GB1434641A - Thermoplastic polyolefin compositions with controlled degra dability - Google Patents
Thermoplastic polyolefin compositions with controlled degra dabilityInfo
- Publication number
- GB1434641A GB1434641A GB4390873A GB4390873A GB1434641A GB 1434641 A GB1434641 A GB 1434641A GB 4390873 A GB4390873 A GB 4390873A GB 4390873 A GB4390873 A GB 4390873A GB 1434641 A GB1434641 A GB 1434641A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight per
- per cent
- peroxide
- compositions
- epoxidized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 229920002397 thermoplastic olefin Polymers 0.000 title 1
- -1 ethylene, propylene Chemical group 0.000 abstract 4
- 150000002978 peroxides Chemical class 0.000 abstract 4
- 229920000098 polyolefin Polymers 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 abstract 2
- 229920000573 polyethylene Polymers 0.000 abstract 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 abstract 2
- UYSQHMXRROFKRN-UHFFFAOYSA-N (2,4-dimethylphenyl)-phenylmethanone Chemical compound CC1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 UYSQHMXRROFKRN-UHFFFAOYSA-N 0.000 abstract 1
- OJLABXSUFRIXFL-UHFFFAOYSA-N (2-benzoylphenyl)-phenylmethanone Chemical compound C=1C=CC=C(C(=O)C=2C=CC=CC=2)C=1C(=O)C1=CC=CC=C1 OJLABXSUFRIXFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000005909 Kieselgur Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 abstract 1
- 239000004295 calcium sulphite Substances 0.000 abstract 1
- 235000010261 calcium sulphite Nutrition 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001879 copper Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- IIRVGTWONXBBAW-UHFFFAOYSA-M disodium;dioxido(oxo)phosphanium Chemical compound [Na+].[Na+].[O-][P+]([O-])=O IIRVGTWONXBBAW-UHFFFAOYSA-M 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
- 159000000014 iron salts Chemical class 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 125000005474 octanoate group Chemical group 0.000 abstract 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920001748 polybutylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000010094 polymer processing Methods 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0033—Additives activating the degradation of the macromolecular compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1434641 Degradable polyolefin compositions CHEMISCHE WERKE HULS AG 19 Sept 1973 [20 Sept 1972] 43908/73 Heading C3P Thermoplastic compositions of controlled degradability comprise relative to the polyolefin (a) 0À01 to 1 weight per cent of an antioxidant, (b) 0À02 to 1 weight per cent of an organic copper salt, (c) 0À1 to 2 weight per cent of an organic manganese, cobalt or iron salt, (d) 0À01 to 0À4 weight per cent of a peroxide, (e) 0À02 to 3 weight per cent of a ketone and optionally (f) 1 to 10 weight per cent of an optionally epoxidized hydrocarbon oil, carboxylic acid ester or carboxylic acid amide. The polyolefin may be a polymer or copolymer of ethylene, propylene or butene-1. The antioxidant may be a hindered phenol. The copper, manganese, cobalt and iron salts may be resinates, naphthenates, oleates, palmitates, stearates and octoates. The peroxide may be cumene, benzoyl, propyl, t-butyl, cyclohexyl, barium or potassium peroxide. Preferably a mixture of a peroxide which decomposes at polymer processing temperatures with a peroxide which is stable at such temperatures is used. The ketone may be benzophenone, benzoin, 2,4-dimethyl benzophenone, o-dibenzoyl benzene or a hydroxyketone of melting point above 250‹ C. The epoxidized oil may be an epoxidized polyethylene or polybutadiene, or an epoxidized vegetable oil. The compositions may also contain light stabilizers, reducing agents such as disodium phosphite and calcium sulphite, and fillers such as kaolin, clay and diatomaceous earth. The compositions may be subject to silent electric discharges, e.g. corona discharges. Examples describe compositions of polybutene-1, polypropylene and polyethylene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722246167 DE2246167C3 (en) | 1972-09-20 | Thermoplastic molding compounds with targeted degradation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1434641A true GB1434641A (en) | 1976-05-05 |
Family
ID=5856862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4390873A Expired GB1434641A (en) | 1972-09-20 | 1973-09-19 | Thermoplastic polyolefin compositions with controlled degra dability |
Country Status (4)
| Country | Link |
|---|---|
| FR (1) | FR2200299B1 (en) |
| GB (1) | GB1434641A (en) |
