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GB2388367A - A process for making rare earth doped optical fibre - Google Patents

A process for making rare earth doped optical fibre Download PDF

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Publication number
GB2388367A
GB2388367A GB0318455A GB0318455A GB2388367A GB 2388367 A GB2388367 A GB 2388367A GB 0318455 A GB0318455 A GB 0318455A GB 0318455 A GB0318455 A GB 0318455A GB 2388367 A GB2388367 A GB 2388367A
Authority
GB
United Kingdom
Prior art keywords
core
solution
rare earth
earth doped
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB0318455A
Other versions
GB2388367B (en
GB0318455D0 (en
Inventor
Tarun Bandyopadhyay
Ranjansen
Shyamal Kumar Bhadra
Kamal Dasgupta
Mukul Chandra Paul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MINISTRY OF INFORMATION TECHNO
Council of Scientific and Industrial Research CSIR
Original Assignee
MINISTRY OF INFORMATION TECHNO
Council of Scientific and Industrial Research CSIR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MINISTRY OF INFORMATION TECHNO, Council of Scientific and Industrial Research CSIR filed Critical MINISTRY OF INFORMATION TECHNO
Publication of GB0318455D0 publication Critical patent/GB0318455D0/en
Publication of GB2388367A publication Critical patent/GB2388367A/en
Application granted granted Critical
Publication of GB2388367B publication Critical patent/GB2388367B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • C03B37/01807Reactant delivery systems, e.g. reactant deposition burners
    • C03B37/01838Reactant delivery systems, e.g. reactant deposition burners for delivering and depositing additional reactants as liquids or solutions, e.g. for solution doping of the deposited glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • C03B37/01807Reactant delivery systems, e.g. reactant deposition burners
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • C03B37/01853Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/08Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant
    • C03B2201/12Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant doped with fluorine
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/20Doped silica-based glasses doped with non-metals other than boron or fluorine
    • C03B2201/28Doped silica-based glasses doped with non-metals other than boron or fluorine doped with phosphorus
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/30Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C03B2201/31Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with germanium
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/30Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C03B2201/34Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with rare earth metals, i.e. with Sc, Y or lanthanides, e.g. for laser-amplifiers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses
    • C03B2201/30Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi
    • C03B2201/34Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with rare earth metals, i.e. with Sc, Y or lanthanides, e.g. for laser-amplifiers
    • C03B2201/36Doped silica-based glasses doped with metals, e.g. Ga, Sn, Sb, Pb or Bi doped with rare earth metals, i.e. with Sc, Y or lanthanides, e.g. for laser-amplifiers doped with rare earth metals and aluminium, e.g. Er-Al co-doped
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Lasers (AREA)
  • Glass Compositions (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)

Abstract

The present invention provides an improved process for making rare earth doped preforms and fibres by a combination of MCVD technique and solution doping method, said method comprising developing matched or depressed clad structure inside a silica glass substrate tube followed by deposition of unsintered particulate layer containing GeO2 and P2O5 for formation of the core and solution doping by soaking the porous soot layer into an alcoholic/aqueous solution of RE-salts containing co-dopants like AlCl3 / Al(NO3)3 in definite proportion, controlling the porosity of the soot, dipping period, strength of the solution and the proportion of the codopants to achieve the desired RE ion concentration in the core and minimise the core clad boundary defects and followed by drying, oxidation, dehydration and sintering of the RE containing porous deposit and collapsing at a high temperature to produce the preform and overladding with silica tubes of suitable dimensions and fibre drawing to produce fibres.

