GB497708A - Improvements in or relating to the production and use of cation-exchange material - Google Patents
Improvements in or relating to the production and use of cation-exchange materialInfo
- Publication number
- GB497708A GB497708A GB16989/37A GB1698937A GB497708A GB 497708 A GB497708 A GB 497708A GB 16989/37 A GB16989/37 A GB 16989/37A GB 1698937 A GB1698937 A GB 1698937A GB 497708 A GB497708 A GB 497708A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- materials
- nascent oxygen
- alkaline medium
- exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/24—Carbon, coal or tar
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Gas Separation By Absorption (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Cation-exchange materials, which can be used for adsorbing bases from smoke, vapours or gases, for example for removing nicotine from smoke, are obtained by treating carbonaceous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid, or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkali bichromate.ALSO:Cation-exchange materials, which can be used in purifying sugar juice or in the preparation of pharmaceutical products, are obtained by treating carboniferous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkali-bichromate. Pharmaceutical products can be prepared by combining these base-exchange materials with alkaloids or other organic bases. In an example a solution of the chlorhydrate of butylester of p-dibutyl-amino-benzoic acid is run over base-exchange material saturated with calcium ions; it is stated that the product, when applied to a wound, stops h morrhage and sterilizes the wound. Specification 492,316, [Group I], is referred to.ALSO:Cation-exchange materials are obtained by treating carboniferous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described, lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkalibichromate. The products obtained can be used in treating water, the manufacture and separation of salts by base-exchange processes, the purification of sugar juice, for adsorbing bases from smoke, vapours or gases, for example for removing nicotine from smoke. Pharmaceutical products can be prepared by combining these base-exchange materials with alkaloids or other organic bases. In an example, a solution of the chlorhydrate of butylester of p-dibutylaminobenzoic acid is run over base-exchange material saturated with Ca cations; it is stated that the product, when applied to a wound, stops h morrhage and sterilizes the wound. Specification 492,316 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR497708X | 1937-04-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB497708A true GB497708A (en) | 1938-12-19 |
Family
ID=8904963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16989/37A Expired GB497708A (en) | 1937-04-23 | 1937-06-18 | Improvements in or relating to the production and use of cation-exchange material |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB497708A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2739598A (en) * | 1953-05-04 | 1956-03-27 | R S Aries And Associates Inc | Filter for tobacco smoke |
US2754829A (en) * | 1950-02-21 | 1956-07-17 | Howard V Hess | Smoke filter |
US2792006A (en) * | 1954-10-08 | 1957-05-14 | Anders Jordahl | Filters and filter material for use in filtering tobacco smoke |
US2800908A (en) * | 1955-09-29 | 1957-07-30 | Blank Samuel | Treatment of tobacco smoke |
US2815760A (en) * | 1951-12-24 | 1957-12-10 | Schreus Hans Theo | Tobacco smoke filter |
US3109436A (en) * | 1961-11-02 | 1963-11-05 | Bavley Abraham | Tobacco products |
-
1937
- 1937-06-18 GB GB16989/37A patent/GB497708A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2754829A (en) * | 1950-02-21 | 1956-07-17 | Howard V Hess | Smoke filter |
US2815760A (en) * | 1951-12-24 | 1957-12-10 | Schreus Hans Theo | Tobacco smoke filter |
US2739598A (en) * | 1953-05-04 | 1956-03-27 | R S Aries And Associates Inc | Filter for tobacco smoke |
US2792006A (en) * | 1954-10-08 | 1957-05-14 | Anders Jordahl | Filters and filter material for use in filtering tobacco smoke |
US2800908A (en) * | 1955-09-29 | 1957-07-30 | Blank Samuel | Treatment of tobacco smoke |
US3109436A (en) * | 1961-11-02 | 1963-11-05 | Bavley Abraham | Tobacco products |
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