| IT (1) | IT1000075B (en) |
| NL (1) | NL7312913A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU626260B2 (en) * | 1987-05-21 | 1992-07-30 | Epron Industries Limited | Degradable plastics |
| US5545681A (en) * | 1993-12-20 | 1996-08-13 | The Procter & Gamble Company | pH-Modified polymer compositions with enhanced biodegradability |
| WO2006043827A1 (en) * | 2004-10-22 | 2006-04-27 | Nor-X Industry As | Thermoplastic material with adjustable useful lifetime, method for their manufacture and products thereof |
| RU2336286C2 (en) * | 2003-04-23 | 2008-10-20 | Нор-Икс Индастри Ас | Additive for thermoplastic, its application and method of its production, method of producing thermoplastic, containing said additive, and thermoplastic, produced in said way |
| WO2007027163A3 (en) * | 2005-09-01 | 2008-11-13 | Super Film Ambalaj Sanayi Ve T | Degradable biodegradable polypropylene film |
| RU2352597C1 (en) * | 2008-06-25 | 2009-04-20 | Александр Николаевич Пономарев | Biodegradable granular polyolefin blend and method of production |
| RU2686179C1 (en) * | 2017-12-12 | 2019-04-24 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Воронежский государственный университет инженерных технологий" (ФГБОУ ВО "ВГУИТ") | One-step method of producing a pro-oxidant additive to polyolefins |
| RU2804818C2 (en) * | 2022-03-16 | 2023-10-06 | Общество с ограниченной ответственностью "Активная упаковка" | Concentrated polymer composition (master batch) with antimicrobial properties and biodegradability based on polyolefins |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR930703370A (en) * | 1990-12-21 | 1993-11-29 | 다이안 제이. 맥마혼 | Photodegradable Plastic Composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1052998A (en) * | 1963-11-12 | 1966-12-30 | ||
| US3886683A (en) * | 1970-11-27 | 1975-06-03 | Princeton Chemical Res Inc | Degradable plastic |
| BE789277A (en) * | 1971-09-27 | 1973-03-26 | Union Carbide Corp | COMPOSITION OF ETHYLENE POLYMER DEGRADABLE UNDER THE ACTION OF WEATHER |
-
1973
- 1973-09-06 FR FR7332170A patent/FR2200299B1/fr not_active Expired
- 1973-09-18 IT IT5257873A patent/IT1000075B/en active
- 1973-09-19 GB GB4390873A patent/GB1434641A/en not_active Expired
- 1973-09-19 NL NL7312913A patent/NL7312913A/xx not_active Application Discontinuation
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU626260B2 (en) * | 1987-05-21 | 1992-07-30 | Epron Industries Limited | Degradable plastics |
| US5545681A (en) * | 1993-12-20 | 1996-08-13 | The Procter & Gamble Company | pH-Modified polymer compositions with enhanced biodegradability |
| RU2336286C2 (en) * | 2003-04-23 | 2008-10-20 | Нор-Икс Индастри Ас | Additive for thermoplastic, its application and method of its production, method of producing thermoplastic, containing said additive, and thermoplastic, produced in said way |
| CN100436520C (en) * | 2003-04-23 | 2008-11-26 | Nor-X工业公司 | Additive for thermoplastics, use of and method for its manufacture, method for the manufacture of a thermoplastic containing such additive and thermoplastic so manufactured |
| AU2004232619B2 (en) * | 2003-04-23 | 2009-12-03 | Nor-X Industry As | Additive for thermoplastics, use of and method for its manufacture, method for the manufacture of a thermoplastic containing such additive and thermoplastic so manufactured |
| WO2006043827A1 (en) * | 2004-10-22 | 2006-04-27 | Nor-X Industry As | Thermoplastic material with adjustable useful lifetime, method for their manufacture and products thereof |
| WO2007027163A3 (en) * | 2005-09-01 | 2008-11-13 | Super Film Ambalaj Sanayi Ve T | Degradable biodegradable polypropylene film |
| RU2352597C1 (en) * | 2008-06-25 | 2009-04-20 | Александр Николаевич Пономарев | Biodegradable granular polyolefin blend and method of production |
| RU2686179C1 (en) * | 2017-12-12 | 2019-04-24 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Воронежский государственный университет инженерных технологий" (ФГБОУ ВО "ВГУИТ") | One-step method of producing a pro-oxidant additive to polyolefins |
| RU2804818C2 (en) * | 2022-03-16 | 2023-10-06 | Общество с ограниченной ответственностью "Активная упаковка" | Concentrated polymer composition (master batch) with antimicrobial properties and biodegradability based on polyolefins |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7312913A (en) | 1974-03-22 |
| FR2200299B1 (en) | 1978-10-20 |
| DE2246167B2 (en) | 1976-03-11 |
| DE2246167A1 (en) | 1974-03-28 |
| IT1000075B (en) | 1976-03-30 |
| FR2200299A1 (en) | 1974-04-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |