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GB728237A - Improvements relating to the treatment of textile materials with a colloidal solution of silica - Google Patents

Improvements relating to the treatment of textile materials with a colloidal solution of silica

Info

Publication number
GB728237A
GB728237A GB2224952A GB2224952A GB728237A GB 728237 A GB728237 A GB 728237A GB 2224952 A GB2224952 A GB 2224952A GB 2224952 A GB2224952 A GB 2224952A GB 728237 A GB728237 A GB 728237A
Authority
GB
United Kingdom
Prior art keywords
solution
silica
added
metallic salt
materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2224952A
Inventor
John Payne
Kenneth Conrad Bryant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Original Assignee
Monsanto Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE522535D priority Critical patent/BE522535A/xx
Application filed by Monsanto Chemicals Ltd filed Critical Monsanto Chemicals Ltd
Priority to GB2224952A priority patent/GB728237A/en
Priority to FR1088393D priority patent/FR1088393A/en
Priority to DEM19908A priority patent/DE1045967B/en
Publication of GB728237A publication Critical patent/GB728237A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/17Halides of elements of Groups 3 or 13 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/28Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65Salts of oxyacids of nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71Salts of phosphoric acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Silicon Compounds (AREA)

Abstract

Textile materials are immersed in an aqueous colloidal silica solution and there is then added a metallic salt capable of producing in solution a positive ion having an ionic charge of at least three, so that silica is deposited upon the textile material. The rate of deposition of silica increases with increase in quantity of the metallic salt added and also with increase of the pH value of the solution, but a uniform deposition is obtained with pH less than 7. The silica solution may vary up to 30 per cent by weight concentration, but concentrations of the order of 0.05 per cent are preferred. The metallic salt may be added in the ratio by weight of 0.5 to 2 : 1 relative to the weight of silica. The textile materials may be immersed in a bath of water to which the silica solution is afterwards added with stirring. The water may be acidified prior to the immersion of the materials, or the colloidal silica solution may be acidified, or the metallic salt may be added in aqueous solution which may be acidified. The metallic salt may be aluminium sulphate or acetate, alum, chrome alum, ferric chloride or sulphate or ceric ammonium nitrate. Acetic or hydrochloric acid may be used for the acidification. The colloidal solution of silica may be buffered to a constant pH with a solution of sodium acetate in acetic acid. The materials may be after-treated with a cationic softening agent, suitably at 40 DEG C. Textile fibres, yarns or fabrics of wool, cotton, silk, regenerated cellulose, cellulose acetate or nylon may be treated. Specifications 607,696, 611,914, [Group III], 626,847; 645,703, 649,896, 649,897, 654,850, 660,593, 662,423 and 663,013, [all in Group III], are referred to.
GB2224952A 1952-09-04 1952-09-04 Improvements relating to the treatment of textile materials with a colloidal solution of silica Expired GB728237A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE522535D BE522535A (en) 1952-09-04
GB2224952A GB728237A (en) 1952-09-04 1952-09-04 Improvements relating to the treatment of textile materials with a colloidal solution of silica
FR1088393D FR1088393A (en) 1952-09-04 1953-09-01 Improvements in the treatment of textile materials
DEM19908A DE1045967B (en) 1952-09-04 1953-09-02 Improvements to increase the adhesion of textile fibers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2224952A GB728237A (en) 1952-09-04 1952-09-04 Improvements relating to the treatment of textile materials with a colloidal solution of silica

Publications (1)

Publication Number Publication Date
GB728237A true GB728237A (en) 1955-04-13

Family

ID=10176307

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2224952A Expired GB728237A (en) 1952-09-04 1952-09-04 Improvements relating to the treatment of textile materials with a colloidal solution of silica

Country Status (4)

Country Link
BE (1) BE522535A (en)
DE (1) DE1045967B (en)
FR (1) FR1088393A (en)
GB (1) GB728237A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2909451A (en) * 1956-04-27 1959-10-20 American Cyanamid Co Process for preparing aluminum phosphate dispersion and process of treating pile fabric with the resulting dispersion
US2999774A (en) * 1956-05-31 1961-09-12 American Viscose Corp Production of soil-resistant material
US3857727A (en) * 1970-10-22 1974-12-31 L Benisek Textile finishing

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL239185A (en) * 1959-05-14

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE737152C (en) * 1940-07-15 1943-07-07 Ig Farbenindustrie Ag Method of sliding fastening of sliding rayon fabrics
DE741887C (en) * 1941-02-08 1943-11-30 Ig Farbenindustrie Ag Method for securing sliding or knitting of sliding rayon fabrics or knitted rayon fabrics
BE444225A (en) * 1941-02-08

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2909451A (en) * 1956-04-27 1959-10-20 American Cyanamid Co Process for preparing aluminum phosphate dispersion and process of treating pile fabric with the resulting dispersion
US2999774A (en) * 1956-05-31 1961-09-12 American Viscose Corp Production of soil-resistant material
US3857727A (en) * 1970-10-22 1974-12-31 L Benisek Textile finishing

Also Published As

Publication number Publication date
BE522535A (en)
FR1088393A (en) 1955-03-07
DE1045967B (en) 1958-12-11

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