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GB566412A - An improved manufacture of diolefins - Google Patents

An improved manufacture of diolefins

Info

Publication number
GB566412A
GB566412A GB16141/41A GB1614141A GB566412A GB 566412 A GB566412 A GB 566412A GB 16141/41 A GB16141/41 A GB 16141/41A GB 1614141 A GB1614141 A GB 1614141A GB 566412 A GB566412 A GB 566412A
Authority
GB
United Kingdom
Prior art keywords
diolefins
olefins
isobutylene
acids
tertiary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16141/41A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB566412A publication Critical patent/GB566412A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Diolefins are made by subjecting polymers of branched chain olefins or copolymers of tertiary and secondary olefins to temperatures above 800 DEG F., e.g. 1200-1400 DEG F., if desired in presence of a catalyst composed of copper gauze, chromic oxide or bauxite. Thus, tertiary olefins in the C4, C5 and C6 naphthas are extracted by acids, polymerized by contacting with acids or acidic containing agents and then cracked. Examples give the results of cracking the dimer of trimethylethylene and the trimer of isobutylene. Mixtures of isobutylene and diolefins are obtained which can be copolymerised with AlCl3 or BF3 to give high molecular weight polymers. Specification 472,553 is referred to.
GB16141/41A 1940-12-19 1941-12-15 An improved manufacture of diolefins Expired GB566412A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US566412XA 1940-12-19 1940-12-19

Publications (1)

Publication Number Publication Date
GB566412A true GB566412A (en) 1944-12-29

Family

ID=22005723

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16141/41A Expired GB566412A (en) 1940-12-19 1941-12-15 An improved manufacture of diolefins

Country Status (1)

Country Link
GB (1) GB566412A (en)

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