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GB435171A - Improvements in or relating to the colouring of materials - Google Patents

Improvements in or relating to the colouring of materials

Info

Publication number
GB435171A
GB435171A GB3457733A GB3457733A GB435171A GB 435171 A GB435171 A GB 435171A GB 3457733 A GB3457733 A GB 3457733A GB 3457733 A GB3457733 A GB 3457733A GB 435171 A GB435171 A GB 435171A
Authority
GB
United Kingdom
Prior art keywords
acid
printed
goods
dried
rinsed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3457733A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB3457733A priority Critical patent/GB435171A/en
Publication of GB435171A publication Critical patent/GB435171A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/02General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
    • D06P1/12General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes prepared in situ

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Azo dyes, forming on the material; printing.--In the production of azo dyestuffs on textile fibres by processes in which the development of the colour is effected by treatment with an acid hydrolyzing agent, the material is treated immediately before or during the hydrolysis with a strong solution of an inert salt. Specified salts are chlorides or sulphates of the alkali metals, aluminium or zinc, chlorides of the alkaline earth metals and sodium phosphates. The process is applicable to material impregnated or printed with the coupling component and with a diazo component in the form either of a diazoamino compound obtainable by coupling a diazo salt with a secondary amine or in the form of a nitrosamine alkali metal salt. The dyeings are of exceptional brightness and especially fast to light and washing. The following examples are specified. (1) Cotton piece goods are printed with an aqueous paste containing the diazoamino compound from diazotized 4-chloro-2-toluidine and methylglucamine, turkey red oil, the o-toluidide of 2 : 3-oxynaphthoic acid, caustic soda and a thickener and the printed goods are dried, immersed for 20 seconds in an aqueous solution at 220 DEG F. containing 1,0 per cent of acetic acid, 0,5 per cent of formic acid and 28 per cent of sodium chloride, rinsed, treated with a hot soap solution, again rinsed and dried to obtain a bright red pattern. (2) A brilliant orange pattern is similarly obtained using as diazoamino compound that from diazotized m-aminobenzotrifluoride and ethylxylamine and as coupling component the o-anisidide of 2 : 3-oxynaphthoic acid. (3) A yellow pattern is similarly obtained using the diazoamino compound from diazotized 2 : 5-dichloraniline and diethanolamine and as coupling component diacetoacetyltolidine. (4) Cotton piece goods are printed with an aqueous paste containing the bis-diazoamino compound from tetrazotized dianisidine and sarcosin, turkey red oil, the anilide of 2 : 3-oxynaphthoic acid, caustic soda and a thickener and the printed goods are immersed in a cold saturated sodium chloride solution, exposed to the action of steam carrying acetic acid vapour, washed, soaped, rinsed and dried to obtain a bright blue pattern. (5) Cotton piece goods are impregnated with an aqueous paste containing the diazoamino compound from diazotized p-toluene-azo-2 5-dimethoxyaniline and proline, turkey red oil, the o-toluidide of 2 3-oxynaphthoic acid, caustic soda and a thickener and the impregnated goods are immersed in an aqueous solution at 60 DEG F. containing acetic and formic acids and sodium chloride as in (1), passed over a metal roll heated to 220 DEG F., washed, soaped, rinsed and dried to obtain a deep blue-black dyeing. (6) Cotton piece goods are printed with an aqueous paste containing the diazoamino compound from diazotized 2 : 5-diethoxy-4-benzoylaminoaniline and nipecotinic acid, the o - toluidide of 2 : 3 - oxyanthracenecarboxylic acid, caustic soda and a thickener and the printed goods are dried, immersed in a cold acid sodium chloride solution as in (5), subjected to the action of live steam, washed, soaped, rinsed and dried to obtain a green pattern. (7) Cotton piece goods are printed with an aqueous paste containing the diazoamino compound from diazotized 4<1>-ethoxy-4-aminodiphenylamine and benzyltaurine, turkey red oil, the anilide of 2 : 3-oxynaphthoic acid, caustic soda and a thickener and the printed goods are dried, immersed for about 30 seconds in a boiling saturated potassium chloride solution containing 2 per cent of acetic acid, washed, soaped, rinsed and dried to obtain a fast navy blue print. (8) Cotton piece goods are printed with an aqueous paste containing the diazoamino compound from diazotized 1 - aminoanthraquinone and monoethyl - o - toluidine-4-sulphonic acid, turkey red oil, the anilide of 2 : 3-oxynaphthoic acid, caustic soda and a thickener and the printed goods are dried, immersed for 1 minute in a boiling saturated sodium sulphate solution containing acetic and formic acids, washed, soaped, rinsed and dried to obtain a bright red pattern. (9) Cotton piece goods are impregnated with an aqueous paste containing the diazoamino compound from diazotized 1-naphthylamine and 1 - methylaminonaphthalene - 2 : 4 - disulphonic acid, the anilide of 7-oxy-8-carboxy-a -naphthocarbazole, caustic soda and a thickener and the impregnated goods are immersed in a saturated potassium chloride solution, treated with steam containing formic acid vapour, washed, soaped, rinsed and dried to obtain a uniform black dyeing. (10) Cotton piece goods are printed over the whole surface with an aqueous paste containing the diazoamino compound from diazotized m-nitro-p-toluidine and p-toluidine-w-methanesulphonic acid, the o-toluidide of 2-oxycarbazole-3-carboxylic acid, caustic soda and a thickener, and the printed goods are further treated as in (1) to obtain a brown dyeing. The diazoamino compounds used may be any of the general formula Ar--N = N--R in which Ar is an aromatic residue of the benzene, naphthalene, diphenyl, diphenylamine, anthraquinone or carbazole series free from solubilizing groups such as sulphonic or carboxylic groups and carrying, if desired, substituents such as alkyl, alkoxy, halogen, nitro, trifluoromethyl or acylamino groups and R is the residue of a secondary amine containing at least one solubilizing group such as a sulphonic, carboxylic or hydroxyl group. In general, the coupling components may be the arylides of 2 : 3-oxynaphthoic acid, oxycarbazole-, oxynaphthocarbazole- and oxyanthracene-carboxylic acids, a or b -naphthol, acylaceto derivatives of aromatic amines, 2-methylindole and arylmethylpyrazolones. In an example of the use of a nitrosamine, cotton goods are printed with an aqueous paste containing a nitrosaminealkali metal salt of p-nitraniline, the anilide of 2 : 3-oxynaphthoic acid, sodium ricinoleate, caustic soda and tragacanth thickening and the printed goods are immersed in a boiling saturated sodium chloride solution containing acetic acid, rinsed, soaped, rinsed and dried to obtain a fast red pattern. Additional acid substances specified for use in the development are citric, tartaric, oxalic and monochloracetic acids, sodium dihydrogen phosphate, potassium hydrogen oxalate and sodium hydrogen sulphate.
GB3457733A 1933-12-08 1933-12-08 Improvements in or relating to the colouring of materials Expired GB435171A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3457733A GB435171A (en) 1933-12-08 1933-12-08 Improvements in or relating to the colouring of materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3457733A GB435171A (en) 1933-12-08 1933-12-08 Improvements in or relating to the colouring of materials

Publications (1)

Publication Number Publication Date
GB435171A true GB435171A (en) 1935-09-16

Family

ID=10367354

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3457733A Expired GB435171A (en) 1933-12-08 1933-12-08 Improvements in or relating to the colouring of materials

Country Status (1)

Country Link
GB (1) GB435171A (en)

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