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GB672716A - Process for the improvement of textile articles - Google Patents

Process for the improvement of textile articles

Info

Publication number
GB672716A
GB672716A GB16491/49A GB1649149A GB672716A GB 672716 A GB672716 A GB 672716A GB 16491/49 A GB16491/49 A GB 16491/49A GB 1649149 A GB1649149 A GB 1649149A GB 672716 A GB672716 A GB 672716A
Authority
GB
United Kingdom
Prior art keywords
silicon
acetate
solvent
benzene
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16491/49A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodiaceta SA
Original Assignee
Rhodiaceta SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodiaceta SA filed Critical Rhodiaceta SA
Publication of GB672716A publication Critical patent/GB672716A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/60—Ammonia as a gas or in solution
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/78—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon; with halides or oxyhalides of silicon; with fluorosilicates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
    • D06M13/507—Organic silicon compounds without carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Textile articles made of cellulose esters possessing free hydroxyl groups are immersed in solutions containing not more than 10 per cent by weight of a compound or mixture of compounds of formula <FORM:0672716/IV (a)/1> wherein X1, X2, X3 and X4 are the same or different and each represents a halogen atom or an acyloxy radical, the solvent being an organic compound which is a non-solvent for the textile material. Suitable silicon compounds are silicon tetrachloride, silicon tetra-acetate, silicon tetrapropionate, silicon tetrabutyrate and silicon dichlorodiacetate. The organic solvent may have a slight swelling action, but not enough to alter the other properties or appearance of the textile material. Preferred solvents are benzene, xylene, perchlorethylene and allyl chloride. The process may include an aftertreatment with a hydrolysing agent to remove any excess of silicon derivative, either with water, aqueous sodium carbonate, alkaline phosphates or ammonium hydroxide or with ammonia gas. The treated textiles show an increased resistance to heat. The process may be applied at any treatment or finishing stage. In an example threads of cellulose acetate are treated for fifteen minutes at room temperature in fifty times their weight of an 8 per cent solution of silicon tetrachloride in allyl chloride. They are then dried in air. Example III describes the use of silicon tetra-acetate in benzene.ALSO:Textile articles made of cellulose esters possessing free hydroxyl groups are immersed in solutions containing not more than 10 per cent by weight of a compound or mixture of compounds of formula <FORM:0672716/IV (c)/1> wherein X1, X2, X3 and X4 are the same or different and each represents a halogen atom or an acyloxy radical, the solvent being an organic compound which is a non-solvent for the textile material. Suitable silicon compounds are silicon tetrachloride, silicon tetra-acetate, silicon tetrapropionate, silicon tetrabutyrate and silicon dichlorodiacetate. The organic solvent may have a slight swelling action, but not enough to alter the other properties or appearance of the textile material. Preferred solvents are benzene, xylene, perchlorethylene and allyl chloride. The process may include an after-treatment with a hydrolysing agent to remove any excess of silicon derivative, either with water, aqueous sodium carbonate, alkaline phosphates or ammonium hydroxide or with ammonia gas. The treated textiles show an increased resistance to heat. The process may be applied at any treatment or finishing stage. In an example, threads of cellulose acetate are treated for fifteen minutes at room temperature in fifty times their weight of an 8 per cent solution of silicon tetrachloride in allyl chloride. They are then dried in air. Example III describes the use of silicon tetra-acetate in benzene.
GB16491/49A 1948-06-21 1949-06-21 Process for the improvement of textile articles Expired GB672716A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR843395X 1948-06-21

Publications (1)

Publication Number Publication Date
GB672716A true GB672716A (en) 1952-05-28

Family

ID=9311902

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16491/49A Expired GB672716A (en) 1948-06-21 1949-06-21 Process for the improvement of textile articles

Country Status (5)

Country Link
BE (1) BE489191A (en)
CH (2) CH270805A (en)
DE (1) DE843395C (en)
FR (1) FR968252A (en)
GB (1) GB672716A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1156379B (en) * 1959-07-07 1963-10-31 Wacker Chemie Gmbh Process for improving the dry and damp heat resistance of formaldehyde-treated, optionally dyed polyvinyl alcohol textiles
US4068024A (en) * 1970-11-24 1978-01-10 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Process for preparing finely divided hydrophobic oxide particles
US4384013A (en) * 1979-12-10 1983-05-17 Desoto, Inc. Volatile amine-cured trialkoxysilyl-containing aqueous latex coatings
EP0508136A2 (en) * 1991-03-14 1992-10-14 Matsushita Electric Industrial Co., Ltd. Surface-treated apparel material

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE508810A (en) * 1951-02-07

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1156379B (en) * 1959-07-07 1963-10-31 Wacker Chemie Gmbh Process for improving the dry and damp heat resistance of formaldehyde-treated, optionally dyed polyvinyl alcohol textiles
US4068024A (en) * 1970-11-24 1978-01-10 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Process for preparing finely divided hydrophobic oxide particles
US4384013A (en) * 1979-12-10 1983-05-17 Desoto, Inc. Volatile amine-cured trialkoxysilyl-containing aqueous latex coatings
EP0508136A2 (en) * 1991-03-14 1992-10-14 Matsushita Electric Industrial Co., Ltd. Surface-treated apparel material
EP0508136A3 (en) * 1991-03-14 1993-01-07 Matsushita Electric Industrial Co., Ltd. Surface-treated apparel material
US5474839A (en) * 1991-03-14 1995-12-12 Matsushita Electric Industrial Co., Ltd. Surface-treated apparel material

Also Published As

Publication number Publication date
DE843395C (en) 1952-07-07
CH270805A (en) 1950-09-30
BE489191A (en)
FR968252A (en) 1950-11-23
CH276326A (en) 1951-06-30

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