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GB355808A - Improvements in the manufacture of ?-aminothiophenols - Google Patents

Improvements in the manufacture of ?-aminothiophenols

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Publication number
GB355808A
GB355808A GB1661030A GB1661030A GB355808A GB 355808 A GB355808 A GB 355808A GB 1661030 A GB1661030 A GB 1661030A GB 1661030 A GB1661030 A GB 1661030A GB 355808 A GB355808 A GB 355808A
Authority
GB
United Kingdom
Prior art keywords
hydrolysed
mercaptobenzthiazole
mercapto
treating
elevated temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1661030A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COLIN HENRY LUMSDEN
Imperial Chemical Industries Ltd
Original Assignee
COLIN HENRY LUMSDEN
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by COLIN HENRY LUMSDEN, Imperial Chemical Industries Ltd filed Critical COLIN HENRY LUMSDEN
Priority to GB1661030A priority Critical patent/GB355808A/en
Publication of GB355808A publication Critical patent/GB355808A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

O-Aminothiophenols are prepared by treating 2-mercaptoarylenethiazoles with aqueous caustic soda of from 5 to 40 per cent strength at an elevated temperature in a closed vessel. The reaction proceeds smoothly without formation of by-products so that the o-aminoarythioglycollic acids may be formed directly by treating the reacting solution with chloracetic acid. In examples 2-mercaptobenzthiazole is hydrolysed to o-aminothiophenol and the latter isolated as o-aminothioglycollic acid, 6-ethoxy-2-mercaptobenzthiazole is hydrolysed to 2 - amino - 5 - ethoxythiophenol, and 2 - mercapto-b (N).a -naphthathiazole is hydrolysed to 2-mercapto-1-naphthylamine. The Specification adverts to the prior use of hot alcoholic potash, whilst the Provisional Specification describes the treatment of 2-mercaptoarylenethioazoles with aqueous caustic alkali of less than 80 per cent strength at an elevated temperature and in a closed vessel.
GB1661030A 1930-05-29 1930-05-29 Improvements in the manufacture of ?-aminothiophenols Expired GB355808A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1661030A GB355808A (en) 1930-05-29 1930-05-29 Improvements in the manufacture of ?-aminothiophenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1661030A GB355808A (en) 1930-05-29 1930-05-29 Improvements in the manufacture of ?-aminothiophenols

Publications (1)

Publication Number Publication Date
GB355808A true GB355808A (en) 1931-08-31

Family

ID=10080429

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1661030A Expired GB355808A (en) 1930-05-29 1930-05-29 Improvements in the manufacture of ?-aminothiophenols

Country Status (1)

Country Link
GB (1) GB355808A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2454260A (en) * 1946-02-12 1948-11-16 Hoffmann La Roche Preparation of metal mercaptides of amino-aryl mercaptans
US2791612A (en) * 1955-10-10 1957-05-07 American Cyanamid Co Isolation process for 2-aminothiophenol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2454260A (en) * 1946-02-12 1948-11-16 Hoffmann La Roche Preparation of metal mercaptides of amino-aryl mercaptans
US2791612A (en) * 1955-10-10 1957-05-07 American Cyanamid Co Isolation process for 2-aminothiophenol

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