GB498225A - Process of producing cycloproprane - Google Patents
Process of producing cyclopropraneInfo
- Publication number
- GB498225A GB498225A GB15204/37A GB1520437A GB498225A GB 498225 A GB498225 A GB 498225A GB 15204/37 A GB15204/37 A GB 15204/37A GB 1520437 A GB1520437 A GB 1520437A GB 498225 A GB498225 A GB 498225A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iodide
- dichloropropane
- sodium
- zinc
- sodium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
- C07C1/28—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by ring closure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cyclopropane is prepared by reacting with zinc upon 1-chloro-3-iodopropane or 1 : 3-diiodopropane, or upon 1 : 3-dichloropropane in the presence of iodide ions, e.g. from sodium iodide. The addition of sodium carbonate or acetamide favours the formation of iodide ions. The product possesses anaesthetic properties. According to the examples: (1) 1 : 3-dichloropropane is slowly added to a mixture of zinc, sodium carbonate, acetamide and sodium iodide maintained at about 125 DEG C.; cyclopropane distils over and is collected; (2) a mixture of 1 : 3-dichloropropane, aqueous ethanol, sodium carbonate, sodium iodide and zinc dust is heated on the steam bath for some hours and the product collected. U.S.A. Specification 2,098,239 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US498225XA | 1936-06-13 | 1936-06-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB498225A true GB498225A (en) | 1939-01-02 |
Family
ID=21961921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15204/37A Expired GB498225A (en) | 1936-06-13 | 1937-06-01 | Process of producing cycloproprane |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB498225A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1110636B (en) * | 1960-04-11 | 1961-07-13 | Studiengesellschaft Kohle Mbh | Process for the production of cyclopropane hydrocarbons |
-
1937
- 1937-06-01 GB GB15204/37A patent/GB498225A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1110636B (en) * | 1960-04-11 | 1961-07-13 | Studiengesellschaft Kohle Mbh | Process for the production of cyclopropane hydrocarbons |
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