GB501208A - Improvements in the separation of ammonia and hydrogen sulphide from gases - Google Patents
Improvements in the separation of ammonia and hydrogen sulphide from gasesInfo
- Publication number
- GB501208A GB501208A GB2333937A GB2333937A GB501208A GB 501208 A GB501208 A GB 501208A GB 2333937 A GB2333937 A GB 2333937A GB 2333937 A GB2333937 A GB 2333937A GB 501208 A GB501208 A GB 501208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- sulphur
- ammonium
- hydrogen sulphide
- gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 title abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 4
- 229910021529 ammonia Inorganic materials 0.000 title abstract 2
- 238000000926 separation method Methods 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 4
- 239000005864 Sulphur Substances 0.000 abstract 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 4
- 239000007788 liquid Substances 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 2
- 239000004291 sulphur dioxide Substances 0.000 abstract 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 abstract 2
- SPEMQUPJTGQFIM-UHFFFAOYSA-N triazanium;hydrogen sulfite;sulfite Chemical compound [NH4+].[NH4+].[NH4+].OS([O-])=O.[O-]S([O-])=O SPEMQUPJTGQFIM-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 150000004763 sulfides Chemical class 0.000 abstract 1
- WQDSRJBTLILEEK-UHFFFAOYSA-N sulfurous acid Chemical compound OS(O)=O.OS(O)=O WQDSRJBTLILEEK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000002912 waste gas Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Abstract
501,208. Gas purifying materials; sulphur ; ammonium salts. JOHNSON, G. W. (I. G. Farbenindustrie Akt.-Ges.) Aug. 25, 1937, No. 23339. Drawings to Specification. [Class 55 (ii)] [Also in Group III] Ammonia and hydrogen sulphide are removed 'from gases by scrubbing first with an ammonium sulphite - bisulphite solution, removing substantial amounts of hydrogen sulphide, then with an alkaline liquid containing heavy metal compounds forming sulphides which are afterwards regenerated by oxidizing gases; and finally with an ammonium sulphite-bisulphite solution, which is used for the first and final stages in either order and then added to the second stage liquid. Thiosulphate solution branched off from the cycle of the second stage liquid may be boiled to obtain sulphate and sulphur which may be used in preparing sulphur dioxide for making the sulphite-bisulphite solution ; or this may be derived from sulphur formed during the oxidation of the alkaline washing liquid, or from combustion of the hydrogen sulphide in waste gases from treatment of gas liquor. In an example, coke oven gas is first scrubbed with ammonium polysulphide to remove cyanogen and the ammonium thiocyanate formed may be caused to react with an excess of sulphuric, nitric, phosphoric, or hydrochloric acid, the said solution being added to concentrated thiosulphate solution from the second stage washer before boiling to obtain sulphate and sulphur. Or this solution may be acidified with sulphur dioxide and heated to 140‹ C. in a pressure-tight vessel:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2333937A GB501208A (en) | 1937-08-25 | 1937-08-25 | Improvements in the separation of ammonia and hydrogen sulphide from gases |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2333937A GB501208A (en) | 1937-08-25 | 1937-08-25 | Improvements in the separation of ammonia and hydrogen sulphide from gases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB501208A true GB501208A (en) | 1939-02-23 |
Family
ID=10194030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2333937A Expired GB501208A (en) | 1937-08-25 | 1937-08-25 | Improvements in the separation of ammonia and hydrogen sulphide from gases |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB501208A (en) |
-
1937
- 1937-08-25 GB GB2333937A patent/GB501208A/en not_active Expired
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