GB355808A - Improvements in the manufacture of ?-aminothiophenols - Google Patents
Improvements in the manufacture of ?-aminothiophenolsInfo
- Publication number
- GB355808A GB355808A GB1661030A GB1661030A GB355808A GB 355808 A GB355808 A GB 355808A GB 1661030 A GB1661030 A GB 1661030A GB 1661030 A GB1661030 A GB 1661030A GB 355808 A GB355808 A GB 355808A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrolysed
- mercaptobenzthiazole
- mercapto
- treating
- elevated temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
O-Aminothiophenols are prepared by treating 2-mercaptoarylenethiazoles with aqueous caustic soda of from 5 to 40 per cent strength at an elevated temperature in a closed vessel. The reaction proceeds smoothly without formation of by-products so that the o-aminoarythioglycollic acids may be formed directly by treating the reacting solution with chloracetic acid. In examples 2-mercaptobenzthiazole is hydrolysed to o-aminothiophenol and the latter isolated as o-aminothioglycollic acid, 6-ethoxy-2-mercaptobenzthiazole is hydrolysed to 2 - amino - 5 - ethoxythiophenol, and 2 - mercapto-b (N).a -naphthathiazole is hydrolysed to 2-mercapto-1-naphthylamine. The Specification adverts to the prior use of hot alcoholic potash, whilst the Provisional Specification describes the treatment of 2-mercaptoarylenethioazoles with aqueous caustic alkali of less than 80 per cent strength at an elevated temperature and in a closed vessel.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1661030A GB355808A (en) | 1930-05-29 | 1930-05-29 | Improvements in the manufacture of ?-aminothiophenols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1661030A GB355808A (en) | 1930-05-29 | 1930-05-29 | Improvements in the manufacture of ?-aminothiophenols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB355808A true GB355808A (en) | 1931-08-31 |
Family
ID=10080429
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1661030A Expired GB355808A (en) | 1930-05-29 | 1930-05-29 | Improvements in the manufacture of ?-aminothiophenols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB355808A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2454260A (en) * | 1946-02-12 | 1948-11-16 | Hoffmann La Roche | Preparation of metal mercaptides of amino-aryl mercaptans |
US2791612A (en) * | 1955-10-10 | 1957-05-07 | American Cyanamid Co | Isolation process for 2-aminothiophenol |
-
1930
- 1930-05-29 GB GB1661030A patent/GB355808A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2454260A (en) * | 1946-02-12 | 1948-11-16 | Hoffmann La Roche | Preparation of metal mercaptides of amino-aryl mercaptans |
US2791612A (en) * | 1955-10-10 | 1957-05-07 | American Cyanamid Co | Isolation process for 2-aminothiophenol |
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