GB738667A - Novel emulsifying agent compositions and their use - Google Patents
Novel emulsifying agent compositions and their useInfo
- Publication number
- GB738667A GB738667A GB32119/52A GB3211952A GB738667A GB 738667 A GB738667 A GB 738667A GB 32119/52 A GB32119/52 A GB 32119/52A GB 3211952 A GB3211952 A GB 3211952A GB 738667 A GB738667 A GB 738667A
- Authority
- GB
- United Kingdom
- Prior art keywords
- magnesium
- calcium
- zinc salt
- general formula
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000003995 emulsifying agent Substances 0.000 title abstract 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 6
- 239000011575 calcium Substances 0.000 abstract 6
- 229910052791 calcium Inorganic materials 0.000 abstract 6
- 239000011777 magnesium Substances 0.000 abstract 6
- 229910052749 magnesium Inorganic materials 0.000 abstract 6
- 150000003751 zinc Chemical class 0.000 abstract 6
- 239000007788 liquid Substances 0.000 abstract 5
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 4
- 229930195729 fatty acid Natural products 0.000 abstract 4
- 239000000194 fatty acid Substances 0.000 abstract 4
- 150000004665 fatty acids Chemical class 0.000 abstract 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 4
- 239000000839 emulsion Substances 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 2
- OXLXSOPFNVKUMU-UHFFFAOYSA-N 1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC OXLXSOPFNVKUMU-UHFFFAOYSA-N 0.000 abstract 2
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 abstract 2
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 abstract 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical class C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 abstract 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 2
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 abstract 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- 239000005642 Oleic acid Substances 0.000 abstract 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 2
- YUDRVAHLXDBKSR-UHFFFAOYSA-N [CH]1CCCCC1 Chemical compound [CH]1CCCCC1 YUDRVAHLXDBKSR-UHFFFAOYSA-N 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- 239000004359 castor oil Substances 0.000 abstract 2
- 235000019438 castor oil Nutrition 0.000 abstract 2
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 abstract 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 abstract 2
- 150000005690 diesters Chemical class 0.000 abstract 2
- 239000012153 distilled water Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- -1 ether alcohols Chemical class 0.000 abstract 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003350 kerosene Substances 0.000 abstract 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 2
- 150000002989 phenols Chemical class 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- 239000008234 soft water Substances 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 239000004753 textile Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 abstract 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- 239000010730 cutting oil Substances 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
An emulsifying agent, for use in making water-emulsifiable organic liquid compositions, comprises a mixture of (a) a polyethenoxy compound of the general formula R(OC2H4)nOH, where R is the residue of a compound ROH containing at least 10 carbon atoms and at least one carboxyl or hydroxyl group, and (b) up to an equal weight of a calcium, magnesium, or zinc salt of a sulphosuccinic diester of the general formula <FORM:0738667/III/1> where R is a straight or branched chain alkyl residue containing from 6-10 carbon atoms or the cyclohexyl radical. Suitable polyethenoxy compounds are derived from alkylated phenols, higher alcohols, fatty acids, ether alcohols, and fatty acid monoethanol amides, e.g. dodecyl phenol, alkylated beta-naphthol, oleic acid, or castor oil. The calcium, magnesium, or zinc salt (which is preferably of sulpho-succinic dioctyl ester) may be formed by dissolving the corresponding sodium salt in the liquid to be emulsified, mixing with an excess of a concentrated aqueous solution of a calcium, magnesium, or zinc salt, and discarding the aqueous layer which separates. For the preparation of emulsions useful in the textile industry and as fat solvents, the organic liquid may be trichloroethylene, tetrahydronaphthalene, or decahydronaphthalene. Emulsifiable compositions for plant spraying contain D.D.T., benzene hexachloride, 2,4-dinitro-o-cresol, esters of 2,4-D and 2,4,5-T, or Chlordane, dissolved in solvent naphtha, carbon tetrachloride, methylnaphthalene, xylene, or kerosene. Reference is made to the preparation of textile and cutting oils and Example 6 relates to an emulsifiable light lubricating oil. The emulsions formed are stable even when using soft or distilled water.ALSO:Emulsifiable compositions for use in plant spraying consist of an organic liquid in which is dissolved an emulsifying agent comprising a mixture of (a) a polyethenoxy compound of the general formula R(OC2H4)nOH, where R is the residue of a compound ROH containing at least 10 carbon atoms and at least one carboxyl or hydroxyl group, and (b) up to an equal weight of a calcium, magnesium, or zinc salt of a sulphosuccinic diester of the general formula <FORM:0738667/VI/1> where R is a straight or branched chain alkyl residue containing from 6-10 carbon atoms or the cyclohexyl radical. Suitable polyethenoxy compounds are derived from alkylated phenols, higher alcohols, fatty acids, ether alcohols, and fatty acid monoethanol amides, e.g. dodecyl phenol, alkylated beta-naphthol, oleic acid, or castor oil. The calcium, magnesium, or zinc salt (which is preferably of sulphosuccinic dioctyl ester) may be formed by dissolving the corresponding sodium salt in the liquid to be emulsified, mixing with an excess of a concentrated aqueous solution of a calcium, magnesium, or zinc salt, and discarding the aqueous layer which separates. The compositions may contain D.D.T., benzene hexachloride, 2,4-dinitro-o-cresol, esters of 2,4-D and 2,4,5-T, or Chlordane, dissolved in solvent naphtha, carbon tetrachloride, methylnaphthalene, xylene, or kerosene. The emulsions formed are stable even when using soft or distilled water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB32119/52A GB738667A (en) | 1952-12-18 | 1952-12-18 | Novel emulsifying agent compositions and their use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB32119/52A GB738667A (en) | 1952-12-18 | 1952-12-18 | Novel emulsifying agent compositions and their use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB738667A true GB738667A (en) | 1955-10-19 |
Family
ID=10333551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32119/52A Expired GB738667A (en) | 1952-12-18 | 1952-12-18 | Novel emulsifying agent compositions and their use |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB738667A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2313116A1 (en) * | 1975-01-30 | 1976-12-31 | Hoechst Ag | EMULSIONANTS USABLE FOR THE PREPARATION OF EMULSIONABLE CONCENTRATES OF BIOCIDAL SUBSTANCES |
-
1952
- 1952-12-18 GB GB32119/52A patent/GB738667A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2313116A1 (en) * | 1975-01-30 | 1976-12-31 | Hoechst Ag | EMULSIONANTS USABLE FOR THE PREPARATION OF EMULSIONABLE CONCENTRATES OF BIOCIDAL SUBSTANCES |
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