GB758986A - Improvements in or relating to aqueous dispersions of pigments - Google Patents
Improvements in or relating to aqueous dispersions of pigmentsInfo
- Publication number
- GB758986A GB758986A GB2203854A GB2203854A GB758986A GB 758986 A GB758986 A GB 758986A GB 2203854 A GB2203854 A GB 2203854A GB 2203854 A GB2203854 A GB 2203854A GB 758986 A GB758986 A GB 758986A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- water
- pigments
- copolymer
- yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 6
- 239000000049 pigment Substances 0.000 title abstract 6
- 150000003839 salts Chemical class 0.000 abstract 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 4
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 abstract 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 239000002585 base Substances 0.000 abstract 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- OGMSGZZPTQNTIK-UHFFFAOYSA-N 1-methyl-2-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1C OGMSGZZPTQNTIK-UHFFFAOYSA-N 0.000 abstract 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 2
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- 229910000004 White lead Inorganic materials 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003086 colorant Substances 0.000 abstract 2
- 210000003298 dental enamel Anatomy 0.000 abstract 2
- VAPILSUCBNPFBS-UHFFFAOYSA-L disodium 2-oxido-5-[[4-[(4-sulfophenyl)diazenyl]phenyl]diazenyl]benzoate Chemical compound [Na+].[Na+].Oc1ccc(cc1C([O-])=O)N=Nc1ccc(cc1)N=Nc1ccc(cc1)S([O-])(=O)=O VAPILSUCBNPFBS-UHFFFAOYSA-L 0.000 abstract 2
- 239000001023 inorganic pigment Substances 0.000 abstract 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 abstract 2
- 229910000464 lead oxide Inorganic materials 0.000 abstract 2
- 235000001510 limonene Nutrition 0.000 abstract 2
- 229940087305 limonene Drugs 0.000 abstract 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 2
- 239000001095 magnesium carbonate Substances 0.000 abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 2
- 239000010445 mica Substances 0.000 abstract 2
- 229910052618 mica group Inorganic materials 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 2
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 abstract 2
- 239000000454 talc Substances 0.000 abstract 2
- 229910052623 talc Inorganic materials 0.000 abstract 2
- 150000003505 terpenes Chemical class 0.000 abstract 2
- 235000007586 terpenes Nutrition 0.000 abstract 2
- 239000000080 wetting agent Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 241000449980 Mansa Species 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 1
- 235000011160 magnesium carbonates Nutrition 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D135/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
Inorganic pigments are dispersed in water with 0.05 to 3 per cent of a water-soluble salt of a homogeneous copolymer of maleic anhydride and an unsaturated hydrocarbon having only one active olefinic linkage and containing five to ten carbon atoms, said copolymer having a molecular weight below 5000, a viscosity less than 1000 c.p.s. at 25 DEG C. in 35 per cent solution in dioxane or methyl ethyl ketone, and the salt thereof giving a pH in water of at least 4.5. Unsaturated hydrocarbons specified are diisobutylene, amylene, isoamylene, hexene, decene, styrene, a -methylstyrene, vinyltoluene, isopropenyltoluene, indene, dicyclopentadiene and terpenes such as b -pinene and limonene. Salts described are those derived from alkali metal, ammonium, quaternary ammonium and amine bases. The pigments may be calcium and/or magnesium carbonate; barium sulphate; zinc, chromium and lead oxides; mica, talc, white lead, silica, china clay, rutile, anatase, blanc fixe, kaolin, lithopone and mixtures and also included may be insoluble colours such as iron oxide, cadmium sulphide, toluidine red, lithol toner, chrome orange or yellow or green, "Mansa" (Registered Trade Mark) yellow and phthalocyanine green or blue. The dispersions may contain up to 85 per cent pigment and wetting agents such as sulphated alcohols, sulphonated alkylbenzenes, sodium alkylphenoxypolyethoxyethyl sulphonate and alkylphenoxypolyethoxyethanols, are optional additives. In examples diethylene glycol and an antifoamer are also included. The dispersions find application in water-base coating compositions, such as paints and enamels, and may be added to copolymer latices, e.g. those of copolymers of styrene with butadiene, vinyl acetate and acrylic compounds.ALSO:Aqueous dispersions of inorganic pigments contain as dispersing agent a water soluble salt of homogenous copolymer of maleic anhydride and an unsaturated hydrocarbon having only one active olefinic linkage and containing 5 to 10 carbon atoms, said copolymer having a molecular weight below 5000, a viscosity less than 1000 cps. at 25 DEG C. in 35 per cent solution in dioxane of methyl ethyl ketone, and the salt thereof giving a pH in water of at least 4.5. Unsaturated hydrocarbons specified are diisobutylene, amylene, isoamylene, hexene, decene, styrene, a-methylstyrene, vinyltoluene, isopropenyl toluene, indene, dicyclopentadiene and terpenes such as b -pinene and limonene. Salts disclosed are those derived from alkali metal, ammonium, quaternary ammonium and amine bases and the amount of salt used in the dispersion is from 0.05 to 3 per cent by weight of the pigments. Pigments specified are calcium and magnesium carbonates; barium sulphate; zinc, chrome and lead oxides; mica, talc, white lead, silica, china clay, rutile, anatase, blanc fixe, kaolin, lithopone and mixtures and also present may be unsoluble colours such as iron oxide, cadmium sulphide, toluidine red, lithol toner, chrome orange or yellow or green, "Hanso" (Registered Trade Mark) yellow and phthalocyanine green or blue. The dispersions, optionally containing wetting agents, may contain up to 85 per cent of pigment and are useful in paints and enamels.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37366053A | 1953-08-11 | 1953-08-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB758986A true GB758986A (en) | 1956-10-10 |
Family
ID=38524395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2203854A Expired GB758986A (en) | 1953-08-11 | 1954-07-28 | Improvements in or relating to aqueous dispersions of pigments |
Country Status (6)
| Country | Link |
|---|---|
| CH (1) | CH335787A (en) |
| DE (1) | DE1119434B (en) |
| ES (1) | ES216915A1 (en) |
| FR (1) | FR1109893A (en) |
| GB (1) | GB758986A (en) |
| NL (1) | NL104335C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000840A (en) * | 1957-12-20 | 1961-09-19 | Monsanto Chemicals | Dispersing agents |
| WO1997015382A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Dispersants for inorganic materials in aqueous systems |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3479223D1 (en) * | 1983-05-20 | 1989-09-07 | Allied Colloids Ltd | Water soluble polymers and dispersions containing them |
| AU581417B2 (en) * | 1984-11-16 | 1989-02-23 | Ciba Specialty Chemicals Water Treatments Limited | Water soluble polymers and dispersions containing them |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE623404C (en) * | 1930-05-26 | |||
| DE737999C (en) * | 1941-05-20 | 1943-08-03 | Ig Farbenindustrie Ag | Process for reducing the viscosity of pigmented aqueous dispersions of organic binders |
| US2647094A (en) * | 1950-08-19 | 1953-07-28 | Monsanto Chemicals | Pigment pastes comprising a pigment and a salt of a copolymer of styrene and a maleic half-ester |
| DE838750C (en) * | 1951-03-17 | 1952-05-12 | Wacker Chemie Gmbh | Dispersing, thickening and cleaning agents and auxiliaries for the treatment of materials with aqueous fluids and dispersions |
-
0
- NL NL104335D patent/NL104335C/xx active
-
1954
- 1954-07-28 GB GB2203854A patent/GB758986A/en not_active Expired
- 1954-08-09 FR FR1109893D patent/FR1109893A/en not_active Expired
- 1954-08-09 DE DER14823A patent/DE1119434B/en active Pending
- 1954-08-10 ES ES0216915A patent/ES216915A1/en not_active Expired
- 1954-08-10 CH CH335787D patent/CH335787A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000840A (en) * | 1957-12-20 | 1961-09-19 | Monsanto Chemicals | Dispersing agents |
| WO1997015382A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Dispersants for inorganic materials in aqueous systems |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1109893A (en) | 1956-02-02 |
| ES216915A1 (en) | 1955-12-16 |
| CH335787A (en) | 1959-01-31 |
| DE1119434B (en) | 1961-12-14 |
| NL104335C (en) |
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