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GB1368449A - Preparation of cyclohexanone by selective vapour - Google Patents

Preparation of cyclohexanone by selective vapour

Info

Publication number
GB1368449A
GB1368449A GB4325171A GB4325171A GB1368449A GB 1368449 A GB1368449 A GB 1368449A GB 4325171 A GB4325171 A GB 4325171A GB 4325171 A GB4325171 A GB 4325171A GB 1368449 A GB1368449 A GB 1368449A
Authority
GB
United Kingdom
Prior art keywords
prepared
catalyst
carrier material
alumina
nitrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4325171A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19702045882 external-priority patent/DE2045882C3/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1368449A publication Critical patent/GB1368449A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/006—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenation of aromatic hydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1368449 Cyclohexanone BAYER AG 16 Sept 1971 [17 Sept 1970] 43251/71 Heading C2C [Also in Division Bl] Cyclohexanone is prepared by vapour phase hydrogenation of phenol at a temperature of from 100‹ to 350‹ C. in the presence of catalyst which comprises palladium supported on carrier material which comprises an aluminium spinel. Palladium constitutes preferably from 0.01 to 10 weight per cent of the catalyst; aluminium spinel constitutes preferably at least 20 weight per cent of the carrier material which preferably has a surface area of from 20 to 120 m.<SP>2</SP>/g. and an average pore diameter of from 200 to 800 Angstroms and may have been prepared from alumina and a compound, for example hydroxide or salt such as nitrate or organic acid salt, of at least one metal selected from lithium, magnesium, zinc, cobalt and nickel. As exemplified, phenol is hydrogenated at 150-220‹ C. in the presence of catalyst prepared from palladium (II) chloride and carrier material which has been prepared either from gamma-alumina and lithium hydroxide or zinc nitrate or from active alumina and magnesium nitrate or cobalt (II) nitrate and in the presence of comparison catalyst prepared from palladium (II) chloride and carrier material which is alpha-alumina or gammaalumina, each catalyst being treated with hydrogen at 200‹ C. prior to use.
GB4325171A 1970-09-17 1971-09-16 Preparation of cyclohexanone by selective vapour Expired GB1368449A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19702045882 DE2045882C3 (en) 1970-09-17 Process for the production of cyclohexanone by selective hydrogenation of phenol in the gas phase

Publications (1)

Publication Number Publication Date
GB1368449A true GB1368449A (en) 1974-09-25

Family

ID=5782627

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4325171A Expired GB1368449A (en) 1970-09-17 1971-09-16 Preparation of cyclohexanone by selective vapour

Country Status (15)

Country Link
JP (1) JPS528824B1 (en)
BE (1) BE772764A (en)
BG (1) BG21013A3 (en)
CA (1) CA996953A (en)
CH (1) CH558675A (en)
CS (1) CS170103B2 (en)
ES (1) ES395133A1 (en)
FR (1) FR2108255A5 (en)
GB (1) GB1368449A (en)
HU (1) HU163988B (en)
IT (1) IT954133B (en)
NL (1) NL170726C (en)
PL (1) PL77961B1 (en)
RO (1) RO59280A (en)
SU (1) SU413656A3 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0037856A1 (en) * 1980-01-24 1981-10-21 Allied Corporation Enhanced distillation of cyclohexanol from phenol with additional cyclohexanone feed
GB2276332A (en) * 1993-03-26 1994-09-28 British Tech Group Catalytic method of replacing halogen in halocarbons
WO2010005859A2 (en) * 2008-07-07 2010-01-14 Albemarle Corporation Processes for hydrogenating aromatic amines

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0037856A1 (en) * 1980-01-24 1981-10-21 Allied Corporation Enhanced distillation of cyclohexanol from phenol with additional cyclohexanone feed
GB2276332A (en) * 1993-03-26 1994-09-28 British Tech Group Catalytic method of replacing halogen in halocarbons
GB2276332B (en) * 1993-03-26 1997-09-03 British Tech Group Catalytic method of replacing halogen in halocarbons
WO2010005859A2 (en) * 2008-07-07 2010-01-14 Albemarle Corporation Processes for hydrogenating aromatic amines
WO2010005859A3 (en) * 2008-07-07 2010-05-06 Albemarle Corporation Processes for hydrogenation

Also Published As

Publication number Publication date
CA996953A (en) 1976-09-14
CH558675A (en) 1975-02-14
IT954133B (en) 1973-08-30
ES395133A1 (en) 1974-11-16
CS170103B2 (en) 1976-08-27
FR2108255A5 (en) 1972-05-19
BE772764A (en) 1972-03-17
SU413656A3 (en) 1974-01-30
DE2045882B2 (en) 1976-01-15
NL170726B (en) 1982-07-16
DE2045882A1 (en) 1972-03-23
HU163988B (en) 1973-12-28
JPS528824B1 (en) 1977-03-11
BG21013A3 (en) 1976-01-20
PL77961B1 (en) 1975-04-30
NL170726C (en) 1982-12-16
NL7112756A (en) 1972-03-21
RO59280A (en) 1976-02-15

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee