GB729345A - Improvements in the hardening of gelatin - Google Patents
Improvements in the hardening of gelatinInfo
- Publication number
- GB729345A GB729345A GB30402/52A GB3040252A GB729345A GB 729345 A GB729345 A GB 729345A GB 30402/52 A GB30402/52 A GB 30402/52A GB 3040252 A GB3040252 A GB 3040252A GB 729345 A GB729345 A GB 729345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methane
- sulphonoxy
- methanesulphonoxy
- gelatine
- hardening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/30—Hardeners
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The methanesulphonic esters, 1 : 2-di- (methanesulphonoxy) - ethane, 1 : 3 - di - (methanesulphonoxy) - propane, 1 : 5 - di - (methanesulphonoxy) - pentane, b ,b 1 - di - (methanesulphonoxy) - diethyl ether and 1 : 6 - di - (methanesulphonoxy)-hexane, used for hardening gelatine, are made by reacting ethylene glycol, trimethylene glycol, pentanediol-1 : 5, diethylene glycol and hexamethylene glycol, respectively, with methanesulphonyl chloride in pyridine at 5 DEG to 15 DEG C.ALSO:In hardening gelatine, e.g. gelatine-silver halide photographic emulsions, at least 1 part by weight, preferably 10 parts, of a methane sulphonic ester having the formula CH3SO3-CH2-X-CH2-SO3CH3, wherein X is CH2-O-CH2 or (CH2)n and n is 0, 1, 2, 3 or 4, are added to each 620 parts of gelatine in aqueous solution. The following esters may be used:-1:2-di (methane sulphonoxy)-ethane, 1:3-di (methane sulphonoxy)-propane, 1:5-di (methane sulphonoxy)-pentane, b , b 1-di (methane sulphonoxy)-diethyl ether, 1:6-di (methane sulphonoxy)-hexane (see Group IV (b)). Formaldehyde or alum may also be added.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US259511A US2726162A (en) | 1951-12-01 | 1951-12-01 | Hardening of gelatin |
Publications (1)
Publication Number | Publication Date |
---|---|
GB729345A true GB729345A (en) | 1955-05-04 |
Family
ID=22985249
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30402/52A Expired GB729345A (en) | 1951-12-01 | 1952-12-01 | Improvements in the hardening of gelatin |
Country Status (5)
Country | Link |
---|---|
US (1) | US2726162A (en) |
BE (1) | BE515924A (en) |
DE (1) | DE935706C (en) |
FR (1) | FR1078393A (en) |
GB (1) | GB729345A (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2950197A (en) * | 1955-04-18 | 1960-08-23 | Eastman Kodak Co | Hardening of gelatin |
US2964404A (en) * | 1957-07-26 | 1960-12-13 | Eastman Kodak Co | Hardening of gelating with aziridinylsulfonyl compounds |
US3041241A (en) * | 1957-11-08 | 1962-06-26 | Burroughs Wellcome Co | Method of temporarily alleviating the symptoms of chronic and acute myelocytic leukemias with 2, 5-bismethanesulphonoxyhexane |
DE1128852B (en) * | 1958-04-24 | 1962-05-03 | Nat Res Dev | Process for the preparation of dimethanesulfonic acid esters of polyhydric alcohols |
GB891466A (en) * | 1958-04-24 | 1962-03-14 | Nat Res Dev | New methane sulphonic acid esters of polyols |
US3100704A (en) * | 1958-07-24 | 1963-08-13 | Gen Aniline & Film Corp | Photographic materials containing carbodhmides |
DE1155233B (en) * | 1959-08-01 | 1963-10-03 | Perutz Photowerke Ges Mit Besc | Method of hardening gelatin |
DE1211070B (en) * | 1962-07-25 | 1966-02-17 | Eastman Kodak Co | Light-sensitive, photographic silver halide emulsion containing a hardener |
GB1054123A (en) * | 1963-03-14 | |||
US3241972A (en) * | 1963-05-28 | 1966-03-22 | Eastman Kodak Co | Gelatin compositions |
GB1113341A (en) * | 1963-11-08 | 1968-05-15 | May & Baker Ltd | Improvements in or relating to the hardening of gelatin |
US3467519A (en) * | 1965-04-28 | 1969-09-16 | Agfa Gevaert Ag | Swelling reduction treatment for the accelerated processing of gelatin photographic materials |
US3873590A (en) * | 1969-09-15 | 1975-03-25 | Chevron Res | Methyl esters of organic sulfonic acid oligomers |
JPS5127377B2 (en) * | 1971-12-27 | 1976-08-12 | ||
JPS532459B2 (en) * | 1974-04-01 | 1978-01-28 | ||
US4508773A (en) * | 1983-04-27 | 1985-04-02 | Eschem Inc. | Paper product and glue therefor |
DE3684430D1 (en) | 1985-12-25 | 1992-04-23 | Fuji Photo Film Co Ltd | METHOD FOR PRODUCING AN IMAGE. |
US4864046A (en) * | 1989-02-09 | 1989-09-05 | Pfizer Inc. | Process for optically active 3-thiolanyl sulfonate esters |
US4921972A (en) * | 1989-05-17 | 1990-05-01 | Pfizer Inc. | Process for optically active 3-thiolanyl sulfonate esters |
US4940823A (en) * | 1989-07-12 | 1990-07-10 | Pfizer Inc. | Process for optically active 3-thiolanyl sulfonate esters |
US5187259A (en) * | 1990-11-14 | 1993-02-16 | Eastman Kodak Company | Chain extended gelatin |
US6071688A (en) * | 1998-07-29 | 2000-06-06 | Eastman Kodak Company | Providing additives to a coating composition by vaporization |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2121616A (en) * | 1937-05-29 | 1938-06-21 | Du Pont | Sulphates of polybasic acid esters |
US2240476A (en) * | 1940-03-12 | 1941-04-29 | Eastman Kodak Co | Photographic gelatin layer containing an ester of sulphosuccinic acid |
-
0
- BE BE515924D patent/BE515924A/xx unknown
-
1951
- 1951-12-01 US US259511A patent/US2726162A/en not_active Expired - Lifetime
-
1952
- 1952-11-25 DE DEE6370A patent/DE935706C/en not_active Expired
- 1952-12-01 GB GB30402/52A patent/GB729345A/en not_active Expired
- 1952-12-01 FR FR1078393D patent/FR1078393A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE935706C (en) | 1955-11-24 |
FR1078393A (en) | 1954-11-17 |
BE515924A (en) | |
US2726162A (en) | 1955-12-06 |
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