Description

GB 2388367 A continued (72) Inventor(s): Tarun Bandyopadhyay Ranjan Sen
Shyamal Kumar Bhadra Kamal Dasgupta Mukul Chandra Paul (74) Agent and/or Address for Service: A A Thornton & Co 235 High Holborn' LONDON, WC1V 7LE, United Kingdom
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER 1-. THAI ON 1 LOOPTEl ION l MEAI (Tat 1) (19)WorldIntellectualPropertyOrganization International Bureau '__ (43) International Publication Date (10) International Publication Number HAugust2002 (0X.0X.2002)PCT WO 02/060830 Al (51) InternationalPatentClassification:C03B37/Ot8. (IN>. SEN, Ranjan ilNllNi: ('entral Glass and t''eramic E101 S 310G7. CrO213 f,/16 Rcscar.-h Institute. 196. Kaja S.('. Mulik, Calcutta 700 (132 (IN). (21) International Application Number:PC['/INOI/001\14 (74) Agent: GABRIEL, Devadoss, Calab. Kumaran Sagar.
(22) International Filing Date: February 2()UI (0.0.20()1) 84-(', C:6 Lanes Sainik E'arms. New Delhi 110 06 (IN).
(25) Filing Language: English (81) Designated States /nationalj: AK, A(n AL, AM. A'l', Atl.
AZ, BA. BB. H(l, HE. BY. BZ, CA. Clf, CN, CR. Cl1, CZ.
(26) Publication Language: English r)ln OK. DM, DZ. FE. ES, Fl. GB. GD, Gl', GH, GM. HR.
IlU,0),M,lN.IS.JP,KE.KO,KP,KR.K/.LC.l.K,l.R. I S. 1'1', 1.11, 1.\1, MA. MD' M(J. MK. MN, MW. M\, MZ
(71) Applicants valor all designated Stale. except INS): MIN-,rK,T,r. Tz lEJl; RO. Rl), SD, SE. SG Sl, SK. Sl. l'J, TM.
Scope Complex, Lodhi Road, New Delhi 110 003 (IN).
COUNCIL OF SCIENTIFIC AND INDUSTRL\L RE
SEARCH flNlih;-l; Ran Marg, 110 001 New Delhi (1) (84) Designated States (regional/: ARIPO patent ((ill. CiM, BHADRA, Shyamal. Kumar IINm9]; Ceutra1 Glass and OF, IS. MVv, MZ, Sly). Sly,. SZ, TZ, ITG, ZWh Eurasian (2eramic Research Institute, 196. Raja S C. Mulik. Calcutta patent (AM, A; [, t3 Y. KG. KZ. MD, RU, 'I'J, I'M), European 7()()032 (INK DASGUPTA, Kamal IINIINi: Central Glass patent (A'l', BE, Cll. CY, DE. OK, ES. 1'1. t R. OH. OR. [E, and Ceramic Research Institute, 196. Raja S.C. Mulik, ('al- IJ'. Lll. MC. NL, P'l: SE, 'I'R), OAPI patent (BI-: BJ, Cl.
curia 70() 03 (IN). PALiL, Mu kul, Cha ndra I IN/II': Cen- ('(i, Cl, ('M, GA. ON. GW. ML. MR. NF..SN. 1'1), 'I G! tral Glass and Ceramic Research Institute, 196. Raja S.C.
Mulik. (Calcutta 700 032 (IN). Published: with international search report (72) Inventors; and (75) Inventors/Applicants rJor l 'S only): BANDVOPAD- For two-lelter codes and other abbreviations. refer tc> the "C; ud HYAY, Tarun l[NIII4I. Central Glass and ('eratnic ance. \rotesonC'odesand.4bbrevianons' appearingalthebe,gin Research Institute. 196. Raja S.C2. Mulik. (2alcotta 700 ()3 ning of each regular issue of the PC7 Gazelle i 1\ O (54) Title: A PROCESS FOR MAKIN('RARF. t.AR'I'}I DOPED OPTI(:AI FlBRt' X O (57) Abstract: The present invention provides an improved process for making rare earth doped preforms and fibres by a combi-
0 nation of M('VD technique and solution doping method, said method comprising developing matched or depressed clad structure inside a silica glass substrate tube followed by deposition of unsiniered particulate layer containing Gc02 and P205 for formation of O the core and solution doping by soaking the porous soot lays r into an alcoholic/aqueous solution of Rt.-salts containing co-dopants like A]C'I I AItNO3)3 in definite proportion, controlling the porosity of the soot, dipping period. strength of the solution and the O proportion of the codopants to achieve the desired Rli. ion concentration in the cure and minimise the core clad bc>undary defects and iollcwed by drying. oxidation, dehydration and sintenng of the HE containing porous deposit and collapsing at a high temperature to produce the preform and overladding with silica tubes of suitable dimensions and fibre drawing to prc>duce fibres
GB0318455A 2001-02-02 2001-02-02 A process for making rare earth doped optical fibre Expired - Lifetime GB2388367B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IN2001/000014 WO2002060830A1 (en) 2001-02-02 2001-02-02 A process for making rare earth doped optical fibre

Publications (3)

Publication Number Publication Date
GB0318455D0 GB0318455D0 (en) 2003-09-10
GB2388367A true GB2388367A (en) 2003-11-12
GB2388367B GB2388367B (en) 2005-05-18

Family

ID=11076302

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0318455A Expired - Lifetime GB2388367B (en) 2001-02-02 2001-02-02 A process for making rare earth doped optical fibre

Country Status (6)

Country Link
KR (1) KR100655480B1 (en)
CN (1) CN1274618C (en)
AU (1) AU2001242728B2 (en)
CA (1) CA2436579C (en)
GB (1) GB2388367B (en)
WO (1) WO2002060830A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040112089A1 (en) * 2002-12-16 2004-06-17 Digiovanni David J. Manufacture of optical fibers using enhanced doping
CA2454896A1 (en) * 2003-01-16 2004-07-16 Sumitomo Electric Industries, Ltd. Method of producing optical fiber preform, and optical fiber preform and optical fiber produced with the method
CN101479205B (en) * 2006-06-26 2013-02-20 住友电气工业株式会社 Process for producing optical fiber base, process for producing optical fiber, and optical fiber
JP5018492B2 (en) * 2008-01-15 2012-09-05 住友電気工業株式会社 Preform manufacturing method
FR2939522B1 (en) * 2008-12-08 2011-02-11 Draka Comteq France OPTICAL FIBER AMPLIFIER RESISTANT TO IONIZING RADIATION
CN102086089A (en) * 2010-12-27 2011-06-08 富通集团有限公司 Method for manufacturing rare-earth-doped fiber precast rod
CN102515501B (en) * 2011-11-29 2014-04-30 富通集团有限公司 Method for manufacturing doped optical fibre preform by MCVD (modified chemical vapour deposition)
CN104058587B (en) * 2014-07-14 2016-06-22 富通集团有限公司 A kind of rare earth doped optical fibre prefabricated rods and preparation method thereof
CN106966581A (en) * 2017-05-18 2017-07-21 江苏亨通光导新材料有限公司 A kind of preform and preparation method thereof
CN110467342A (en) * 2019-08-15 2019-11-19 武汉长进激光技术有限公司 A kind of ultra wide band gain Er-doped fiber and preparation method thereof
CN110467343A (en) * 2019-08-23 2019-11-19 武汉长进激光技术有限公司 A kind of nano-porous glass material hydroxyl-removal sintering method
CN110510864A (en) * 2019-09-11 2019-11-29 烽火通信科技股份有限公司 The preparation method and preform of highly doped rare-earth-doped fiber precast rod
US11673831B2 (en) * 2019-10-01 2023-06-13 The Hong Kong University Of Science And Technology Method for preparing optical fibers with high-particle-coated porous polymeric outer coating layers
CN111847864A (en) * 2020-06-16 2020-10-30 武汉长进激光技术有限公司 C-band expanded broadband gain erbium-doped optical fiber and preparation method thereof
CN115448590A (en) * 2022-08-31 2022-12-09 长飞光纤光缆股份有限公司 Method for preparing rare earth doped optical fiber preform by in-tube method
CN118026517A (en) * 2024-01-31 2024-05-14 武汉长进光子技术股份有限公司 Solution doping device and doping method for preparing optical fiber preform

Citations (3)

* Cited by examiner, † Cited by third party
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EP0451293A1 (en) * 1989-10-31 1991-10-16 Fujitsu Limited Production method for optical fiber base material
EP0466932A1 (en) * 1990-02-05 1992-01-22 The Furukawa Electric Co., Ltd. Quartz glass doped with rare earth element and production thereof
EP1043281A1 (en) * 1999-04-09 2000-10-11 Spectran Corporation Method of fabricating preforms doped with rare earth metal for optical fibers

Family Cites Families (4)

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US5005175A (en) 1989-11-27 1991-04-02 At&T Bell Laboratories Erbium-doped fiber amplifier
JP2766420B2 (en) 1992-04-07 1998-06-18 株式会社フジクラ Method for producing erbium-doped quartz
GB2273389B (en) 1992-12-14 1996-07-17 Pirelli Cavi Spa Rare earth doped optical fibre amplifiers
JP3773575B2 (en) 1996-01-12 2006-05-10 富士通株式会社 Doped fiber, splicing method thereof, and optical amplifier

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0451293A1 (en) * 1989-10-31 1991-10-16 Fujitsu Limited Production method for optical fiber base material
EP0466932A1 (en) * 1990-02-05 1992-01-22 The Furukawa Electric Co., Ltd. Quartz glass doped with rare earth element and production thereof
EP1043281A1 (en) * 1999-04-09 2000-10-11 Spectran Corporation Method of fabricating preforms doped with rare earth metal for optical fibers

Also Published As

Publication number Publication date
CA2436579C (en) 2006-09-26
WO2002060830A1 (en) 2002-08-08
GB2388367B (en) 2005-05-18
KR100655480B1 (en) 2006-12-08
KR20040034595A (en) 2004-04-28
CA2436579A1 (en) 2002-08-08
CN1274618C (en) 2006-09-13
WO2002060830A8 (en) 2003-11-20
CN1500069A (en) 2004-05-26
GB0318455D0 (en) 2003-09-10
AU2001242728B2 (en) 2007-05-10

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PE20 Patent expired after termination of 20 years

Expiry date: 20210201