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GB716081A - Improvements in wet spinning of acrylonitrile polymers - Google Patents

Improvements in wet spinning of acrylonitrile polymers

Info

Publication number
GB716081A
GB716081A GB21409/52A GB2140952A GB716081A GB 716081 A GB716081 A GB 716081A GB 21409/52 A GB21409/52 A GB 21409/52A GB 2140952 A GB2140952 A GB 2140952A GB 716081 A GB716081 A GB 716081A
Authority
GB
United Kingdom
Prior art keywords
vinyl
water
bath
esters
ethylene carbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21409/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Industrial Rayon Corp
Original Assignee
Industrial Rayon Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Industrial Rayon Corp filed Critical Industrial Rayon Corp
Publication of GB716081A publication Critical patent/GB716081A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F13/00—Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like
    • D01F13/04—Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like of synthetic polymers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Artificial Filaments (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

In the manufacture of polyacrylonitrile fibres, a solution of polyacrylonitrile, or a copolymer thereof containing at least 80 per cent. by weight of acrylonitrile, in a mixture of ethylene carbonate and water, the water being present in an amount of 2.5-18.5 per cent. by weight of the solution, is extruded into a coagulating bath comprising ethylene carbonate and water, the ethylene carbonate concentration in the bath being 10-50 per cent. by weight. The spinning solution, which may contain small amounts of polyhydric alcohols, e.g. ethylene, propylene or dipropylene glycol, preferably has a temperature of 40 DEG -80 DEG C. or above, and the "cloud point" of the solution is preferably below 67 DEG C. The coagulating bath, which preferably has a temperature of 45 DEG -80 DEG C., may also contain small amounts of ethylene or dipropylene glycol, but ethylene carbonate and water preferably comprise at least 95 per cent. by weight of the bath. The ethylene carbonate concentration of the bath may be maintained by continuously withdrawing portions of the bath, and these portions may be subjected to flash-distillation to remove the water, the residuum being used as solvent in preparing the spinning solution. The fibres may be submitted to one or more stretching operations, e.g. an air-stretch followed by a hot water- or steam-stretch, and thereafter heat-treated in the relaxed condition, e.g. in hot water or steam. Examples are given. Copolymers of acrylonitrile with vinyl esters, ethers, and ketones; acrylic acid and its esters and amide; methacrylic acid and its esters, amide and nitrile; maleic, itaconic, fumaric and crotonic acids and their esters, amides and nitriles; allyl alcohol and its esters or ethers; styrene and nuclear substituted styrenes, e.g. chloro- and dichlorostyrene; halogenated monoethylenic compounds such as vinyl chloride, vinyl fluoride, vinylidene chloride, 1, 2-dichloropropene-1, 1,2-dichloro-propene-2, allyl chloride, methallyl chloride, 2-chloro-allyl-alcohol and 1-allyloxy-3-chloro-2-propanol; N-vinyl compounds such as N-vinyl-pyrrolidone, N-vinyl succinimide or N-vinyl carbazole; N-tertiary butyl acrylamide, N-tertiary octyl acrylamide; and 2-or 4-vinylpyridine may be employed.
GB21409/52A 1951-09-08 1952-08-26 Improvements in wet spinning of acrylonitrile polymers Expired GB716081A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US245697A US2716586A (en) 1951-09-08 1951-09-08 Wet spinning of acrylonitrile polymers

Publications (1)

Publication Number Publication Date
GB716081A true GB716081A (en) 1954-09-29

Family

ID=22927697

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21409/52A Expired GB716081A (en) 1951-09-08 1952-08-26 Improvements in wet spinning of acrylonitrile polymers

Country Status (7)

Country Link
US (1) US2716586A (en)
BE (1) BE513901A (en)
CH (1) CH311155A (en)
DE (1) DE1030970B (en)
FR (1) FR1065710A (en)
GB (1) GB716081A (en)
NL (2) NL79123C (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2869974A (en) * 1955-03-02 1959-01-20 Du Pont Process for shrinking polyacrylonitrile textiles with specific chemical shrinking agents
US2869975A (en) * 1955-03-28 1959-01-20 Du Pont Process for shrinking and setting polyacrylonitrile textile filaments with specific chemical shrinking agents
DE1057285B (en) * 1955-08-18 1959-05-14 Dr Paul Halbig Process for the production of threads or fibers from polymers
US2948581A (en) * 1955-12-20 1960-08-09 American Cyanamid Co Method of producing a synthetic fiber
US3091507A (en) * 1956-08-27 1963-05-28 Dow Chemical Co Method of preventing ring dyeing in aquagel acrylonitrile polymer fibers by steamingthe fibers
BE565269A (en) * 1957-03-27
US3073669A (en) * 1958-09-06 1963-01-15 Asahi Chemical Ind Method for producing shaped articles from polymers and copolymers of acrylonitrile
NL249219A (en) * 1959-03-09 1900-01-01
US3069218A (en) * 1959-06-30 1962-12-18 Hermes Julius Dyed acrylonitrile containing textile having controlled shrinkage and processes for forming same
US3069222A (en) * 1959-06-30 1962-12-18 Hermes Julius Acrylonitrile containing textile having controlled shrinkage and processes for forming same
US3069221A (en) * 1959-06-30 1962-12-18 Hermes Julius Dyeing of acrylonitrile polymeric structures
DE1184896B (en) * 1960-09-07 1965-01-07 Hans J Zimmer Verfahrenstechni Process for the production of spinnable, non-gelling, approximately 15 to 22 percent by weight solutions of polyacrylonitrile or its copolymers
US3268490A (en) * 1962-03-07 1966-08-23 Sunden Olof Method of preparing polyacrylonitrile fibers
US3404204A (en) * 1964-03-07 1968-10-01 American Cyanamid Co Method of producing high-shrinkage acrylic fibers
US3523150A (en) * 1966-12-12 1970-08-04 Monsanto Co Manufacture of industrial acrylic fibers
US3505445A (en) * 1967-11-17 1970-04-07 Monsanto Co Solvent removal process for wet spun fibers
WO2010106143A1 (en) 2009-03-20 2010-09-23 Dsm Ip Assets B.V. Net for aquaculture

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2558733A (en) * 1949-06-08 1951-07-03 American Cyanamid Co Method of producing synthetic fibers from polymers and copolymers of acrylonitrile
BE496324A (en) * 1949-06-13
US2577763A (en) * 1949-11-05 1951-12-11 American Viscose Corp Wet spinning process
US2570257A (en) * 1950-06-17 1951-10-09 Ind Rayon Corp Spinning of acrylonitrile polymers

Also Published As

Publication number Publication date
BE513901A (en) 1900-01-01
NL79123C (en) 1900-01-01
FR1065710A (en) 1954-05-28
CH311155A (en) 1955-11-30
DE1030970B (en) 1958-05-29
US2716586A (en) 1955-08-30
NL172230B (en)

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