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GB650928A - Process for the manufacture of sulphonated carbazole derivatives of the anthraquinone series - Google Patents

Process for the manufacture of sulphonated carbazole derivatives of the anthraquinone series

Info

Publication number
GB650928A
GB650928A GB32976/48A GB3297648A GB650928A GB 650928 A GB650928 A GB 650928A GB 32976/48 A GB32976/48 A GB 32976/48A GB 3297648 A GB3297648 A GB 3297648A GB 650928 A GB650928 A GB 650928A
Authority
GB
United Kingdom
Prior art keywords
benzoylamino
anthraquinone
acylamino
sulphonated
sulphonating agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32976/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB650928A publication Critical patent/GB650928A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B5/00Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
    • C09B5/24Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
    • C09B5/26Carbazoles of the anthracene series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Indole Compounds (AREA)

Abstract

Sulphonated carbazoles are made by treating with sulphonating agents at 0-60 DEG C. anthraquinone compounds of the formula <FORM:0650928/IV (c)/1> where X is hydrogen, halogen, alkyl, or alkoxy, and Y is hydrogen, alkyl, halogen, or acylamino. The products dye wool, leather, super-polyamides, and natural silk brown-yellow to brown shades. Sulphonating agents are concentrated sulphuric acid, the monohydrate, oleum, and chlorsulphonic acid, or mixtures thereof. The 1-acylamino groups may be acetylamino, chloracetylamino, propionylamino, phenylacetylamino, hexahydrobenzoylamino, benzoylamino, halogenbenzoylamino, nitrobenzoylamino, amino- or methoxy-benzoylamino, and phthaloylamino. The starting materials are prepared by condensing a 1.5-aminohalogenanthraquinone with an aminodiphenyl followed by acylation, or from a 1-acylamino - 5 - halogenanthraquinone and an aminodiphenyl, followed by acylation, if necessary. Examples describe the treatment with sulphonating agents of 1-benzoylamino-5-(41-phenylamilino)-anthraquinone and of 1-benzoylamino - 5 - benzoylbenzidino - anthraquinone. A further list of starting materials variously substituted as indicated is also given.
GB32976/48A 1947-12-29 1948-12-21 Process for the manufacture of sulphonated carbazole derivatives of the anthraquinone series Expired GB650928A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH650928X 1947-12-29

Publications (1)

Publication Number Publication Date
GB650928A true GB650928A (en) 1951-03-07

Family

ID=4526104

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32976/48A Expired GB650928A (en) 1947-12-29 1948-12-21 Process for the manufacture of sulphonated carbazole derivatives of the anthraquinone series

Country Status (1)

Country Link
GB (1) GB650928A (en)

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