[go: up one dir, main page]

GB487593A - Manufacture of mixed polymerisation products soluble in benzine - Google Patents

Manufacture of mixed polymerisation products soluble in benzine

Info

Publication number
GB487593A
GB487593A GB28720/36A GB2872036A GB487593A GB 487593 A GB487593 A GB 487593A GB 28720/36 A GB28720/36 A GB 28720/36A GB 2872036 A GB2872036 A GB 2872036A GB 487593 A GB487593 A GB 487593A
Authority
GB
United Kingdom
Prior art keywords
vinyl
ester
maleic
atoms
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28720/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB28720/36A priority Critical patent/GB487593A/en
Publication of GB487593A publication Critical patent/GB487593A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Interpolymers soluble in benzine are prepared from a mixture of (a) a vinyl ester containing no straight, branched, or cyclic chain, uninterrupted by other atoms, of more than 4 carbon atoms with at least an equal quantity of (b) an ester of an aliphatic or cycloaliphatic alcohol containing an uninterrupted chain of more than 6 carbon atoms and an olefinic carboxylic acid whose esters polymerize when subjected in admixture with a vinyl ester to conditions which cause polymerization thereof. As (a) components are specified vinyl formate, acetate, propionate, and chloride; as (b) components are specified acrylic octyl, dodecyl, and terpineol esters; methacrylic bornyl ester; the corresponding maleic esters, and maleic diheptyl and di-iso-bornyl esters. In examples: (1) vinyl acetate and maleic di-iso-bornyl ester are heated in the presence of benzoyl peroxide; (2) vinyl propionate and acrylic terpineol ester are heated in benzine solution in the presence of oleic peroxide; (3) vinyl chloride and maleic diheptyl ester in emulsion in aqueous hydrogen peroxide and sodium oleate are heated under pressure. The products of examples (1) and (3) are stated to be soluble in aliphatic hydrocarbons and in linseed oil to form lacquers. According to the Provisional Specification, the interpolymers are prepared from olefinic monomers containing oxygen or halogen, the one (a) having no straight carbon chain of more than 4 atoms and the other (b) having at least one straight carbon chain of more than 6 atoms. The monomers may be compounds capable of polymerizing alone, or of co-polymerizing with another olefinic polymerizable monomer. As component (a) there are specified vinyl methyl ketone, methyl and ethyl acrylates, methacrylates and maleates; as component (b) there are specified vinyl laurate and stearate, methacrylic bornyl ester, and vinyl ethers of alcohols having more than 6 carbon atoms.
GB28720/36A 1936-10-22 1936-10-22 Manufacture of mixed polymerisation products soluble in benzine Expired GB487593A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB28720/36A GB487593A (en) 1936-10-22 1936-10-22 Manufacture of mixed polymerisation products soluble in benzine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB28720/36A GB487593A (en) 1936-10-22 1936-10-22 Manufacture of mixed polymerisation products soluble in benzine

Publications (1)

Publication Number Publication Date
GB487593A true GB487593A (en) 1938-06-22

Family

ID=10280011

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28720/36A Expired GB487593A (en) 1936-10-22 1936-10-22 Manufacture of mixed polymerisation products soluble in benzine

Country Status (1)

Country Link
GB (1) GB487593A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2604453A (en) * 1948-12-30 1952-07-22 Standard Oil Dev Co New copolymer compositions
US2628220A (en) * 1951-06-15 1953-02-10 Standard Oil Dev Co Alkyl maleate-vinyl ester copolymer
DE1003767B (en) * 1952-01-02 1957-03-07 Monsanto Chemicals Soil improvers
DE1005274B (en) * 1951-08-18 1957-03-28 Exxon Research Engineering Co Process for the preparation of lubricating oil improvers
DE1012417B (en) * 1951-08-22 1957-07-18 Exxon Research Engineering Co Mineral oil-based lubricating oil
US2980654A (en) * 1957-08-23 1961-04-18 Gen Aniline & Film Corp Copolymers of n-vinylpyrrolidones with dialkyl maleates or fumarates
US2999853A (en) * 1957-08-23 1961-09-12 Gen Aniline & Film Corp Copolymers of n-vinylpyrrolidones with dialkyl maleates or fumarates
US3038887A (en) * 1959-03-12 1962-06-12 Eastman Kodak Co Norcamphanyl esters of alpha, beta-unsaturated dicarboxylic acids and polymers thereof
US3056768A (en) * 1959-12-29 1962-10-02 Air Reduction Vinyl chloride copolymers and methods of making the same
US3058965A (en) * 1959-04-20 1962-10-16 Interchem Corp New acrylic copolymers and methods for producing same
US3196133A (en) * 1962-02-07 1965-07-20 Firestone Tire & Rubber Co Polymer composed of vinyl chloride, a dihydrocarbonyl ester of a monoethylenically unsaturated dicarboxylic acid, a monohydrogen, monohydrocarbonyl ester of a monoethylenically unsaturated polymerizable dicarboxylic acid, and an ester of acrylic or methacrylic acids

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2604453A (en) * 1948-12-30 1952-07-22 Standard Oil Dev Co New copolymer compositions
US2628220A (en) * 1951-06-15 1953-02-10 Standard Oil Dev Co Alkyl maleate-vinyl ester copolymer
DE1005274B (en) * 1951-08-18 1957-03-28 Exxon Research Engineering Co Process for the preparation of lubricating oil improvers
DE1012417B (en) * 1951-08-22 1957-07-18 Exxon Research Engineering Co Mineral oil-based lubricating oil
DE1003767B (en) * 1952-01-02 1957-03-07 Monsanto Chemicals Soil improvers
US2980654A (en) * 1957-08-23 1961-04-18 Gen Aniline & Film Corp Copolymers of n-vinylpyrrolidones with dialkyl maleates or fumarates
US2999853A (en) * 1957-08-23 1961-09-12 Gen Aniline & Film Corp Copolymers of n-vinylpyrrolidones with dialkyl maleates or fumarates
US3038887A (en) * 1959-03-12 1962-06-12 Eastman Kodak Co Norcamphanyl esters of alpha, beta-unsaturated dicarboxylic acids and polymers thereof
US3058965A (en) * 1959-04-20 1962-10-16 Interchem Corp New acrylic copolymers and methods for producing same
US3056768A (en) * 1959-12-29 1962-10-02 Air Reduction Vinyl chloride copolymers and methods of making the same
US3196133A (en) * 1962-02-07 1965-07-20 Firestone Tire & Rubber Co Polymer composed of vinyl chloride, a dihydrocarbonyl ester of a monoethylenically unsaturated dicarboxylic acid, a monohydrogen, monohydrocarbonyl ester of a monoethylenically unsaturated polymerizable dicarboxylic acid, and an ester of acrylic or methacrylic acids

Similar Documents

Publication Publication Date Title
GB487593A (en) Manufacture of mixed polymerisation products soluble in benzine
GB439390A (en) Improvements in or relating to the polymerisation of acrylic acid esters
ATE540T1 (en) PROCESS FOR THE MANUFACTURE OF AQUEOUS POLYACRYLATE DISPERSIONS WITH IMPROVED FLOW BEHAVIOR.
ES2116792T3 (en) PROCEDURE FOR THE OBTAINING OF WATER-BASED AND EXEMPTED POLYMER DISPERSIONS OF EMULSIONANTS.
GB605517A (en) A process for the manufacture of co-polymerisation products
GB1099152A (en) Improvements in or relating to aqueous dispersions of synthetic resins
ES414566A1 (en) Cross-linkable acrylic ester copolymers
GB1289194A (en)
GB838656A (en) Production of resinous compositions
GB535219A (en) Improvements in and relating to polymerizable compositions
GB1007165A (en) Process for the manufacture of stable aqueous dispersions of vinyl ester polymers
GB471755A (en) Improvements in or relating to the polymerisation of methacrylic acid esters
GB364089A (en) Improvements in the manufacture and production of polymerisation products
ES397735A1 (en) Process for the preparation of aqueous styrene/acrylic acid ester copolymer dispersions
GB1103674A (en) Improved denture compositions and their use
GB1034121A (en) Improvements in or relating to polyvinyl ester synthetic latices
GB469976A (en) Manufacture of artificial materials containing polymerised 2-chloro-1:3-butadiene
GB991550A (en) Process for the manufacture of stable aqueous dispersions of copolymers of vinyl esters of organic acids and ethylene
JPS54135882A (en) Emulsion polymerization
GB798565A (en) Improvements in the production of aqueous dispersions of ethylene polymers
GB1015874A (en) A process for the preparation of latices by emulsion polymerization
GB664715A (en) Polymeric lubricating oil additives
GB527494A (en) Improvements in or relating to the manufacture of resinous products derived from acrylic acid derivatives
GB615429A (en) Process for the polymerisation of unsaturated compounds
GB897340A (en) A process for the production of polyvinyl chloride and copolymers containing vinyl chloride