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GB497708A - Improvements in or relating to the production and use of cation-exchange material - Google Patents

Improvements in or relating to the production and use of cation-exchange material

Info

Publication number
GB497708A
GB497708A GB16989/37A GB1698937A GB497708A GB 497708 A GB497708 A GB 497708A GB 16989/37 A GB16989/37 A GB 16989/37A GB 1698937 A GB1698937 A GB 1698937A GB 497708 A GB497708 A GB 497708A
Authority
GB
United Kingdom
Prior art keywords
acid
materials
nascent oxygen
alkaline medium
exchange
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16989/37A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AUXILIAIRE DES CHEMINS DE FER
LAuxiliaire des Chemins de Fer et de lIndustrie
Original Assignee
AUXILIAIRE DES CHEMINS DE FER
LAuxiliaire des Chemins de Fer et de lIndustrie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AUXILIAIRE DES CHEMINS DE FER, LAuxiliaire des Chemins de Fer et de lIndustrie filed Critical AUXILIAIRE DES CHEMINS DE FER
Publication of GB497708A publication Critical patent/GB497708A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/24Carbon, coal or tar

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Cation-exchange materials, which can be used for adsorbing bases from smoke, vapours or gases, for example for removing nicotine from smoke, are obtained by treating carbonaceous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid, or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkali bichromate.ALSO:Cation-exchange materials, which can be used in purifying sugar juice or in the preparation of pharmaceutical products, are obtained by treating carboniferous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkali-bichromate. Pharmaceutical products can be prepared by combining these base-exchange materials with alkaloids or other organic bases. In an example a solution of the chlorhydrate of butylester of p-dibutyl-amino-benzoic acid is run over base-exchange material saturated with calcium ions; it is stated that the product, when applied to a wound, stops h morrhage and sterilizes the wound. Specification 492,316, [Group I], is referred to.ALSO:Cation-exchange materials are obtained by treating carboniferous organic materials of mineral or vegetable origin with nascent oxygen in a concentrated acid or alkaline medium, the oxidation potential being at least 1,1 volt. The nascent oxygen may be set free in the acid or alkaline medium by dissolving therein a strong oxidizing agent. An oxidation catalyst may be present. Or the nascent oxygen may be liberated electrolytically. The materials may be subjected to two or more such treatments successively. In examples described, lignite, coal or anthracite is treated with acid or alkali containing potassium chlorate or alkalibichromate. The products obtained can be used in treating water, the manufacture and separation of salts by base-exchange processes, the purification of sugar juice, for adsorbing bases from smoke, vapours or gases, for example for removing nicotine from smoke. Pharmaceutical products can be prepared by combining these base-exchange materials with alkaloids or other organic bases. In an example, a solution of the chlorhydrate of butylester of p-dibutylaminobenzoic acid is run over base-exchange material saturated with Ca cations; it is stated that the product, when applied to a wound, stops h morrhage and sterilizes the wound. Specification 492,316 is referred to.
GB16989/37A 1937-04-23 1937-06-18 Improvements in or relating to the production and use of cation-exchange material Expired GB497708A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR497708X 1937-04-23

Publications (1)

Publication Number Publication Date
GB497708A true GB497708A (en) 1938-12-19

Family

ID=8904963

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16989/37A Expired GB497708A (en) 1937-04-23 1937-06-18 Improvements in or relating to the production and use of cation-exchange material

Country Status (1)

Country Link
GB (1) GB497708A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739598A (en) * 1953-05-04 1956-03-27 R S Aries And Associates Inc Filter for tobacco smoke
US2754829A (en) * 1950-02-21 1956-07-17 Howard V Hess Smoke filter
US2792006A (en) * 1954-10-08 1957-05-14 Anders Jordahl Filters and filter material for use in filtering tobacco smoke
US2800908A (en) * 1955-09-29 1957-07-30 Blank Samuel Treatment of tobacco smoke
US2815760A (en) * 1951-12-24 1957-12-10 Schreus Hans Theo Tobacco smoke filter
US3109436A (en) * 1961-11-02 1963-11-05 Bavley Abraham Tobacco products

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2754829A (en) * 1950-02-21 1956-07-17 Howard V Hess Smoke filter
US2815760A (en) * 1951-12-24 1957-12-10 Schreus Hans Theo Tobacco smoke filter
US2739598A (en) * 1953-05-04 1956-03-27 R S Aries And Associates Inc Filter for tobacco smoke
US2792006A (en) * 1954-10-08 1957-05-14 Anders Jordahl Filters and filter material for use in filtering tobacco smoke
US2800908A (en) * 1955-09-29 1957-07-30 Blank Samuel Treatment of tobacco smoke
US3109436A (en) * 1961-11-02 1963-11-05 Bavley Abraham Tobacco products

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