GB1467340A - Fire retardant stable aqueous copolymer latex - Google Patents
Fire retardant stable aqueous copolymer latexInfo
- Publication number
- GB1467340A GB1467340A GB4886274A GB4886274A GB1467340A GB 1467340 A GB1467340 A GB 1467340A GB 4886274 A GB4886274 A GB 4886274A GB 4886274 A GB4886274 A GB 4886274A GB 1467340 A GB1467340 A GB 1467340A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- vinyl
- alkyl
- hydrogen
- hydrocarbyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 5
- 239000004816 latex Substances 0.000 title abstract 4
- 229920000126 latex Polymers 0.000 title abstract 4
- 239000003063 flame retardant Substances 0.000 title abstract 3
- -1 alkyl vinyl ethers Chemical class 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- 150000002431 hydrogen Chemical group 0.000 abstract 3
- LHHMNJZNWUJFOC-UHFFFAOYSA-N 1-chloro-2-[2-chloroethoxy(ethenyl)phosphoryl]oxyethane Chemical compound ClCCOP(=O)(C=C)OCCCl LHHMNJZNWUJFOC-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- GYQQNCSTNDNVMM-UHFFFAOYSA-L disodium 4-(octadecylamino)-4-oxo-2-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCCCNC(=O)CC(C([O-])=O)S(O)(=O)=O.CCCCCCCCCCCCCCCCCCNC(=O)CC(C([O-])=O)S(O)(=O)=O GYQQNCSTNDNVMM-UHFFFAOYSA-L 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical class CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-L ethenyl-dioxido-oxo-$l^{5}-phosphane Chemical compound [O-]P([O-])(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-L 0.000 abstract 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 abstract 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- VLJNBZUVERYEMA-UHFFFAOYSA-M sodium;4-amino-4-oxo-2-sulfobutanoate Chemical group [Na+].NC(=O)CC(C([O-])=O)S(O)(=O)=O VLJNBZUVERYEMA-UHFFFAOYSA-M 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/02—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
1467340 Fire retardant copolymer latex and its production STAUFFER CHEMICAL CO 12 Nov 1974 [12 Nov 1973] 48862/74 Heading C3P A stable, fire retardant copolymer latex comprising (1) at least one halogen-containing α,#- ethylenically unsaturated monomer; (2) at least one bis(hydrocarbyl)vinyl phosphonate having the formula wherein X is hydrogen, halogen, cyano, aryl, C 1-18 alkyl or -P(=O)OR<SP>1</SP>OR wherein R and R<SP>1</SP> are optionally substituted C 1-18 hydrocarbyl and may be the same, different or, when taken together with the phosphorus and oxygen atoms, form a heterocyclic ring structure; and optionally (3) at least one monomer selected from alpha olefins, vinyl esters of carboxylic acids, C 1-20 alkyl esters of acrylic and methacrylic acid, ethylenically unsaturated dicarboxylic acids, the anhydrides and C 1-20 mono- and di-alkyl esters thereof, amides of ethylenically unsaturated acids and the N-methylol and diacetone derivatives thereof; vinyl aryl compounds; C 1-20 alkyl vinyl ethers; C 4-20 dienes; and glycidyl esters of acrylic and methacrylic acid is prepared by an emulsion polymerization process in which the emulsifier is a sodium sulphosuccinamate of the formula wherein R 1 is hydrogen, C 1-18 hydrocarbyl or di-sodium, 1,2-dicarboxy ethyl and R 2 is C 1-18 hydrocarbyl, e.g. tetrasodium N - (1,2 - di - carboxyethyl) - N- octadecyl sulphosuccinamate and di-sodium N-octadecyl sulphosuccinamate. Numerous examples of the monomers (1), (2) and (3) are specified. The copolymer may also contain mono(alkyl) hydrogen, mono(cycloalkyl) hydrogen or mono(aryl)hydrogen vinyl phosphonates or bis(alkyl), bis(cycloalkyl) or bis- (aryl) allylphosphonates. Particularly preferred copolymers