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GB1274302A - Photographic silver halide materials containing silica particles - Google Patents

Photographic silver halide materials containing silica particles

Info

Publication number
GB1274302A
GB1274302A GB03884/69A GB1388469A GB1274302A GB 1274302 A GB1274302 A GB 1274302A GB 03884/69 A GB03884/69 A GB 03884/69A GB 1388469 A GB1388469 A GB 1388469A GB 1274302 A GB1274302 A GB 1274302A
Authority
GB
United Kingdom
Prior art keywords
silver halide
poly
surface coating
emulsion layer
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB03884/69A
Inventor
Robrecht Julius Thiers
Jozef Frans Willems
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa Gevaert NV
Agfa Gevaert AG
Original Assignee
Agfa Gevaert NV
Agfa Gevaert AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa Gevaert NV, Agfa Gevaert AG filed Critical Agfa Gevaert NV
Priority to GB03884/69A priority Critical patent/GB1274302A/en
Priority to US853211A priority patent/US3656954A/en
Priority to SE12422/69A priority patent/SE358747B/xx
Priority to FR6931058A priority patent/FR2034977A1/fr
Priority to BE738856D priority patent/BE738856A/xx
Priority to DE1955898A priority patent/DE1955898C2/en
Publication of GB1274302A publication Critical patent/GB1274302A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/34Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/04Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
    • G03C1/053Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/30Hardeners
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/815Photosensitive materials characterised by the base or auxiliary layers characterised by means for filtering or absorbing ultraviolet light, e.g. optical bleaching
    • G03C1/8155Organic compounds therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/85Photosensitive materials characterised by the base or auxiliary layers characterised by antistatic additives or coatings
    • G03C1/856Phosphorus compounds
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/95Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/151Matting or other surface reflectivity altering material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/155Nonresinous additive to promote interlayer adhesion in element

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

1,274,302. Photographic silver halide materials containing silica particles. AGFAGEVAERT. Sept. 10, 1969 [March 17, 1969], No. 13884/69. Heading G2C. A photographic material comprises a support, a light-sensitive silver halide emulsion layer and a non-light-sensitive hydrophilic colloid protective surface coating which is coated at the same side of the support as the said emulsion layer and contains dispersed therein silica particles wherein said material contains in one of its hydrophilic colloid layers resorcinol and in the same or other hydrophilic layer a poly-N-vinyl lactam or polyvinyl lactone and the said hydrophilic protective surface coating also contains a polycarbocyclic aromatic (i.e. two or more benzene rings fused together, or at least two aromatic rings directly joined together or joined by an aliphatic or carbocyclic aromatic group which groups may be interrupted by one or more hetero atoms) sulphoric acid or a water soluble salt thereof, preferably of the formula:- wherein M is H, a water-solubilizing metal cation or ammonium, B 1 is H, a fused aromatic ring which may be substituted, or an amino group which may be substituted, A is alkylene, alkenylene or bisamido, and B 2 is an aromatic group which may be substituted. Resorcinol is preferably present in the light-sensitive silver halide emulsion layer, and the poly-N-vinyllactam or polyvinyllactone is preferably present in the non- light-sensitive hydrophilic colloid protective surface coating. The poly-N-vinyl lactam is preferably poly-N-vinyl-2-pyrrolidone and the preferred polyvinyl lactone is poly-N-vinyl-2- oxazolidone. These compounds are anti-foggants. The average silica particle size is preferably less than 1 micron. The hydrophilic colloid of the surface coating is preferably gelatine. The silver halide emulsion layer may be a gelatino silver halide X-ray emulsion layer and the material may be an X-ray film having both sides coated as above. The milkiness and cloudiness produced by resorcinol and a polyvinyl lactam or lactone is reduced or eliminated by the presence of silica and a polycarbocyclic aromatic (as defined above) sulphonic acid or water-soluble salt thereof in the surface coating.
GB03884/69A 1969-03-17 1969-03-17 Photographic silver halide materials containing silica particles Expired GB1274302A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB03884/69A GB1274302A (en) 1969-03-17 1969-03-17 Photographic silver halide materials containing silica particles
US853211A US3656954A (en) 1969-03-17 1969-08-26 Photographic material with improved surface properties
SE12422/69A SE358747B (en) 1969-03-17 1969-09-09
FR6931058A FR2034977A1 (en) 1969-03-17 1969-09-11
BE738856D BE738856A (en) 1969-03-17 1969-09-15
DE1955898A DE1955898C2 (en) 1969-03-17 1969-11-06 Photographic recording material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB03884/69A GB1274302A (en) 1969-03-17 1969-03-17 Photographic silver halide materials containing silica particles

Publications (1)

Publication Number Publication Date
GB1274302A true GB1274302A (en) 1972-05-17

Family

ID=10031110

Family Applications (1)

Application Number Title Priority Date Filing Date
GB03884/69A Expired GB1274302A (en) 1969-03-17 1969-03-17 Photographic silver halide materials containing silica particles

Country Status (6)

Country Link
US (1) US3656954A (en)
BE (1) BE738856A (en)
DE (1) DE1955898C2 (en)
FR (1) FR2034977A1 (en)
GB (1) GB1274302A (en)
SE (1) SE358747B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3885963A (en) * 1972-04-18 1975-05-27 Xerox Corp Light activating imaging process
US3856527A (en) * 1973-08-06 1974-12-24 Eastman Kodak Co Protective layer for photothermographic elements
US3856526A (en) * 1973-08-06 1974-12-24 Eastman Kodak Co Protective layer for photothermographic elements
JPS51134621A (en) * 1975-05-16 1976-11-22 Fuji Photo Film Co Ltd Silver halide photosensitive materials
JPS5494319A (en) * 1978-01-09 1979-07-26 Konishiroku Photo Ind Co Ltd Silver halide photographic material
IT1253002B (en) * 1990-10-05 1995-07-10 Minnesota Mining & Mfg PHOTOGRAPHIC ELEMENT WITH SILVER HALIDES AND PROCEDURE TO PREPARE A DISPERSION IN WATER COMPOSITIONS OF DISCRETE PARTICLES OF A WATER-INSOLUBLE POLYMER AGENT
US11814210B1 (en) * 2023-05-15 2023-11-14 Ryan Benson Dual mouth shotgun can

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB811182A (en) * 1956-08-20 1959-04-02 Ici Ltd Improvement of photographic prints
US3022169A (en) * 1958-03-05 1962-02-20 Agfa Ag Matting of photographic layers
US3181948A (en) * 1958-06-02 1965-05-04 Gevaert Photo Prod Nv Method for optical bleaching of coated papers and resultant product
BE581611A (en) * 1958-08-27
US3006762A (en) * 1959-02-09 1961-10-31 Gen Aniline & Film Corp Sensitizers for photographic emulsions
NL251799A (en) * 1959-05-19
US3058826A (en) * 1959-12-11 1962-10-16 Du Pont Photographic elements exhibiting reduced haze and method for preparation
US3380828A (en) * 1965-08-02 1968-04-30 Eastman Kodak Co Antistain agents for spectrally sensitized silver halide photographic elements

Also Published As

Publication number Publication date
DE1955898C2 (en) 1983-05-05
DE1955898A1 (en) 1970-10-01
FR2034977A1 (en) 1970-12-18
BE738856A (en) 1970-03-16
SE358747B (en) 1973-08-06
US3656954A (en) 1972-04-18

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
435 Patent endorsed 'licences of right' on the date specified (sect. 35/1949)
PCNP Patent ceased through non-payment of renewal fee