GB604830A - Improvements in or relating to the stabilisation of chlorinated paraffin wax - Google Patents
Improvements in or relating to the stabilisation of chlorinated paraffin waxInfo
- Publication number
- GB604830A GB604830A GB3287445A GB3287445A GB604830A GB 604830 A GB604830 A GB 604830A GB 3287445 A GB3287445 A GB 3287445A GB 3287445 A GB3287445 A GB 3287445A GB 604830 A GB604830 A GB 604830A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- triethanolamine
- chlorinated
- iron
- stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012188 paraffin wax Substances 0.000 title abstract 3
- 230000006641 stabilisation Effects 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 4
- 229910052742 iron Inorganic materials 0.000 abstract 4
- 239000003381 stabilizer Substances 0.000 abstract 3
- 239000001993 wax Substances 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- -1 iron halides Chemical class 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000011135 tin Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/38—Chemical modification of petroleum
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Chlorinated paraffin wax is stabilized by incorporating at least 0.5 per cent of triethanolamine. Chlorinated waxes of differing chlorine content or their mixtures with such substances as esters, employed as plasticizers, may be treated, the amount of stabilizer being in excess of that required to neutralize all the hydrogen chloride liable to be liberated. Chlorinated paraffin wax with dibutyl phthalate in proportions of 60 : 40 by weight is stabilized by addition of 1 per cent of triethanolamine for 3-4 hrs. at 160 DEG C. or for at least 4-5 months at ordinary temperature. The colour imparted by the stabilizer may be removed by known methods for removing resinified impurities, e.g. filtration through fuller's earth. Triethanolamine inhibits the catalytic effect of metals and their compounds such as iron, zinc and iron halides. Examples compare the hydrogen chloride evolved when a chlorinated wax of 41 per cent chlorine content contaminated with small amounts of iron, tin, zinc and aluminium is heated at 160 DEG C., alone or after addition of 1 per cent triethanolamine and/or small amounts of ferric chloride. The effect of varying amounts of stabilizer, 0.1, 0.6 and 1 per cent, on a chlorinated wax, dibutyl phthalate mixture, with or without added iron, is also shown. Specifications 418,230 and 495,410 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3287445A GB604830A (en) | 1945-12-05 | 1945-12-05 | Improvements in or relating to the stabilisation of chlorinated paraffin wax |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3287445A GB604830A (en) | 1945-12-05 | 1945-12-05 | Improvements in or relating to the stabilisation of chlorinated paraffin wax |
Publications (1)
Publication Number | Publication Date |
---|---|
GB604830A true GB604830A (en) | 1948-07-12 |
Family
ID=10345309
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3287445A Expired GB604830A (en) | 1945-12-05 | 1945-12-05 | Improvements in or relating to the stabilisation of chlorinated paraffin wax |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB604830A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103289744A (en) * | 2013-06-14 | 2013-09-11 | 河北大景大搪化工设备有限公司 | Technique and device for continuously refining heavy liquid paraffin |
CN104560197A (en) * | 2014-12-23 | 2015-04-29 | 丹阳市助剂化工厂有限公司 | Tail gas processing process of chlorinated paraffin |
-
1945
- 1945-12-05 GB GB3287445A patent/GB604830A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103289744A (en) * | 2013-06-14 | 2013-09-11 | 河北大景大搪化工设备有限公司 | Technique and device for continuously refining heavy liquid paraffin |
CN104560197A (en) * | 2014-12-23 | 2015-04-29 | 丹阳市助剂化工厂有限公司 | Tail gas processing process of chlorinated paraffin |
CN104560197B (en) * | 2014-12-23 | 2016-06-15 | 丹阳市助剂化工厂有限公司 | The tail gas treatment process of chlorinated paraffin |
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