are formed from (1) vinylidene chloride vinyl chloride or vinylidene bromide and (2), bis(beta-chloroethyl) vinyl phosphonate, di-n-butyl vinyl phosphonate, or bis(2- chloroisopropyl)1 - methyl vinyl phosphonate and third monomers selected from those listed above. The latex copolymers may be blended with ordinarily flammable polymeric materials which may contain one or more cross-linkable comonomers N-methylol acrylamide, N-methylol methacrylamide, glycidyl acrylate and glycidyl methacrylate. The specific examples describe the polymerization of vinylidene chloride, bis(beta-chloroethyl) vinyl phosphonate and N- methylol acrylamide (60 : 150 : 15) in the presence of tetrasodium N-(1,2-dicarboxyethyl)-N- octadecyl sulphosuccinamate or disodium N- octadecyl sulphosuccinamate and their subsequent blending with polybutyl acrylate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41064473A | 1973-11-12 | 1973-11-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1467340A true GB1467340A (en) | 1977-03-16 |
Family
ID=23625615
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4886274A Expired GB1467340A (en) | 1973-11-12 | 1974-11-12 | Fire retardant stable aqueous copolymer latex |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5079592A (en) |
| BE (1) | BE822096A (en) |
| CA (1) | CA1052924A (en) |
| CS (1) | CS188206B2 (en) |
| DE (1) | DE2452369A1 (en) |
| FR (1) | FR2250776B1 (en) |
| GB (1) | GB1467340A (en) |
| IL (1) | IL45910A (en) |
| IT (1) | IT1023193B (en) |
| NL (1) | NL7414616A (en) |
| NO (1) | NO744035L (en) |
| SE (1) | SE7414120L (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004391A1 (en) * | 1978-03-20 | 1979-10-03 | Stauffer Chemical Company | Vinyl film/substrate laminate |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4218408A (en) * | 1976-05-03 | 1980-08-19 | Balcke-Durr Aktiengesellschaft | Cooling tower with ripple plates |
| DE4124560A1 (en) * | 1991-07-24 | 1993-01-28 | Wacker Chemie Gmbh | COATING AGENTS FOR THE PRODUCTION OF WATERPROOF, VAPOR-PERMEABLE AND FLAME-RETARDANT COATINGS |
| EP1976893B1 (en) * | 2006-01-09 | 2010-05-19 | Basf Se | Method for treating surfaces |
-
1974
- 1974-10-23 IL IL45910A patent/IL45910A/en unknown
- 1974-11-05 DE DE19742452369 patent/DE2452369A1/en active Pending
- 1974-11-08 CA CA213,401A patent/CA1052924A/en not_active Expired
- 1974-11-08 NL NL7414616A patent/NL7414616A/en not_active Application Discontinuation
- 1974-11-08 FR FR7437199A patent/FR2250776B1/fr not_active Expired
- 1974-11-08 NO NO744035A patent/NO744035L/no unknown
- 1974-11-09 JP JP49129479A patent/JPS5079592A/ja active Pending
- 1974-11-11 IT IT53956/74A patent/IT1023193B/en active
- 1974-11-11 SE SE7414120A patent/SE7414120L/xx unknown
- 1974-11-12 BE BE7000582A patent/BE822096A/en unknown
- 1974-11-12 GB GB4886274A patent/GB1467340A/en not_active Expired
- 1974-11-12 CS CS747700A patent/CS188206B2/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004391A1 (en) * | 1978-03-20 | 1979-10-03 | Stauffer Chemical Company | Vinyl film/substrate laminate |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2452369A1 (en) | 1975-05-22 |
| IL45910A (en) | 1977-06-30 |
| NL7414616A (en) | 1975-05-14 |
| BE822096A (en) | 1975-05-12 |
| NO744035L (en) | 1975-06-09 |
| IT1023193B (en) | 1978-05-10 |
| CA1052924A (en) | 1979-04-17 |
| CS188206B2 (en) | 1979-02-28 |
| JPS5079592A (en) | 1975-06-28 |
| FR2250776A1 (en) | 1975-06-06 |
| IL45910A0 (en) | 1974-12-31 |
| SE7414120L (en) | 1975-05-13 |
| FR2250776B1 (en) | 1979-06-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |