GB1480112A - Production of shaped articles - Google Patents
Production of shaped articlesInfo
- Publication number
- GB1480112A GB1480112A GB40640/74A GB4064074A GB1480112A GB 1480112 A GB1480112 A GB 1480112A GB 40640/74 A GB40640/74 A GB 40640/74A GB 4064074 A GB4064074 A GB 4064074A GB 1480112 A GB1480112 A GB 1480112A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- present
- initiator
- sodium
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
- C08L13/02—Latex
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Moulding By Coating Moulds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
1480112 Diene rubber latex production; and its coagulation BAYER AG 18 Sept 1974 [22 Sept 1973] 40640/74 Heading C3P A monomer mixture comprising (by weight) 85-50 parts butadiene and/or isoprene, 10-40 parts (meth)acrylonitrile and 0À1-10 parts α,#- unsaturated acid is polymerized in aqueous emulsion at 10-80 C. at pH below 7 in the presence of initiator, molecular weight modifier and 0À5-6% of alkyl aryl sulphonate to give a latex containing rubber having a Defo value less than 2000 and particle diameter not more than 200 nm.; the pH is adjusted with alkali metal hydroxide to above 8 and the rubber then precipitated with coagulant. Additionally up to 40 parts styrene and up to 10 parts (meth)- acrylamide or the N-methylol, ether, ester or urethane derivative thereof may be present as may up to 5% of a further surface active substance, e.g. alkali metal sulphonate or sulphate or a non-ionic emulsifier. In Example 1, the sodium salt of naphthalene-#-sulphonic acid/ formaldehyde condensation product and FeSO 4 were also present together with t-dodecyl mercaptan and formaldehyde sulphoxylate: tbutylhydroperoxide was used as initiator. In Example 2, FeCl 2 was present with n-dodecylmercaptan: the initiator was p-menthane hydroperoxide used with formaldehyde sulphoxylate. The polymerization may be stopped before pH adjustment by addition of e.g. sodium bisulphite, sodium dithionite, Rongalite (Registered Trade Mark), hydroxylamine, dialkylhydroxylamines, hydrazine or sodium dimethyl dithiocarbamate. Subsequent cross-linking may be facilitated by the presence in the latex of, e.g. zinc oxide together, if desired with a vulcanizing agent (several disclosed). Stabilizers, e.g. casein, cellulose derivatives, styrene/maleic acid ester copolymers or polyacrylic acid may also be present. As coagulants, Ca(NO 3 ) 2 or CaCl 2 may be used with water or organic solvents. The product may be coagulated in the form of a film on the surface of a coagulant-coated mould or as a continuously extruded article.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2347755A DE2347755B2 (en) | 1973-09-22 | 1973-09-22 | Use of rubber latices for the production of dipping articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1480112A true GB1480112A (en) | 1977-07-20 |
Family
ID=5893339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB40640/74A Expired GB1480112A (en) | 1973-09-22 | 1974-09-18 | Production of shaped articles |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS5541601B2 (en) |
| BE (1) | BE820146A (en) |
| BR (1) | BR7407844D0 (en) |
| CA (1) | CA1053869A (en) |
| CS (1) | CS202540B2 (en) |
| DE (1) | DE2347755B2 (en) |
| ES (1) | ES430285A1 (en) |
| FR (1) | FR2244787B1 (en) |
| GB (1) | GB1480112A (en) |
| IN (1) | IN142708B (en) |
| IT (1) | IT1019341B (en) |
| NL (1) | NL176175C (en) |
| PL (1) | PL110067B1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0142174A2 (en) * | 1983-11-15 | 1985-05-22 | Dainippon Ink And Chemicals, Inc. | Heat-resistant high impact styrene resin, process for production thereof, and resin composition comprising said styrene resin |
| WO2002036665A1 (en) * | 2000-10-30 | 2002-05-10 | Zeon Corporation | Dip moldings, composition for dip molding and method for producing dip moldings |
| EP1209186A1 (en) * | 1999-05-28 | 2002-05-29 | Suzuki Latex Industry Co., Ltd. | Nontacky latex products |
| EP1215236A2 (en) * | 2000-12-12 | 2002-06-19 | Takeda Chemical Industries, Ltd. | A latex for dip molding and a dip molded product |
| WO2003080722A1 (en) * | 2002-03-27 | 2003-10-02 | Zeon Corporation | Dip-forming composition, dip-formed article and process for making same |
| EP2161288A1 (en) * | 2008-09-09 | 2010-03-10 | Polimeri Europa S.p.A. | Process for the elimination of residual mercaptans from nitrile rubbers |
| GB2594352A (en) * | 2020-02-17 | 2021-10-27 | Korea Kumho Petrochemical Co Ltd | Latex composition for dip molding and dip-molded article including the same |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1563236A (en) * | 1976-10-06 | 1980-03-19 | Doverstrand Ltd | Copolymer latices and their use in paper coating compositions having pick resistance |
| DE3018385A1 (en) * | 1980-05-14 | 1982-01-21 | Bayer Ag, 5090 Leverkusen | METHOD FOR TREATING FIBER MATERIALS |
| DE3118200A1 (en) * | 1981-05-08 | 1982-11-25 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING HIGH-NITRILE RUBBER RUBBER |
| DE3119612A1 (en) * | 1981-05-16 | 1982-12-02 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING THERMOSENSIBILIZABLE SYNTHESIS RUBBER LATICES |
| DE3406231A1 (en) * | 1984-02-21 | 1985-08-29 | Bayer Ag, 5090 Leverkusen | Laminated dip-moulded articles and production thereof |
| NL8600359A (en) * | 1986-02-13 | 1987-09-01 | Polysar Financial Services Sa | LATEX, PROCESS FOR THE MANUFACTURE OF A CONSOLIDATED FILES AND CONSOLIDATED FILES, MADE BY THE METHOD. |
| JP2515976B2 (en) * | 1986-02-27 | 1996-07-10 | 日本ゼオン 株式会社 | Method for producing sulfur master batch |
| JP2692483B2 (en) * | 1992-03-03 | 1997-12-17 | 日本ゼオン株式会社 | Latex for dip molding and dip molding |
| JP2007031574A (en) * | 2005-07-27 | 2007-02-08 | Nippon A & L Kk | Copolymer latex for dip molding, dip molding composition and dip-molded product |
| WO2007026704A1 (en) * | 2005-08-31 | 2007-03-08 | Zeon Corporation | Composition for dip molding and dip molded product |
| JP7046611B2 (en) * | 2017-08-21 | 2022-04-04 | 住友精化株式会社 | Method for manufacturing latex composition |
| CN114894929A (en) * | 2022-04-29 | 2022-08-12 | 华能国际电力股份有限公司 | Digestion and detection method for cation exchange resin dissolved matter |
-
1973
- 1973-09-22 DE DE2347755A patent/DE2347755B2/en not_active Ceased
-
1974
- 1974-08-24 IN IN1909/CAL/74A patent/IN142708B/en unknown
- 1974-09-18 GB GB40640/74A patent/GB1480112A/en not_active Expired
- 1974-09-20 CS CS746497A patent/CS202540B2/en unknown
- 1974-09-20 BR BR7844/74A patent/BR7407844D0/en unknown
- 1974-09-20 FR FR7431872A patent/FR2244787B1/fr not_active Expired
- 1974-09-20 BE BE148728A patent/BE820146A/en not_active IP Right Cessation
- 1974-09-20 NL NLAANVRAGE7412481,A patent/NL176175C/en not_active IP Right Cessation
- 1974-09-20 PL PL1974174227A patent/PL110067B1/en unknown
- 1974-09-20 CA CA209,716A patent/CA1053869A/en not_active Expired
- 1974-09-20 IT IT53116/74A patent/IT1019341B/en active
- 1974-09-20 JP JP10785774A patent/JPS5541601B2/ja not_active Expired
- 1974-09-21 ES ES430285A patent/ES430285A1/en not_active Expired
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0142174A3 (en) * | 1983-11-15 | 1987-01-14 | Dainippon Ink And Chemicals, Inc. | Heat-resistant high impact styrene resin, process for production thereof, and resin composition comprising said styrene resin |
| EP0142174A2 (en) * | 1983-11-15 | 1985-05-22 | Dainippon Ink And Chemicals, Inc. | Heat-resistant high impact styrene resin, process for production thereof, and resin composition comprising said styrene resin |
| EP1209186A4 (en) * | 1999-05-28 | 2004-04-07 | Suzuki Latex Industry Co Ltd | Nontacky latex products |
| EP1209186A1 (en) * | 1999-05-28 | 2002-05-29 | Suzuki Latex Industry Co., Ltd. | Nontacky latex products |
| US6939617B2 (en) | 1999-05-28 | 2005-09-06 | Suzuki Latex Industry Co., Ltd. | Non-adhesive latex products |
| WO2002036665A1 (en) * | 2000-10-30 | 2002-05-10 | Zeon Corporation | Dip moldings, composition for dip molding and method for producing dip moldings |
| US7183347B2 (en) | 2000-10-30 | 2007-02-27 | Zeon Corporation | Dip moldings, composition for dip molding and method for producing dip moldings |
| US6870019B2 (en) | 2000-12-12 | 2005-03-22 | Nippon A & L Inc. | Latex for dip molding and a dip molded product |
| EP1215236A3 (en) * | 2000-12-12 | 2003-06-04 | Takeda Chemical Industries, Ltd. | A latex for dip molding and a dip molded product |
| EP1215236A2 (en) * | 2000-12-12 | 2002-06-19 | Takeda Chemical Industries, Ltd. | A latex for dip molding and a dip molded product |
| WO2003080722A1 (en) * | 2002-03-27 | 2003-10-02 | Zeon Corporation | Dip-forming composition, dip-formed article and process for making same |
| EP2161288A1 (en) * | 2008-09-09 | 2010-03-10 | Polimeri Europa S.p.A. | Process for the elimination of residual mercaptans from nitrile rubbers |
| ITMI20081603A1 (en) * | 2008-09-09 | 2010-03-10 | Polimeri Europa Spa | PROCESS FOR THE ELIMINATION OF REMAINING MERCAPTANES FROM NITRILE RUBBERS |
| US8367778B2 (en) | 2008-09-09 | 2013-02-05 | Polimeri Europa S.P.A. | Process for the elimination of residual mercaptans from nitrile rubbers |
| GB2594352A (en) * | 2020-02-17 | 2021-10-27 | Korea Kumho Petrochemical Co Ltd | Latex composition for dip molding and dip-molded article including the same |
| US11708441B2 (en) | 2020-02-17 | 2023-07-25 | Korea Kumho Petrochemical Co., Ltd. | Latex composition for dip molding and dip-molded article including the same |
| GB2594352B (en) * | 2020-02-17 | 2024-08-21 | Korea Kumho Petrochemical Co Ltd | Latex composition for dip molding and dip-molded article including the same |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2347755A1 (en) | 1975-04-10 |
| NL176175B (en) | 1984-10-01 |
| CA1053869A (en) | 1979-05-08 |
| IT1019341B (en) | 1977-11-10 |
| PL110067B1 (en) | 1980-06-30 |
| JPS5541601B2 (en) | 1980-10-25 |
| FR2244787A1 (en) | 1975-04-18 |
| NL7412481A (en) | 1975-03-25 |
| BE820146A (en) | 1975-03-20 |
| IN142708B (en) | 1977-08-20 |
| JPS5059440A (en) | 1975-05-22 |
| FR2244787B1 (en) | 1978-06-09 |
| DE2347755B2 (en) | 1978-12-07 |
| CS202540B2 (en) | 1981-01-30 |
| NL176175C (en) | 1985-03-01 |
| BR7407844D0 (en) | 1975-07-29 |
| ES430285A1 (en) | 1977-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |