GB1400681A - Process for applying a protective irridescent coating to zinc and cadmium and a composition therefor - Google Patents
Process for applying a protective irridescent coating to zinc and cadmium and a composition thereforInfo
- Publication number
- GB1400681A GB1400681A GB222173A GB222173A GB1400681A GB 1400681 A GB1400681 A GB 1400681A GB 222173 A GB222173 A GB 222173A GB 222173 A GB222173 A GB 222173A GB 1400681 A GB1400681 A GB 1400681A
- Authority
- GB
- United Kingdom
- Prior art keywords
- soluble
- zinc
- cro
- aryl
- cadmium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011701 zinc Substances 0.000 title abstract 9
- 229910052793 cadmium Inorganic materials 0.000 title abstract 8
- 229910052725 zinc Inorganic materials 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000001681 protective effect Effects 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 2
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 229910001335 Galvanized steel Inorganic materials 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 150000001639 boron compounds Chemical class 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000008397 galvanized steel Substances 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 238000002161 passivation Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/24—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
- C23C22/26—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds containing also organic compounds
- C23C22/27—Acids
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
1400681 Passivation of Zn and Cd ORDENA TRUDOVOGO KRASNOGO ZNAMENI INSTITUT KHIMII I KHIMCHESKOI TEKHNOLOGII AKADEMII NAUK LITOVSKOI SSR 16 Jan 1973 [5 April 1972] 2221/73 Heading C7U A passivating composition for zinc or cadmium comprises (dry mixture, weight parts; aqueous solution gms/l) (a) 1À7-70À0 (as Cr) of CrO 3 or a soluble chromate (b) 1À0-45À0 (as NO 3 ) of a soluble nitrate (c) 1À0-25À0 (as SO 4 ) of a soluble sulphate (d) 0À5-10À0 (as B) of a soluble boron compound and (e) 0À05-6À0 of where R 1 , R 2 , R 3 , and R4 are H, C 1 -C 8 alkyl, aryl, aralkyl, alkaryl (each substituted or unsubstituted) and n is 1-5. The groups R 1 to R4 may be substituted by -OH, -OR, -COR, -COOH, -COOR, -CONH 2 , -CN, -NH 2 , -NHR, -NR 2 , where R is alkyl or aryl; a list of suitable acids (e) is given. Compounds (a) may be CrO 3 , chromates of NH4, Be, K, Cd, Li, Mg, Na or Zn and/or dichromates of NH 4 , Be, K, Cd, Li, Mg, Na or Zn, (b) may be nitrates of NH 4 , Be, K, Na, Cd, Li, Mg, Na and/or Zn, (c) may be sulphates of NH4, Be, K, Cd, Li, Mg, Na and/or Zn and/or bisulphates of NH 4 , K, Li, or Na and (d) may be boric acid, Mg orthoborate, or a polyborate of NH 4 , Be, K, Li, Mg, or Na, e.g. Na tetraborate. The pH of the aqueous solution is adjusted to 1À1 to 2À8 by addition of acid such as H 2 SO 4 or alkali such as NaOH, and the solution is used at 15-30C for 3-90 seconds to treat, e.g. steel coated with Zn or Cd electrolytically from a cyanide bath, or hotdip galvanized steel, or other Zn or Cd surfaces.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU7201762901A SU384443A1 (en) | 1972-04-05 | 1972-04-05 | Composition for preparing solution passivating the surface of zinc and cadmium |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1400681A true GB1400681A (en) | 1975-07-23 |
Family
ID=20507624
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB222173A Expired GB1400681A (en) | 1972-04-05 | 1973-01-16 | Process for applying a protective irridescent coating to zinc and cadmium and a composition therefor |
Country Status (11)
Country | Link |
---|---|
US (1) | US3855010A (en) |
CA (1) | CA994219A (en) |
CS (1) | CS169955B1 (en) |
DD (1) | DD102165A1 (en) |
DE (1) | DE2301096C3 (en) |
FR (1) | FR2179112B1 (en) |
GB (1) | GB1400681A (en) |
HU (1) | HU166110B (en) |
IT (1) | IT974434B (en) |
PL (1) | PL91823B1 (en) |
SU (1) | SU384443A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4591416A (en) * | 1983-01-04 | 1986-05-27 | Ebara-Udylite Co., Ltd. | Chromate composition and process for treating zinc-nickel alloys |
JP3904258B2 (en) * | 1996-05-23 | 2007-04-11 | ディップソール株式会社 | Black chromate treatment solution for Zn-Ni alloy plating |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2483510A (en) * | 1945-04-14 | 1949-10-04 | United Chromium Inc | Composition for dip coating solution and dip process for coloring zinc |
US2904414A (en) * | 1954-08-04 | 1959-09-15 | Allied Res Products Inc | Formulation for producing a protective bright chemically polished surface on zinc and cadmium |
US3121032A (en) * | 1960-09-27 | 1964-02-11 | M & T Chemicals Inc | Process for applying a protective transparent coating to zinc and cadmium and composition therefor |
BE635940A (en) * | 1962-08-15 | |||
US3519501A (en) * | 1968-04-16 | 1970-07-07 | Diamond Shamrock Corp | Chromic acid-organic coating compositions |
-
1972
- 1972-04-05 SU SU7201762901A patent/SU384443A1/en active
- 1972-12-29 US US00319391A patent/US3855010A/en not_active Expired - Lifetime
- 1972-12-29 IT IT55176/72A patent/IT974434B/en active
-
1973
- 1973-01-10 DE DE2301096A patent/DE2301096C3/en not_active Expired
- 1973-01-16 GB GB222173A patent/GB1400681A/en not_active Expired
- 1973-01-19 CA CA161,600A patent/CA994219A/en not_active Expired
- 1973-02-07 DD DD168737A patent/DD102165A1/xx unknown
- 1973-04-03 PL PL1973161690A patent/PL91823B1/pl unknown
- 1973-04-04 FR FR7312139A patent/FR2179112B1/fr not_active Expired
- 1973-04-04 CS CS2413A patent/CS169955B1/cs unknown
- 1973-04-05 HU HUII140A patent/HU166110B/hu unknown
Also Published As
Publication number | Publication date |
---|---|
FR2179112B1 (en) | 1976-06-11 |
CA994219A (en) | 1976-08-03 |
PL91823B1 (en) | 1977-03-31 |
DE2301096B2 (en) | 1978-04-13 |
DE2301096A1 (en) | 1973-10-18 |
SU384443A1 (en) | 1977-12-05 |
HU166110B (en) | 1975-01-28 |
DD102165A1 (en) | 1973-12-12 |
IT974434B (en) | 1974-06-20 |
DE2301096C3 (en) | 1978-12-14 |
FR2179112A1 (en) | 1973-11-16 |
CS169955B1 (en) | 1976-08-27 |
US3855010A (en) | 1974-12-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |