/2 parts Ta C) and 15 per cent Ni-Cr binder alloy of particle size 3m and less, the carbides being asymmetric, was mixed with 1 per cent of organic binder (20 per cent camphor in acetone) and mortared. It was then compressed at about 1/2 ton p.s.i. while vibrated in a mould, then presintered at 1200 DEG C. It was then cast to size, placed on a base of 0.5 per cent carbon steel which was partially immersed in water, and an arc struck with a tungsten electrode shrouded in nitrogen to weld the layer to the base. This was repeated with two other similar compacted layers and finally with two containing no binder metal. The hardness of successive layers increased. In a second Example the powder of the first Example was projected through a nitrogen-shrouded arc struck between a tungsten electrode and the upper face of a 0.5 per cent carbon steel base cooled as before. Successive layers were added each about 1/16 in. thick, the last two being free from binder metal powder. Shaping of each of the above produced layers whilst plastic by means of a steel former using 20 tons p.s.i. maintained the hardness but gave increased shock resistance.
GB3285755A 1955-11-16 Production of a hard metal coating of carbides on a ferrous mass Expired GB813120A (en)

Publications (1)

Publication Number Publication Date
GB813120A true GB813120A (en) 1959-05-06

Family

ID=1743195

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3285755A Expired GB813120A (en) 1955-11-16 Production of a hard metal coating of carbides on a ferrous mass

Country Status (1)

Country Link
GB (1) GB813120A (en)

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