GB1310283A - Process for hydrogenative cracking of carbonaceous material - Google Patents
Process for hydrogenative cracking of carbonaceous materialInfo
- Publication number
- GB1310283A GB1310283A GB1310283DA GB1310283A GB 1310283 A GB1310283 A GB 1310283A GB 1310283D A GB1310283D A GB 1310283DA GB 1310283 A GB1310283 A GB 1310283A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bromide
- halide
- iodide
- carbonaceous material
- coal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003575 carbonaceous material Substances 0.000 title abstract 3
- 238000005336 cracking Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- 239000003245 coal Substances 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- -1 zinc halide Chemical class 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910001508 alkali metal halide Inorganic materials 0.000 abstract 1
- 150000008045 alkali metal halides Chemical class 0.000 abstract 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 abstract 1
- JMBNQWNFNACVCB-UHFFFAOYSA-N arsenic tribromide Chemical compound Br[As](Br)Br JMBNQWNFNACVCB-UHFFFAOYSA-N 0.000 abstract 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 abstract 1
- SRVXDMYFQIODQI-UHFFFAOYSA-K gallium(iii) bromide Chemical compound Br[Ga](Br)Br SRVXDMYFQIODQI-UHFFFAOYSA-K 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 229910001507 metal halide Inorganic materials 0.000 abstract 1
- 150000005309 metal halides Chemical class 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 229940005657 pyrophosphoric acid Drugs 0.000 abstract 1
- 239000011269 tar Substances 0.000 abstract 1
- 239000011275 tar sand Substances 0.000 abstract 1
- LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 abstract 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/086—Characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1310283 Hydrocracking SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 12 June 1970 28603/70 Heading C5E Carbonaceous material is cracked at elevated temperature and pressure in the presence of H 2 with a continuous phase of catalyst containing at least one of the following halides:-ZnCl 2 , ZnBr 2 , ZnI 2 ; antimony chloride, bromide or iodide; bismuth chloride or bromide; tin bromide; titanium iodide; arsenic bromide or iodide; HgBr 2 ; HgI 2 and gallium bromide with the proviso that when a zinc halide is used a modifying salt which lowers hydrocarbon solubility in the molten halide is additionally employed. The carbonaceous material may comprise heavy hydrocarbons, heavy petroleum fractions, petroleum residues, tars, coal and/or liquid products derived from coal, tar sand and/or shale. A mineral acid, e.g. H 2 SO 4 , pyrophosphoric acid or a hydrogen halide corresponding to the halogen of the metal halide, may also be present. The modifying salt for zinc halides may be an alkali metal halide. The continuous phase may be maintained at 200- 550‹ C. and under a H 2 partial pressure of at least 17-5 atmospheres.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2860370 | 1970-06-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1310283A true GB1310283A (en) | 1973-03-14 |
Family
ID=10278222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1310283D Expired GB1310283A (en) | 1970-06-12 | 1970-06-12 | Process for hydrogenative cracking of carbonaceous material |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1310283A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2159168A (en) * | 1984-05-25 | 1985-11-27 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
| US7402547B2 (en) | 2003-12-19 | 2008-07-22 | Shell Oil Company | Systems and methods of producing a crude product |
| WO2009009976A1 (en) * | 2007-07-19 | 2009-01-22 | Hanergy Tech Co., Ltd. | Catalyst combination and process for direct liquefaction of carbonaceous materials by using the same |
| WO2009018746A1 (en) * | 2007-08-08 | 2009-02-12 | Hanergy Tech Co., Ltd. | A catalyst for producing diesel from coal tar and its preparation and application |
| US7534342B2 (en) | 2003-12-19 | 2009-05-19 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7678264B2 (en) | 2005-04-11 | 2010-03-16 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
| US7749374B2 (en) | 2006-10-06 | 2010-07-06 | Shell Oil Company | Methods for producing a crude product |
| US7918992B2 (en) | 2005-04-11 | 2011-04-05 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| CN101353586B (en) * | 2007-07-25 | 2012-03-21 | 汉能科技有限公司 | Coal direct liquefaction method |
-
1970
- 1970-06-12 GB GB1310283D patent/GB1310283A/en not_active Expired
Cited By (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2159168A (en) * | 1984-05-25 | 1985-11-27 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
| GB2159168B (en) * | 1984-05-25 | 1989-05-10 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
| US7828958B2 (en) | 2003-12-19 | 2010-11-09 | Shell Oil Company | Systems and methods of producing a crude product |
| US7674368B2 (en) | 2003-12-19 | 2010-03-09 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7416653B2 (en) | 2003-12-19 | 2008-08-26 | Shell Oil Company | Systems and methods of producing a crude product |
| US8663453B2 (en) | 2003-12-19 | 2014-03-04 | Shell Oil Company | Crude product composition |
| US8613851B2 (en) | 2003-12-19 | 2013-12-24 | Shell Oil Company | Crude product composition |
| US7534342B2 (en) | 2003-12-19 | 2009-05-19 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7588681B2 (en) | 2003-12-19 | 2009-09-15 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7591941B2 (en) | 2003-12-19 | 2009-09-22 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7615196B2 (en) | 2003-12-19 | 2009-11-10 | Shell Oil Company | Systems for producing a crude product |
| US7625481B2 (en) | 2003-12-19 | 2009-12-01 | Shell Oil Company | Systems and methods of producing a crude product |
| US7628908B2 (en) | 2003-12-19 | 2009-12-08 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7648625B2 (en) | 2003-12-19 | 2010-01-19 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7837863B2 (en) | 2003-12-19 | 2010-11-23 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7674370B2 (en) | 2003-12-19 | 2010-03-09 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US8608946B2 (en) | 2003-12-19 | 2013-12-17 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7736490B2 (en) | 2003-12-19 | 2010-06-15 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
| US8608938B2 (en) | 2003-12-19 | 2013-12-17 | Shell Oil Company | Crude product composition |
| US7763160B2 (en) | 2003-12-19 | 2010-07-27 | Shell Oil Company | Systems and methods of producing a crude product |
| US7780844B2 (en) | 2003-12-19 | 2010-08-24 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7807046B2 (en) | 2003-12-19 | 2010-10-05 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7811445B2 (en) | 2003-12-19 | 2010-10-12 | Shell Oil Company | Systems and methods of producing a crude product |
| US7413646B2 (en) | 2003-12-19 | 2008-08-19 | Shell Oil Company | Systems and methods of producing a crude product |
| US7402547B2 (en) | 2003-12-19 | 2008-07-22 | Shell Oil Company | Systems and methods of producing a crude product |
| US8025794B2 (en) | 2003-12-19 | 2011-09-27 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7879223B2 (en) | 2003-12-19 | 2011-02-01 | Shell Oil Company | Systems and methods of producing a crude product |
| US8506794B2 (en) | 2003-12-19 | 2013-08-13 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7955499B2 (en) | 2003-12-19 | 2011-06-07 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7959797B2 (en) | 2003-12-19 | 2011-06-14 | Shell Oil Company | Systems and methods of producing a crude product |
| US7959796B2 (en) | 2003-12-19 | 2011-06-14 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US8025791B2 (en) | 2003-12-19 | 2011-09-27 | Shell Oil Company | Systems and methods of producing a crude product |
| US7854833B2 (en) | 2003-12-19 | 2010-12-21 | Shell Oil Company | Systems and methods of producing a crude product |
| US8070936B2 (en) | 2003-12-19 | 2011-12-06 | Shell Oil Company | Systems and methods of producing a crude product |
| US8070937B2 (en) | 2003-12-19 | 2011-12-06 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US8475651B2 (en) | 2003-12-19 | 2013-07-02 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US8163166B2 (en) | 2003-12-19 | 2012-04-24 | Shell Oil Company | Systems and methods of producing a crude product |
| US8394254B2 (en) | 2003-12-19 | 2013-03-12 | Shell Oil Company | Crude product composition |
| US8241489B2 (en) | 2003-12-19 | 2012-08-14 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US8268164B2 (en) | 2003-12-19 | 2012-09-18 | Shell Oil Company | Systems and methods of producing a crude product |
| US8481450B2 (en) | 2005-04-11 | 2013-07-09 | Shell Oil Company | Catalysts for producing a crude product |
| US7918992B2 (en) | 2005-04-11 | 2011-04-05 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7678264B2 (en) | 2005-04-11 | 2010-03-16 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| US7749374B2 (en) | 2006-10-06 | 2010-07-06 | Shell Oil Company | Methods for producing a crude product |
| CN101348726B (en) * | 2007-07-19 | 2012-06-27 | 汉能科技有限公司 | Coal direct liquefaction method |
| WO2009009976A1 (en) * | 2007-07-19 | 2009-01-22 | Hanergy Tech Co., Ltd. | Catalyst combination and process for direct liquefaction of carbonaceous materials by using the same |
| CN101353586B (en) * | 2007-07-25 | 2012-03-21 | 汉能科技有限公司 | Coal direct liquefaction method |
| WO2009018746A1 (en) * | 2007-08-08 | 2009-02-12 | Hanergy Tech Co., Ltd. | A catalyst for producing diesel from coal tar and its preparation and application |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |