GB766766A - Heterocyclic phosphorus-containing compounds and process for their production - Google Patents
Heterocyclic phosphorus-containing compounds and process for their productionInfo
- Publication number
- GB766766A GB766766A GB6255/55A GB625555A GB766766A GB 766766 A GB766766 A GB 766766A GB 6255/55 A GB6255/55 A GB 6255/55A GB 625555 A GB625555 A GB 625555A GB 766766 A GB766766 A GB 766766A
- Authority
- GB
- United Kingdom
- Prior art keywords
- give
- thiono
- ethyl
- heterocyclic
- diethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 125000000623 heterocyclic group Chemical group 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- -1 2-ethyl Chemical group 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Chemical group 0.000 abstract 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical class CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 1
- AVIYEYCFMVPYST-UHFFFAOYSA-N hexane-1,3-diol Chemical compound CCCC(O)CCO AVIYEYCFMVPYST-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- WQYSXVGEZYESBR-UHFFFAOYSA-N thiophosphoryl chloride Chemical compound ClP(Cl)(Cl)=S WQYSXVGEZYESBR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657109—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s)
- C07F9/657118—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms esters of oxyacids of phosphorus in which one or more exocyclic oxygen atoms have been replaced by (a) sulfur atom(s) non-condensed with carbocyclic rings or heterocyclic rings or ring systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
The invention comprises heterocyclic compounds of the formula <FORM:0766766/IV(b)/1> wherein R1, R2, R3 and R4 are H or alkyl, n=0 or 1, and X is chlorine or bromine, and a process for producing them by reaction between a thiophosphonyl chloride or bromide and a 1 : 2- or 1 : 3-alkanediol in presence of a hydrogen halide binding agent, in a hydrocarbon solvent; also a process for chlorinating or brominating the heterocyclic dithiophosphoric acid corresponding, to give the above compounds. In examples, thiophosphoryl chloride reacts with 2 : 2-diethyl-1 : 3-propane diol, 2 - methyl - 2 : 4 - pentane - diol, 2-ethyl - 1 : 3 - hexanediol, and 1 : 2 - propanediol, to give the corresponding 2-chloro-2-thiono - 1 : 3 : 2 - dioxaphospholanes and dioxaphosphorinanes; the 5-ethyl-2-mercapto-4 - propyl - 2 - thiono - 1 : 3 : 2 - dioxaphosphorinane, and the corresponding 5 : 5-diethyl derivative are chlorinated with gaseous chlorine to give the 2-chloro derivatives. Other glycols specified for the formation of the ring compounds include ethylene and butane diols. Specification 759,334, [Group III], is referred to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6255/55A GB766766A (en) | 1955-03-03 | 1955-03-03 | Heterocyclic phosphorus-containing compounds and process for their production |
| DEU3236A DE1022597B (en) | 1955-03-03 | 1955-03-04 | Process for the preparation of phosphorus-containing heterocyclic compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6255/55A GB766766A (en) | 1955-03-03 | 1955-03-03 | Heterocyclic phosphorus-containing compounds and process for their production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB766766A true GB766766A (en) | 1957-01-23 |
Family
ID=22133537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6255/55A Expired GB766766A (en) | 1955-03-03 | 1955-03-03 | Heterocyclic phosphorus-containing compounds and process for their production |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1022597B (en) |
| GB (1) | GB766766A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2043643A1 (en) * | 1969-05-23 | 1971-02-19 | Bayer Ag |
-
1955
- 1955-03-03 GB GB6255/55A patent/GB766766A/en not_active Expired
- 1955-03-04 DE DEU3236A patent/DE1022597B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2043643A1 (en) * | 1969-05-23 | 1971-02-19 | Bayer Ag |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1022597B (en) | 1958-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3324205A (en) | Halogenated phosphates and phosphonates and method of preparation | |
| ES327312A1 (en) | Procedure for the production of new derivatives of benzotiofeno. (Machine-translation by Google Translate, not legally binding) | |
| GB766766A (en) | Heterocyclic phosphorus-containing compounds and process for their production | |
| GB1525794A (en) | Flameproofed polymeric organic materials and methods of production thereof | |
| US3783016A (en) | Method for imparting flame resistance to fibrous materials | |
| IL42107A (en) | Production of aminopropane derivatives | |
| US4092312A (en) | Process for preparing phosphorothioates and phenylphosphonothioates | |
| GB828999A (en) | Novel phosphorane compounds and a process for the manufacture thereof | |
| GB759396A (en) | Heterocyclic phosphorus-containing compounds and the production thereof | |
| GB806772A (en) | Diaminoquinazolines and method of preparing | |
| US3403049A (en) | Flame-resistant organic material | |
| GB341878A (en) | Improvements in or relating to the manufacture of organic halogen compounds | |
| GB1343395A (en) | Process for the recovery of chlorine compounds | |
| GB893747A (en) | Manufacture of organic peroxides | |
| US2810757A (en) | Preparation of octaalkylpyrophosphoramides | |
| ES418102A1 (en) | O-pyrazolopyrimidine-(thiono)-phosphoric(phosphonic) acid esters | |
| GB993302A (en) | Nitrogen-containing heterocyclic disulfides | |
| ES440991A1 (en) | Diaryl-pyridyl-imidazole methanes and their production | |
| GB865750A (en) | Spiro-phosphonium salts | |
| Tsubouchi et al. | 1, 3, 4, 6‐Tetrakis (isopropylthio) thieno [3, 4‐c] thiophenium bis (tetrafluoroborate): X‐ray crystal structure of a stable thieno [3, 4‐c] thiophene dication | |
| ES8101614A1 (en) | Halogenating compounds and a process for their production. | |
| GB743922A (en) | Phosphate plasticizers | |
| GB691520A (en) | o-hydroxyaryl dihalotriazines | |
| Igarashi et al. | Addition reactions of glycals. VI. Chlorination of D-glucal triacetate with iodobenzene dichloride | |
| GB1077216A (en) | Process for the production of compounds having imido-chloride groupings |